Ionic liquid functionalization – an effective way to tune carbon dioxide adsorption properties of carbon nanotubes

RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 35098-35106 ◽  
Author(s):  
P. Tamilarasan ◽  
S. Ramaprabhu

In this research, the influence of non-covalent functionalization by ionic liquids on carbon dioxide (CO2) adsorption–desorption properties of multi-walled carbon nanotubes (MWNTs) and partially exfoliated MWNTs (PEMWNTs) has been studied.

RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43526-43538 ◽  
Author(s):  
Haoyuan Ding ◽  
Rongfeng Chen ◽  
Mingming Liu ◽  
Rong Huang ◽  
Yamei Du ◽  
...  

A series of novel biocompatible MIPs were synthesized for BSA recognition by using MWCNTs with different outside diameters as substrates, and allyl-functionalized ionic liquids with different anion species as monomers.


RSC Advances ◽  
2014 ◽  
Vol 4 (82) ◽  
pp. 43436-43443 ◽  
Author(s):  
A. C. Kleinschmidt ◽  
R. K. Donato ◽  
M. Perchacz ◽  
H. Beneš ◽  
V. Štengl ◽  
...  

Ionic liquid enables a straightforward procedure for the preparation of high quality graphene by opening multi-walled carbon nanotubes.


Membranes ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 481
Author(s):  
Daniel Polak ◽  
Izabela Zielińska ◽  
Maciej Szwast ◽  
Igor Kogut ◽  
Artur Małolepszy

The aim of this work is to develop a new type of carbon-ceramic membranes for the removal of pharmaceutical substances from water. The membranes were prepared by the chemical modification method using an organosilicon precursor—octadecyltrichlorosilane (ODTS). Graphene oxide, multi-walled carbon nanotubes with carboxylic groups, and single-walled carbon nanotubes were used in the modification process. The filtration properties and adsorption properties of the developed membranes were tested. In order to characterize the membrane, the water permeability, the change of the permeate flux in time, and the adsorbed mass of the substance were determined. Additionally, the surface properties of the membranes were characterized by contact angle measurements and porosimetry. The antibiotic tetracycline was used in the adsorption tests. Based on the results, the improved adsorption properties of the modified membrane in relation to the unmodified membrane were noticed. Novel ceramic membranes modified with MWCNT are characterized by 45.4% removal of tetracycline and permeate flux of 520 L·h·m−2·bar−1. We demonstrated the ability of modified membranes to adsorb pharmaceuticals from water streams that are in contact with the membrane. Novel membranes retain their filtration properties. Therefore, such membranes can be used in an integrated filtration–adsorption process.


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