Heterogeneous Fenton catalysts for the abatement of organic pollutants from aqueous solution: a review

RSC Advances ◽  
2015 ◽  
Vol 5 (51) ◽  
pp. 40552-40577 ◽  
Author(s):  
P. V. Nidheesh

Fenton processes have gained much attention in the field of wastewater treatment during recent years.

2016 ◽  
Vol 1 (1) ◽  
pp. 1 ◽  
Author(s):  
Abhilasha Jain ◽  
Marazban Kotwal ◽  
Saima Khan

Advanced Oxidation Processes (AOPs) have emerged as a promising technology for the treatment of wastewaters containing toxic, recalcitrant organic compounds such as dyes, pesticides etc. This review paper focuses on the Fenton and photo- Fenton technique which is one of the most efficient AOPs developed to decolorize and/or degrade organic pollutants. This oxidation method can produce biodegradable intermediates and mineralize complex organic pollutants effectively and efficiently. In this paper Fenton and photo-Fenton methods are categorised into two broad groups as homogeneous and heterogeneous Fenton and photo-Fenton processes. Applications of fundamental and advanced combined Fenton and photo-Fenton processes are also discussed.


Author(s):  
Jiwei Zhang ◽  
Jingjing Xu ◽  
Shuaixia Liu ◽  
Baoxiang Gu ◽  
Feng Chen ◽  
...  

Background: Coal gangue was used as a catalyst in heterogeneous Fenton process for the degradation of azo dye and phenol. The influencing factors, such as solution pH gangue concentration and hydrogen peroxide dosage were investigated, and the reaction mechanism between coal gangue and hydrogen peroxide was also discussed. Methods: Experimental results showed that coal gangue has the ability to activate hydrogen peroxide to degrade environmental pollutants in aqueous solution. Under optimal conditions, after 60 minutes of treatment, more than 90.57% of reactive red dye was removed, and the removal efficiency of Chemical Oxygen Demand (COD) up to 72.83%. Results: Both hydroxyl radical and superoxide radical anion participated in the degradation of organic pollutant but hydroxyl radical predominated. Stability tests for coal gangue were also carried out via the continuous degradation experiment and ion leakage analysis. After five times continuous degradation, dye removal rate decreased slightly and the leached Fe was still at very low level (2.24-3.02 mg L-1). The results of Scanning Electron Microscope (SEM), energy dispersive X-Ray Spectrometer (EDS) and X-Ray Powder Diffraction (XRD) indicated that coal gangue catalyst is stable after five times continuous reuse. Conclusion: The progress in this research suggested that coal gangue is a potential nature catalyst for the efficient degradation of organic pollutant in water and wastewater via the Fenton reaction.


Author(s):  
Manoj Kumar Panjwani ◽  
Qing Wang ◽  
Yueming Ma ◽  
Yuxuan Lin ◽  
Feng Xiao ◽  
...  

The development of a heterogeneous Fenton-like catalyst, possessing high degradation efficiency in a wide pH range, is crucial for wastewater treatment. The Fe-Mn-SiO2 catalyst was designed, and prepared by a...


Author(s):  
Huchuan Yan ◽  
Cui Lai ◽  
Dongbo Wang ◽  
Shiyu Liu ◽  
Xiaopei Li ◽  
...  

Refractory organic pollutants in wastewater have the characteristics of persistence and toxicity, which seriously threaten the health and safety of humans and other organisms. Many researchers have committed to developing...


Author(s):  
Victoria Teniola Adeleke ◽  
Adebayo A Adeniyi ◽  
David Lokhat

Availability of clean water for various activities is a global challenge. Moringa oleifera (MO) seed protein extract has been identified as a natural coagulant for wastewater treatment. The mechanistic understanding...


Author(s):  
Jakub Zdarta ◽  
Katarzyna Jankowska ◽  
Karolina Bachosz ◽  
Oliwia Degórska ◽  
Karolina Kaźmierczak ◽  
...  

Abstract Purpose of Review In the presented review, we have summarized recent achievements on the use of immobilized oxidoreductases for biodegradation of hazardous organic pollutants including mainly dyes, pharmaceuticals, phenols, and bisphenols. In order to facilitate process optimization and achievement of high removal rates, effect of various process conditions on biodegradation has been highlighted and discussed. Recent Findings Current reports clearly show that immobilized oxidoreductases are capable of efficient conversion of organic pollutants, usually reaching over 90% of removal rate. Further, immobilized enzymes showed great recyclability potential, allowing their reuse in numerous of catalytic cycles. Summary Collected data clearly indicates immobilized oxidoreductases as an efficient biocatalytic tools for removal of hazardous phenolic compounds, making them a promising option for future water purification. Data shows, however, that both immobilization and biodegradation conditions affect conversion efficiency; therefore, process optimization is required to achieve high removal rates. Nevertheless, we have demonstrated future trends and highlighted several issues that have to be solved in the near-future research, to facilitate large-scale application of the immobilized oxidoreductases in wastewater treatment.


RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10300-10308
Author(s):  
Hui Feng ◽  
Siqi Feng ◽  
Niu Tang ◽  
Songbai Zhang ◽  
Xiangyang Zhang ◽  
...  

New idea for the low cost synthesis of high performance photocatalysts for the photodegradation of organic pollutants in aqueous solution.


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