scholarly journals Extraction of actinides by tertiary amines in room temperature ionic liquids: evidence for anion exchange as a major process at high acidity and impact of acid nature

RSC Advances ◽  
2015 ◽  
Vol 5 (45) ◽  
pp. 35821-35829 ◽  
Author(s):  
Seraj A. Ansari ◽  
Prasanta K. Mohapatra ◽  
Valérie Mazan ◽  
Isabelle Billard
Keyword(s):  
Ionic Liquids ◽  
Anion Exchange ◽  
Room Temperature ◽  
Exchange Mechanism ◽  
Room Temperature Ionic Liquids ◽  
Tertiary Amines ◽  
High Acidity ◽  
Alkyl Amines ◽  
Major Process ◽  
Acid Nature

The extraction of U(vi) and Pu(iv) by tri-alkyl amines in room temperature ionic liquids, [Cnmim][Tf2N] (where, n = 4, 6 or 8) follow anion exchange mechanism.

Mechanisms of Metal Ion Transfer into Room-Temperature Ionic Liquids:  The Role of Anion Exchange

2003 ◽  
Vol 125 (50) ◽  
pp. 15466-15473 ◽  
Author(s):  
Mark P. Jensen ◽  
Jörg Neuefeind ◽  
James V. Beitz ◽  
S. Skanthakumar ◽  
L. Soderholm
Keyword(s):  
Ionic Liquids ◽  
Anion Exchange ◽  
Metal Ion ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Ion Transfer

Conductivity of N-(2-methoxyethyl)-substituted morpholinium- and piperidinium-based ionic liquids and their acetonitrile solutions

2018 ◽  
Vol 11 (06) ◽  
pp. 1840009 ◽  
Author(s):  
Alena I. Komayko ◽  
Ekaterina A. Arkhipova ◽  
Anton S. Ivanov ◽  
Konstantin I. Maslakov ◽  
Stepan Yu. Kupreenko ◽  
...  
Keyword(s):  
Activation Energy ◽  
Ionic Liquids ◽  
Room Temperature ◽  
Correlation Spectroscopy ◽  
Charge Carriers ◽  
Room Temperature Ionic Liquids ◽  
Tertiary Amines ◽  
Mobility Of Charge Carriers ◽  
Acetonitrile Solutions ◽  
Three Stages

N-ethyl-N-(2-methoxyethyl)-morpholinium bis(trifluoromethylsulfonyl)imide [Et(MEO)Mor][TFSI], N,N-bis(2-methoxyethyl)-morpholinium bis(trifluoromethylsulfonyl)imide [Bis(MEO)Mor][TFSI] and N,N-bis(2-methoxyethyl)-piperidinium bis(trifluoromethylsulfonyl)imide [Bis(MEO)Pip][TFSI] room-temperature ionic liquids (RTILs) were synthesized and their electrochemical properties were studied. Three stages of synthesis of RTILs were used, including the alkylation of secondary and tertiary amines and the anion exchange. The structure of RTILs was confirmed by 1H, [Formula: see text]C, H,H-COSY, 1H–[Formula: see text]C correlation spectroscopy NMR and XPS. Three main approaches based on the Arrhenius, Litovitz, and Vogel–Fulcher–Tammann equations were used to analyze the ion transport properties of RTILs. In addition, the electrical conductivity of the binary acetonitrile solutions of RTILs was studied. It was found that the activation energy and conductivity of RTILs depended on their polarity and ability to associate which affects the mobility of charge carriers and viscosity of the system.

scholarly journals Structure and dynamics of room temperature ionic liquids with bromide anion: results from 81 Br NMR spectroscopy

2015 ◽  
Vol 53 (5) ◽  
pp. 369-378 ◽  
Author(s):  
Takatsugu Endo ◽  
Mamoru Imanari ◽  
Yuki Hidaka ◽  
Hiroko Seki ◽  
Keiko Nishikawa ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Nmr Spectroscopy ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Bromide Anion ◽  
Structure And Dynamics

15N NMR studies provide insights into physico-chemical properties of room-temperature ionic liquids

2021 ◽  
Author(s):  
Christoph Wiedemann ◽  
David Fushman ◽  
Frank Bordusa
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Chemical Properties ◽  
Room Temperature Ionic Liquids ◽  
15N Nmr ◽  
Nmr Studies ◽  
Physico Chemical ◽  
Alternative Solvents

Ionic liquids (ILs) have gained a lot of attention as alternative solvents in many fields of science in the last two decades. It is known that the type of anion...

Sign in / Sign up

Export Citation Format

Share Document