Effect of migration of layered nanoparticles during melt blending on the phase morphology of poly (ethylene terephthalate)/polyamide 6/montmorillonite ternary nanocomposites

RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 29924-29930 ◽  
Author(s):  
Guomin Xu ◽  
Shuhao Qin ◽  
Jie Yu ◽  
Yifu Huang ◽  
Mingqiu Zhang ◽  
...  
Keyword(s):  
Polymer Blends ◽  
Ethylene Terephthalate ◽  
Great Influence ◽  
Polyamide 6 ◽  
Phase Morphology ◽  
Melt Blending ◽  
Melt Compounding ◽  
Poly Ethylene Terephthalate ◽  
Selective Localization ◽  
Poly Ethylene

Migration and selective localization of layered nanoparticles during melt compounding have great influence on phase morphology of polymer blends.

Poly(ethylene terephthalate)(PET) nanocomposites filled with fumed silicas by melt compounding

2002 ◽  
Vol 10 (4) ◽  
pp. 221-229 ◽  
Author(s):  
Su-Chul Chung ◽  
Wan-Gyu Hahm ◽  
Seung-Soon Im ◽  
Seong-Geun Oh
Keyword(s):  
Ethylene Terephthalate ◽  
Melt Compounding ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene

scholarly journals Effects of Phase Morphology on Mechanical Properties: Oriented/Unoriented PP Crystal Combination with Spherical/Microfibrillar PET Phase

Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 248 ◽  
Author(s):  
Dashan Mi ◽  
Yingxiong Wang ◽  
Maja Kuzmanovic ◽  
Laurens Delva ◽  
Yixin Jiang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Ethylene Terephthalate ◽  
Phase Morphology ◽  
Mechanical Recycling ◽  
Immiscible Blends ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene ◽  
The Impact

In situ microfibrillation and multiflow vibrate injection molding (MFVIM) technologies were combined to control the phase morphology of blended polypropylene (PP) and poly(ethylene terephthalate) (PET), wherein PP is the majority phase. Four kinds of phase structures were formed using different processing methods. As the PET content changes, the best choice of phase structure also changes. When the PP matrix is unoriented, oriented microfibrillar PET can increase the mechanical properties at an appropriate PET content. However, if the PP matrix is an oriented structure (shish-kebab), only the use of unoriented spherical PET can significantly improve the impact strength. Besides this, the compatibilizer polyolefin grafted maleic anhydride (POE-g-MA) can cover the PET in either spherical or microfibrillar shape to form a core–shell structure, which tends to improve both the yield and impact strength. We focused on the influence of all composing aspects—fibrillation of the dispersed PET, PP matrix crystalline morphology, and compatibilized interface—on the mechanical properties of PP/PET blends as well as potential synergies between these components. Overall, we provided a theoretical basis for the mechanical recycling of immiscible blends.

Preparation and Characterization of Flame Retardant PET Fiber via Melt Blending

2018 ◽  
Vol 913 ◽  
pp. 729-737
Author(s):  
Hui Ling Xu ◽  
Hong Kun Bao ◽  
Chao Sheng Wang ◽  
Hua Ping Wang
Keyword(s):  
Flame Retardant ◽  
Ethylene Terephthalate ◽  
Carbon Layer ◽  
Melt Blending ◽  
Fiber Fracture ◽  
Limiting Oxygen Index ◽  
Poly Ethylene Terephthalate ◽  
Blending Method ◽  
Poly Ethylene

Poly(ethylene terephthalate) (PET) fiber with excellent flame retardant property was prepared with introducing a containing phosphorus flame retardant 10-(2’,5’-dihydroxyphenyl) -9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (ODOPB) into PET by melt blending method. The intrinsic viscosity of the modified PET was decreased after melt blending, indicated that ODOPB could promote the degradation of PET. The addition of ODOPB can increase the amount of carbon residue of PET, which can effectively reduce the heat transfer. The movement and regularity of PET molecular chain are affected by ODOPB, resulting in the reducing of the crystallization of PET. The Raman curves indicate that the addition of ODOPB can improve the regularity of carbon layer, which is conducive to achieve the effect of flame retardant. When the mass fraction of P is 0.7 %, the limiting oxygen index of sample reaches 32.4% and UL-94 vertical reaches V-2, the fiber fracture strength is 2.6 cN/dtex, which has excellent flame retardant and mechanical properties.

Impact of organoclays on the phase morphology and the compatibilization efficiency of immiscible poly(ethylene terephthalate)/poly(ε‐caprolactone) blends

2020 ◽  
Vol 137 (24) ◽  
pp. 48812
Author(s):  
Dalila Saaoui ◽  
Samira Benali ◽  
Rosica Mincheva ◽  
Abderrahmane Habi ◽  
Philippe Dubois ◽  
...  
Keyword(s):  
Ethylene Terephthalate ◽  
Phase Morphology ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene
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