Crosslinked inter penetrating network of sulfonated styrene and sulfonated PVdF-co-HFP as electrolytic membrane in a single chamber microbial fuel cell

RSC Advances ◽  
2015 ◽  
Vol 5 (39) ◽  
pp. 30758-30767 ◽  
Author(s):  
Vikash Kumar ◽  
Piyush Kumar ◽  
Arpita Nandy ◽  
Patit Paban Kundu

In the present study, semi-IPN membranes of sulfonated styrene (SS) and sulfonated PVdF-co-HFP membranes have been analyzed as a polymer electrolyte membrane in single chamber microbial fuel cells (MFCs).

2014 ◽  
Vol 4 (5) ◽  
pp. 1400-1406 ◽  
Author(s):  
Yuta Nabae ◽  
Mayu Sonoda ◽  
Chiharu Yamauchi ◽  
Yo Hosaka ◽  
Ayano Isoda ◽  
...  

A Pt-free cathode catalyst for polymer electrolyte membrane fuel cells has been developed by multi-step pyrolysis of Fe phthalocyanine and phenolic resin and shows a quite promising fuel cell performance.


Author(s):  
Erman Çelik ◽  
İrfan Karagöz

Polymer electrolyte membrane fuel cells are carbon-free electrochemical energy conversion devices that are appropriate for use as a power source on vehicles and mobile devices emerging with their high energy density, lightweight structure, quick startup and lower operating temperature capabilities. However, they need more developments in the aspects of reactant distribution, less pressure drops, precisely balanced water content and heat management to achieve more reliable and higher overall cell performance. Flow field development is one of the most important fields of study to increase cell performance since it has decisive effects on performance parameters, including bipolar plate, and thus fuel cell weight. In this study, recent developments on conventional flow field designs to eliminate their weaknesses and innovative design approaches and flow field architectures are obtained from patent databases, and both numerical and experimental scientific studies. Fundamental designs that create differences are introduced, and their effects on the performance are discussed with regard to origin, objective, innovation strategy of design besides their strength and probable open development ways. As a result, significant enhancements and design strategies on flow field designs in polymer electrolyte membrane fuel cells are summarized systematically to guide prospective flow field development studies.


Author(s):  
Yeping Peng ◽  
Ghasem Bahrami ◽  
Hossein Khodadadi ◽  
Alireza Karimi ◽  
Ahmad Soleimani ◽  
...  

Purpose The purpose of this study is simulation of of polymer electrolyte membrane fuel cell. Proton-exchange membrane fuel cells are promising power sources for use in power plants and vehicles. These fuel cells provide a high level of energy efficiency at low temperature without any pollution. The convection inside the cell plays a key role in the electrochemical reactions and the performance of the cell. Accordingly, the transport processes in these cells have been investigated thoroughly in previous studies that also carried out functional modeling. Design/methodology/approach A multi-phase model was used to study the limitations of the reactions and their impact on the performance of the cell. The governing equations (conservation of mass, momentum and particle transport) were solved by computational fluid dynamics (CFD) (ANSYS fluent) using appropriate source terms. The two-phase flow in the fuel cell was simulated three-dimensionally under steady-state conditions. The flow of water inside the cell was also simulated at high-current density. Findings The simulation results suggested that the porosity of the gas diffusion layer (GDL) is one of the most important design parameters with a significant impact on the current density limitation and, consequently, on the cell performance. Originality/value This study was mainly focused on the two-phase analysis of the steady flow in the fuel cell and on investigating the impacts of a two-phase flow on the performance of the cell and also on the flow in the GDL, the membrane and the catalyst layer using the CFD.


Author(s):  
Thomas A. Trabold

This paper provides an overview of the application of minichannels, typically on the order of 1 mm hydraulic diameter, in the design of polymer electrolyte membrane (PEM) fuel cells. In these electrochemical devices, minichannels deliver reactant hydrogen and oxygen to the anode and cathode electrodes, respectively, while transporting product water out of the cell. The channels must be designed for low pressure drop, to avoid excessive parasitic power losses from gas handling equipment. However, the channels also need to operate in a flow regime in which the overall water balance in the fuel cell can be maintained. The various aspects of minichannel design, including size and cross-sectional shape, are discussed, with particular emphasis on fuel cell water management. In addition to reviewing these fundamental aspects of minichannel design, examples are given of new experimental tools currently under development which are applied to relate channel water transport and accumulation to fuel cell performance.


Sign in / Sign up

Export Citation Format

Share Document