Inorganic nano-adsorbents for the removal of heavy metals and arsenic: a review

RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 29885-29907 ◽  
Author(s):  
Phoebe Zito Ray ◽  
Heather J. Shipley
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Removal Of Heavy Metals ◽  
Inorganic Adsorbents ◽  
Heavy Metals And Arsenic

Schematic of inorganic adsorbents (INA) for heavy metal removal.

Heavy metal removal from wastewater and leachate co-treatment sludge by sulfur oxidizing bacteria

2001 ◽  
Vol 44 (10) ◽  
pp. 53-58 ◽  
Author(s):  
L. C. Aralp ◽  
A. Erdincler ◽  
T. T. Onay
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Municipal Wastewater ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Heavy Metal Concentration ◽  
Organic Content ◽  
Removal Of Heavy Metals ◽  
Sulfur Oxidizing ◽  
Sulfur Oxidizing Bacteria

Heavy metal concentration in sludge is one of the major obstacles for the application of sludge on land. There are various methods for the removal of heavy metals in sludge. Using sulfur oxidizing bacteria for microbiological removal of heavy metals from sludges is an outstanding option because of high metal solubilization rates and the low cost. In this study, bioleaching by indigenous sulfur oxidizing bacteria was applied to sludges generated from the co-treatment of municipal wastewater and leachate for the removal of selected heavy metals. Sulfur oxidizing bacteria were acclimated to activated sludge. The effect of the high organic content of leachate on the bioleaching process was investigated in four sets of sludges having different concentrations of leachate. Sludges in Sets A, B, C and D were obtained from co-treatment of wastewater and 3%, 5%, 7% and 10% (v/v) leachate respectively. The highest Cr, Ni and Fe solubilization was obtained from Set A. Sulfur oxidizing bacteria were totally inhibited in Set D that received the highest volume of leachate.

scholarly journals Heavy metal removal from wastewater using various adsorbents: a review

2016 ◽  
Vol 7 (4) ◽  
pp. 387-419 ◽  
Author(s):  
Renu ◽  
Madhu Agarwal ◽  
K. Singh
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Aquatic Ecosystems ◽  
Adsorption Process ◽  
Metal Removal ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Review Article ◽  
Removal Capacity ◽  
Removal Of Heavy Metals

Heavy metals are discharged into water from various industries. They can be toxic or carcinogenic in nature and can cause severe problems for humans and aquatic ecosystems. Thus, the removal of heavy metals from wastewater is a serious problem. The adsorption process is widely used for the removal of heavy metals from wastewater because of its low cost, availability and eco-friendly nature. Both commercial adsorbents and bioadsorbents are used for the removal of heavy metals from wastewater, with high removal capacity. This review article aims to compile scattered information on the different adsorbents that are used for heavy metal removal and to provide information on the commercially available and natural bioadsorbents used for removal of chromium, cadmium and copper, in particular.

Wastewater Treatment in Removal of Heavy Metals

2019 ◽  
pp. 220-240
Author(s):  
Tehseen Yaseen ◽  
Anum Yaseen
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
New Process ◽  
Removal Of Heavy Metals ◽  
Treatment Technologies ◽  
Growing Economy ◽  
Nano Science

Nanotechnology is the area of nano science that shows great potential to establish a new process for wastewater treatment. It has been applied on a nanometer scale level. Currently, limited water resources and real treatment of wastewater is a chief requirement for the growing economy. It is in great demand to introduce the progressive wastewater treatment technologies. Therefore, the modern innovative processes in nanomaterial sciences have been appealing the target of scientists. The chapter addresses the developments in nanotechnology with respect to wastewater treatment, especially the removal of heavy metals and to the environmental applications. It will discuss the application of different classes of nanomaterials for wastewater treatment in removal of heavy metals and its possible effects to the environment. Therefore, the scope is to offer an overview of how nanomaterials are causing concerns related to heavy metal removal for water and in the surrounding environment.

Removal of heavy metals using a wetland batch system with Carrizo (Phragmites Australis)

2020 ◽  
Author(s):  
Maribel Guzman ◽  
Maggy Romero ◽  
Michael Flores ◽  
Sebastian Bravo
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Phragmites Australis ◽  
Mine Drainage ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Ammonia Nitrogen ◽  
Abandoned Mines ◽  
Slight Variation ◽  
Removal Of Heavy Metals

Abstract One of the greatest environmental issues related to the development of the mining activity is the generation of Acid Mine Drainage (AMD). This effluent generated by active and abandoned mines in Peru produces multiple discussions about the role of the industry for a sustainable development. Many methods have been developed for AMD treatment, being wetlands a good option for heavy metal removal. In this sense, removal of heavy metal by using laboratory constructed wetlands with Phragmites Australis was studied. During a 9-day period the variation of different physicochemical parameters and heavy metals concentrations was recorded. The pH decreased to a constant value of 8.24 after the sixth day. The electrical conductivity presented a slight variation from 1 to 1.33 µS cm-1 on the ninth day. Moreover, fluctuating values of Dissolved Oxygen and Turbidity were observed. A reduction between 69% and 93% of ammonia nitrogen (NH3-N) was registered. Cu concentration was reduced in 68% and 87%; Zn concentrations dropped in 53% and 95%; and Pb was reduced in 20% and 55%. It was concluded that Phragmites Australis can be an alternative in the treatment of the contaminants produced by AMD.

