Magnetic and magnetocaloric properties of Dy5Pd2: role of magnetic irreversibility

RSC Advances ◽  
2015 ◽  
Vol 5 (59) ◽  
pp. 47860-47865 ◽  
Author(s):  
Tapas Paramanik ◽  
Tapas Samanta ◽  
R. Ranganathan ◽  
I. Das
Keyword(s):  
Intermetallic Compound ◽  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Temperature Region ◽  
Magnetocaloric Properties ◽  
Magnetic Irreversibility

In this report the origin of giant inverse magnetocaloric effect at low temperature region has been studied in cluster glass intermetallic compound Dy5Pd2. In this context the procedure to obtain reversible magnetocaloric effect using Maxwell’s relation has been described.

scholarly journals Новые магнитные материалы на основе соединений RNi для криогенной техники

2020 ◽  
Vol 46 (6) ◽  
pp. 51
Author(s):  
В.Б. Чжан ◽  
И.С. Терёшина ◽  
А.А. Курганская ◽  
С.А. Лушников ◽  
В.Н. Вербецкий ◽  
...  
Keyword(s):  
Low Temperature ◽  
Curie Temperature ◽  
Magnetocaloric Effect ◽  
Temperature Region ◽  
Partial Substitution ◽  
Temperature Range ◽  
Magnetocaloric Properties ◽  
Cryogenic Engineering ◽  
Significant Change ◽  
Curie Temperature Tc

Magnetocaloric properties of compounds Gd(Ni0.98Si0.02), Dy(Ni0.95Si0.05) and their hydrides Gd(Ni0.98Si0.02)H3, Dy(Ni0.95Si0.05)H4 were investigated in the temperature range 2 – 100K. It was found that partial substitution of Ni atoms by Si atoms, as well as subsequent hydrogenation can lead to a significant change in the Curie temperature (TC), the magnetocaloric effect, and the temperature at which the maximum MCE (Tmax) is observed. It is shown that the TC and Tmax of the hydrides are shifted by several degrees to the low temperature region with increasing or maintaining the MCE, which can significantly expand the application of such materials in cryogenic engineering.

scholarly journals Gaudefroyite: a mineral with excellent magnetocaloric effect suitable for liquefying hydrogen

2018 ◽  
Vol 6 (13) ◽  
pp. 5260-5264 ◽  
Author(s):  
Rukang Li ◽  
Guangjing Li ◽  
Colin Greaves
Keyword(s):  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Natural Mineral ◽  
Magnetocaloric Properties

A natural mineral, gaudefroyite, displays excellent low temperature magnetocaloric properties that are suitable for liquefying hydrogen.

Multiple magnetic transitions and magnetocaloric effect in hydrothermally synthesized single crystalline La0.5Sr0.5MnO3nanowires

2012 ◽  
Vol 1454 ◽  
pp. 63-68 ◽  
Author(s):  
Sayan Chandra ◽  
Anis Biswas ◽  
Subarna Datta ◽  
Barnali Ghosh ◽  
A.K. Raychaudhuri ◽  
...  
Keyword(s):  
Hydrothermal Synthesis ◽  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Room Temperature ◽  
Magnetic State ◽  
Double Exchange ◽  
Synthesis Process ◽  
Theoretical Studies ◽  
Magnetic Transitions ◽  
Magnetocaloric Properties

ABSTRACTWe have successfully prepared La0.5Sr0.5MnO3nanowires using a novel hydrothermal synthesis process and studied their magnetic and magnetocaloric properties. The system exhibits an inverse magnetocaloric effect (IMCE) around 175 K indicating presence of significant AFM correlation. The MCE study reveals a clear paramagnetic (PM) to ferromagnetic (FM) transition near room temperature (T ~ 325K) which is followed by onset of AFM at lower temperatures. The development of the FM-like magnetic state at low temperature is attributed to the enhanced double exchange (DE) driven ferromagnetism in AFM state as predicted by recent theoretical studies.

scholarly journals Low-Temperature Magnetocaloric Properties of V12 Polyoxovanadate Molecular Magnet: A Theoretical Study

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4399 ◽  
Author(s):  
Karol Szałowski
Keyword(s):  
Low Temperature ◽  
Magnetocaloric Effect ◽  
Computational Study ◽  
Thermodynamic Description ◽  
Entropy Change ◽  
Molecular Magnet ◽  
Thermodynamic Quantities ◽  
Magnetocaloric Properties ◽  
Adiabatic Magnetization ◽  
Quantities Of Interest

The paper presents a computational study of the magnetocaloric properties of the V12 polyoxovanadate molecular magnet. The description is restricted to low-temperature range (below approximately 100 K), where the magnetic properties of the system in question can be sufficiently modelled by considering a tetramer that consists of four vanadium ions with spins S=1/2. The discussion is focused on the magnetocaloric effect in the cryogenic range. The exact and numerical diagonalization of the corresponding Hamiltonian is used in order to construct the thermodynamic description within a version of the canonical ensemble. The thermodynamic quantities of interest, such as magnetic entropy, specific heat, entropy change under isothermal magnetization/demagnetization, temperature change under adiabatic magnetization/demagnetization, refrigerant capacity, and magnetic Grüneisen ratio, are calculated and discussed extensively. The importance of two quantum level crossings for the described properties is emphasized. The significant ranges of direct and inverse magnetocaloric effect are predicted. In particular, the maximized inverse magnetocaloric response is found for cryogenic temperatures.

