A porous cobalt-based MOF with high CO2 selectivity and uptake capacity

RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29505-29508 ◽  
Author(s):  
Liting Du ◽  
Zhiyong Lu ◽  
Mengtao Ma ◽  
Fan Su ◽  
Li Xu
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Co2 ◽  
Self Assembling ◽  
Metal Organic ◽  
Co2 Selectivity ◽  
Organic Framework

A porous cobalt-based metal–organic framework [CoL2−]n has been designed by self-assembling [Co2(COO)4] paddlewheel SBUs and a novel trigonal hetero–functional ligand. [CoL2−]n exhibits large CO2 uptake and selectivity.

scholarly journals MIL-91(Ti), a small pore metal–organic framework which fulfils several criteria: an upscaled green synthesis, excellent water stability, high CO2 selectivity and fast CO2 transport

2016 ◽  
Vol 4 (4) ◽  
pp. 1383-1389 ◽  
Author(s):  
Virginie Benoit ◽  
Renjith S. Pillai ◽  
Angelica Orsi ◽  
Périne Normand ◽  
Hervé Jobic ◽  
...  
Keyword(s):  
Green Synthesis ◽  
Metal Organic Framework ◽  
Water Stability ◽  
High Co2 ◽  
Co2 Transport ◽  
Small Pore ◽  
Metal Organic ◽  
Co2 Selectivity ◽  
Organic Framework

MIL-91(Ti) is shown to be one of the very few MOFs of real interest for CO2 capture.

High CO2 Uptake Capacity and Selectivity in a Fascinating Nanotube-Based Metal–Organic Framework

2016 ◽  
Vol 56 (2) ◽  
pp. 908-913 ◽  
Author(s):  
Yun-Long Wu ◽  
Jinjie Qian ◽  
Guo-Ping Yang ◽  
Fan Yang ◽  
Yu-Tong Liang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co2 Uptake ◽  
Uptake Capacity ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

scholarly journals A Rationally Designed Nitrogen-Rich Metal-Organic Framework and Its Exceptionally High CO2 and H2 Uptake Capability

2013 ◽  
Vol 3 (1) ◽  
Author(s):  
Xiao-Jun Wang ◽  
Pei-Zhou Li ◽  
Yifei Chen ◽  
Quan Zhang ◽  
Huacheng Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
High Co2 ◽  
Metal Organic ◽  
Organic Framework

A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

CrystEngComm ◽  
2019 ◽  
Vol 21 (24) ◽  
pp. 3679-3685 ◽  
Author(s):  
Donghai Sheng ◽  
Ying Zhang ◽  
Yang Han ◽  
Guang Xu ◽  
Qingxiang Song ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Affinity ◽  
Metal Organic ◽  
Organic Framework

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]·(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity.

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