Low Cost Absorbents, Techniques, and Heavy Metal Removal Efficiency

2018 ◽  
pp. 50-79
Author(s):  
Harendra Kumar Sharma ◽  
Irfan Rashid Sofi ◽  
Khursheed Ahmad Wani
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Metal Removal ◽  
Low Cost ◽  
Heavy Metal Removal ◽  
Future Research ◽  
Removal Of Heavy Metals ◽  
Living Species ◽  
High Concentrations

Heavy metal contamination in water is a serious concern to the environment and human health. High concentrations of heavy metals in the environment can be toxic to a variety of living species. Natural bio-absorbents are abundant and inexpensive and considered a waste if not managed properly. The role of bio-absorbents has been widely studied and has been utilized for the removal of heavy metals. The objective of the chapter is to search the database for different absorbents and their efficiency for the removal of heavy metals. Key words related to the study have been used to select different papers published by the researchers all over the world. A rigorous three-tier process has been utilized by the authors to select the papers from the database for the current study. This chapter has identified a few research gaps in the field of heavy metal removal by using different low cast absorbents that need to be taken into account in future research.

scholarly journals Magnetic Hydroxyapatite for Batch Adsorption of Heavy Metals

2021 ◽  
Vol 287 ◽  
pp. 04005
Author(s):  
Khee Chung Hui ◽  
Norashikin Ahmad Kamal ◽  
Nonni Soraya Sambudi ◽  
Muhammad Roil Bilad
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Removal ◽  
Aqueous Media ◽  
Heavy Metal Removal ◽  
Calcium Nitrate ◽  
Chemical Precipitation ◽  
Batch Adsorption ◽  
Calcium Nitrate Tetrahydrate ◽  
Removal Of Heavy Metals

In this work, magnetic hydroxyapatite or hydroxyapatite-iron (III) oxide (HAp-Fe3O4) composite was used as the adsorbent of heavy metals and the performance was evaluated using the batch test. The presence of heavy metals in the effluent from wastewater discharge can be toxic to many organisms and can even lead to eye burns. Therefore, hydroxyapatite synthesized from the chemical precipitation of calcium nitrate tetrahydrate and diammonium hydrogen phosphate solutions is used to remove heavy metal in aqueous media. Magnetic properties of Fe3O4 can help prevent formation of secondary pollutants caused by the loss of adsorbent. The synthesized HAp-Fe3O4 can remove cadmium, zinc and lead effectively, which is up to 90% removal. Reusability study shows that the adsorbent could retain heavy metal ions even after four cycles. The percentage removal of heavy metals maintains at around 80% after four times of usage. The composite of HAp-Fe3O4 demonstrates good performance and stability which is beneficial for heavy metal removal in the future.

Removal of Heavy Metals from Aqueous Solution Using Rhizopus delemar Mycelia in Free and Polyurethane-Bound Form

2002 ◽  
Vol 57 (7-8) ◽  
pp. 629-633 ◽  
Author(s):  
Kolishka Tsekova ◽  
Galin Petrov
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Polyurethane Foam ◽  
Metal Removal ◽  
Immobilized Cells ◽  
Copper Ions ◽  
Heavy Metal Removal ◽  
Mixed Solution ◽  
Rhizopus Delemar ◽  
Removal Of Heavy Metals

This study assesses the ability of mycelia of Rhizopus delemar (both free and immobilized on polyurethane foam) to remove heavy metals from single-ion solutions as well as from a mixture of them. All experiments were conducted using 0.5-5 mm solutions of CuSO4·5H2O, CoCl2·6H2O and FeSO4·7H2O. Mycelia immobilized on polyurethane foam cells showed some times increase in uptake compared with that of free cells. Metal ions accumulation from a mixed solution was decreased slightly for cobalt and iron and considerable for copper ions. Heavy metal uptake was examined in the immobilized column experiments and more than 92% heavy metal removal (mg heavy metals removed/mg heavy metals added) from a mixed solution was achieved during the 5 cycles. During these experiments, the dry weight of the immobilized cells was decreased by only 2%. These results showed that immobilized mycelia of Rhizopus delemar can be used repeatedly for removal of heavy metals from aqueous solutions.

scholarly journals Efficient removal of heavy metals from melting effluent using multifunctional hydrogel adsorbents

2018 ◽  
Vol 78 (4) ◽  
pp. 982-990 ◽  
Author(s):  
Jianhong Ma ◽  
Yuanmeng Zhang ◽  
Yanhong Tang ◽  
Yuanfeng Wei ◽  
Yutang Liu ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Mechanical Strength ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
High Water ◽  
Poly Vinyl Alcohol ◽  
Removal Of Heavy Metals ◽  
Cross Linkage ◽  
Removal Efficiencies