Chemical disorder driven reentrant spin cluster glass state formation and associated magnetocaloric properties of Nd2Ni0.94Si2.94

2018 ◽  
Vol 20 (10) ◽  
pp. 7082-7092 ◽  
Author(s):  
Santanu Pakhira ◽  
Chandan Mazumdar ◽  
R. Ranganathan ◽  
S. Giri
Keyword(s):  
Intermetallic Compound ◽  
Magnetocaloric Effect ◽  
State Formation ◽  
Cluster State ◽  
Spin Cluster ◽  
Glass State ◽  
Magnetocaloric Properties ◽  
Chemical Disorder ◽  
Ternary Intermetallic Compound

We report the synthesis of a new ternary intermetallic compound Nd2Ni0.94Si2.94 that exhibits large magnetocaloric effect in the presence of reentrant spin cluster state formation.

scholarly journals Role of mechanical treatments in the formation of magnetocaloric properties of Gd melt spun ribbons

2020 ◽  
Author(s):  
A. V. Arkhipov ◽  
S. V. Andreev ◽  
D. S. Neznakhin ◽  
A. V. Tebenkov ◽  
A. Larrañaga ◽  
...  
Keyword(s):  
Magnetocaloric Properties ◽  
Melt Spun ◽  
Melt Spun Ribbons

scholarly journals Dissecting the Roles of Cuticular Wax in Plant Resistance to Shoot Dehydration and Low-Temperature Stress in Arabidopsis

2021 ◽  
Vol 22 (4) ◽  
pp. 1554
Author(s):  
Tawhidur Rahman ◽  
Mingxuan Shao ◽  
Shankar Pahari ◽  
Prakash Venglat ◽  
Raju Soolanayakanahally ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Low Temperature ◽  
Cold Acclimation ◽  
Water Loss ◽  
Cuticular Wax ◽  
Dehydration Stress ◽  
Wax Deposition ◽  
Cuticular Waxes ◽  
Gas Chromatography Mass Spectroscopy

Cuticular waxes are a mixture of hydrophobic very-long-chain fatty acids and their derivatives accumulated in the plant cuticle. Most studies define the role of cuticular wax largely based on reducing nonstomatal water loss. The present study investigated the role of cuticular wax in reducing both low-temperature and dehydration stress in plants using Arabidopsis thaliana mutants and transgenic genotypes altered in the formation of cuticular wax. cer3-6, a known Arabidopsis wax-deficient mutant (with distinct reduction in aldehydes, n-alkanes, secondary n-alcohols, and ketones compared to wild type (WT)), was most sensitive to water loss, while dewax, a known wax overproducer (greater alkanes and ketones compared to WT), was more resistant to dehydration compared to WT. Furthermore, cold-acclimated cer3-6 froze at warmer temperatures, while cold-acclimated dewax displayed freezing exotherms at colder temperatures compared to WT. Gas Chromatography-Mass Spectroscopy (GC-MS) analysis identified a characteristic decrease in the accumulation of certain waxes (e.g., alkanes, alcohols) in Arabidopsis cuticles under cold acclimation, which was additionally reduced in cer3-6. Conversely, the dewax mutant showed a greater ability to accumulate waxes under cold acclimation. Fourier Transform Infrared Spectroscopy (FTIR) also supported observations in cuticular wax deposition under cold acclimation. Our data indicate cuticular alkane waxes along with alcohols and fatty acids can facilitate avoidance of both ice formation and leaf water loss under dehydration stress and are promising genetic targets of interest.

The Role of Li2CO3and PbO in the Low-Temperature Sintering of Sr, K, Nb (SKN)-Doped PZT

2009 ◽  
Vol 92 (6) ◽  
pp. 1203-1207 ◽  
Author(s):  
Niall J. Donnelly ◽  
Thomas R. Shrout ◽  
Clive A. Randall
Keyword(s):  
Low Temperature ◽  
Low Temperature Sintering

Spin-Lattice Coupling and Peculiarities of Magnetic Behavior of Ferrimagnetic Ludwigites Mn0.52+M1.52+Mn3+BO5(M=Cu, Ni)

2015 ◽  
Vol 233-234 ◽  
pp. 133-136 ◽  
Author(s):  
Leonard Bezmaternykh ◽  
Evgeniya Moshkina ◽  
Evgeniy Eremin ◽  
Maxim Molokeev ◽  
Nikita Volkov ◽  
...  
Keyword(s):  
Temperature Field ◽  
Low Temperature ◽  
Magnetic Anisotropy ◽  
Single Crystals ◽  
Magnetic Behavior ◽  
Temperature Hysteresis ◽  
Spin Lattice ◽  
Field Magnetization ◽  
Lattice Coupling

Temperature-field and orientational magnetization dependences of single crystals were measured. Both samples demonstrate significant field-depending temperature hysteresis and low-temperature counter field magnetization. The correlation of orientational dependences of these effects and magnetic anisotropy is analyzed; the role of spin-lattice interactions is discussed.

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