Synthesis and properties of a nano-silica modified environmentally friendly polyurethane adhesive

RSC Advances ◽  
2015 ◽  
Vol 5 (56) ◽  
pp. 44990-44997 ◽  
Author(s):  
Guo Jia-Hu ◽  
Liu Yu-Cun ◽  
Chai Tao ◽  
Jing Su-Ming ◽  
Ma Hui ◽  
...  

In this study, a nano-SiO2 modified waterborne polyurethane (WPU) adhesive with remarkably low VOC content and high adhesion performance was successfully synthesized via in situ polymerization.

2016 ◽  
Vol 30 (1) ◽  
pp. 107-120 ◽  
Author(s):  
Han Yan-ting ◽  
Cheng Zheng ◽  
Dong Wei ◽  
Zhang Fan ◽  
Xin Zhong-yin

The waterborne polyurethane/nano-silica composites (WPU/nano-silica, WPUS) and WPU composites modified by polyethersiloxanediol (WPUPES) were prepared, respectively. The properties of WPUS and WPUPES were investigated by various characterizations. The results showed both WPUS and WPUPES had better waterproof property and thermal stability than neat WPU. However, WPUPES has a lower elongation at break due to the higher micro-phase separation. This is ascribed to migration and aggregation of siloxane segments during the film formation. The tensile strength of WPUS was higher than that of neat WPU. This is attributed to the WPUS chain restriction caused by the network and physical cross-link points of nano-silica particles. Moreover, the glass transition temperature of WPUS shifted to higher temperature region while that of WPUPES shifted to lower temperature region.


RSC Advances ◽  
2016 ◽  
Vol 6 (79) ◽  
pp. 75440-75448 ◽  
Author(s):  
Suli Chen ◽  
Tao Jin ◽  
Wenling Wu ◽  
Guanghui Zhao

Superparamagnetic nanocomposite films based on waterborne polyurethane and hollow Ni0.3Zn0.5Fe2O4 nanospheres (WPU/h-NZFO) were synthesized via an in situ polymerization technique.


Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Bing ◽  
Faming Wang ◽  
Yuhuan Sun ◽  
Jinsong Ren ◽  
Xiaogang Qu

An environmentally friendly biomimetic strategy has been presented and validated for the catalytic hydrogenation reaction in live bacteria. In situ formed ultra-fine metal nanoparticles can realize highly efficient asymmetric hydrogenation reactions.


Cellulose ◽  
2021 ◽  
Author(s):  
Julen Vadillo ◽  
Izaskun Larraza ◽  
Tamara Calvo-Correas ◽  
Nagore Gabilondo ◽  
Christophe Derail ◽  
...  

2019 ◽  
Vol 41 (2) ◽  
pp. 573-584 ◽  
Author(s):  
Yuanbin Ma ◽  
Hui He ◽  
Bai Huang ◽  
Huaishuai Jing ◽  
Zijin Zhao

RSC Advances ◽  
2020 ◽  
Vol 10 (58) ◽  
pp. 35480-35489 ◽  
Author(s):  
Xianlong Cao ◽  
Quanyou Ren ◽  
Youkun Yang ◽  
Xianglong Hou ◽  
Yongbo Yan ◽  
...  

A nesquehonite protective film with high corrosion resistance was prepared on pure Mg via a new environmentally-friendly in situ carbonation route.


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