Abstract It is hard to balance high water permeability and good mechanical strength of hydrogel adsorbents. In this study, an enhanced double network hydrogel adsorbent of poly (vinyl alcohol)/poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PVA/PAMPS) was prepared via simple free-radical polymerization. Hydrophilic PAMPS guaranteed high swellability of the adsorbent, which made the sufficient diffusion of metal ions towards adsorbent inside. Meanwhile, the cross-linkage between PVA and PAMPS chains ensured good mechanical strength of the adsorbent. Significantly, the introduction of multifunctional groups (-NHR, -SO3H and -OH) endowed the adsorbent with both chelation and ion exchange function for enhancing heavy metal adsorption. The maximum adsorption capacities of Pb2+ and Cd2+ reached 340 and 155.1 mg/g, respectively. The adsorbent could efficiently remove heavy metals in melting effluent, especially Pb2+ and Cd2+. The removal efficiencies reached 88.1% for Pb2+, 91.4% for Cd2+, 70.4% for Zn2+, 77.4% for Cu2+, 42.5% for Mn2+, 45.1% for Ni2+ and 95.4% for Fe3+ using 2 g/L adsorbent in 2 h. Moreover, the adsorbent showed a good reusability, and the removal efficiencies maintained 94% for Pb2+ and 93% for Cd2+ in the fifth cycle (m/V = 1 g dry gel/L). This work developed a highly practical hydrogel adsorbent for heavy metal removal from wastewater.

scholarly journals Removal of Heavy Metals during Primary Treatment of Municipal Wastewater and Possibilities of Enhanced Removal: A Review

Water ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1121
Author(s):  
Sylwan Ida ◽  
Thorin Eva
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Municipal Wastewater ◽  
Metal Removal ◽  
Metal Speciation ◽  
Heavy Metal Removal ◽  
Primary Treatment ◽  
Metal Concentrations ◽  
Heavy Metal Concentrations ◽  
Removal Of Heavy Metals

Resource reuse has become an important aspect of wastewater management. At present, use of sludge in agriculture is one of the major reuse routes. Conventional municipal wastewater treatment does not involve any designated process for removal of heavy metals, and these distribute mainly between effluent and sludge. Enhanced removal of heavy metals during primary treatment may decrease the heavy metal concentrations in both effluent and sludge from secondary treatment and promote long-term reuse of secondary sludge. This review considers heavy metal occurrence and removal during primary settling, together with possible treatment technologies for heavy metal removal in primary settlers and their theoretical performance. The variation in total heavy metal concentrations and dissolved fraction in raw municipal wastewater points to a need for site-specific assessments of appropriate technologies for improved heavy metal removal. Studies examining the heavy metal speciation beyond dissolved/particulate are few. Missing or disparate information on process parameters such as hydraulic retention time, pH and composition of return flows makes it hard to generalize the findings from studies concerning heavy metal removal in primary settlers. Coagulation/flocculation and use of low-cost sorbents were identified as the most promising methods for enhancing heavy metal removal during primary settling. Based on the available data on heavy metal speciation and removal during primary settling, sorption technologies may be most effective for enhancing the removal of Cu and Ni, while coagulation may be efficient for Cd, Cr, Cu, Pb, Zn and Hg removal (but not as efficient for Ni removal).

scholarly journals Removal of Heavy Metals from Wastewater Using Novel Polydopamine-Modified CNTs-Based Composite Membranes

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2120
Author(s):  
Faizah Altaf ◽  
Shakeel Ahmed ◽  
Muhammad Usman ◽  
Tahira Batool ◽  
Jaweria Shamshad ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Composite Membranes ◽  
Low Concentrations ◽  
Removal Of Heavy Metals ◽  
Removal Efficiencies ◽  
Immense Potential ◽  
Maximum Removal

The presence of major heavy metals including Pb2+, Cu2+, Co2+, Ni2+, Hg2+, Cr6+, Cd2+, and Zn2+ in water is of great concern because they cannot degrade or be destroyed. They are toxic even at very low concentrations. Therefore, it is necessary to remove such toxicants from water. In the current study, polydopamine carbon nanotubes (PD-CNTs) and polysulfone (PS) composite membranes were prepared. The structural and morphological features of the prepared PDCN composite membranes were studied using FTIR, XRD, SEM, and EDS. The potential application of PDCNs for heavy metal removal was studied for the removal of Pb2+, Cr6+, and Cd2+ from wastewater. The maximum removal efficiency of 96.1% was obtained for Cr6+ at 2.6 pH using a composite membrane containing 1.0% PD-CNTs. The removal efficiencies decreased by 64.1 and 73.4, respectively, by enhancing the pressure from 0.50 up to 0.85 MPa. Under the same circumstances, the percentages of Pb+2 removal at 0.49 bar by the PDCNS membranes containing 0.5% and 1.0% PD-CNT were 70 and 90.3, respectively, and decreased to 54.3 and 57.0, respectively, upon increasing the pressure to 0.85 MPa. The results showed that PDCNS membranes have immense potential for the removal of heavy metals from water.

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