Thiolactone chemistry and copper-mediated CRP for the development of well-defined amphiphilic dispersing agents

2016 ◽  
Vol 7 (8) ◽  
pp. 1632-1641 ◽  
Author(s):  
Frank Driessen ◽  
Roald Herckens ◽  
Pieter Espeel ◽  
Filip E. Du Prez
Keyword(s):  
Radical Polymerization ◽  
Controlled Radical Polymerization ◽  
Synthetic Pathway ◽  
Dispersing Agents ◽  
Grafting Onto

A straightforward synthetic pathway was developed for the synthesis of amphiphilic graft and toothbrush copolymers by combining copper-mediated controlled radical polymerization with the thiolactone-based amine–thiol–ene conjugation in a “grafting-onto approach”.

Controlled radical polymerization of hydrophilic and zwitterionic brush-like polymers from silk fibroin surfaces

2020 ◽  
Vol 8 (45) ◽  
pp. 10392-10406
Author(s):  
Danielle L. Heichel ◽  
Ngoc Chau H. Vy ◽  
Shawn P. Ward ◽  
Douglas H. Adamson ◽  
Kelly A. Burke
Keyword(s):  
Protein Adsorption ◽  
Radical Polymerization ◽  
Silk Fibroin ◽  
Cell Attachment ◽  
Controlled Radical Polymerization

Silk fibroin films were modified with zwitterionic and hydrophilic brush-like polymers via surface-initiated ATRP, resulting in surfaces that reduced protein adsorption and cell attachment.

Bacterial Redox Potential Powers Controlled Radical Polymerization

2020 ◽  
Author(s):  
Mitchell D. Nothling ◽  
Hanwei Cao ◽  
Thomas G. McKenzie ◽  
Dianna M. Hocking ◽  
Richard A. Strugnell ◽  
...  
Keyword(s):  
Redox Potential ◽  
Radical Polymerization ◽  
Controlled Radical Polymerization

Tetrathiophosphoric acid tri(1-phenylethyl) ester and1-phenylethyl-diphenylphosphinodithioate as controlled radical polymerization agents

2003 ◽  
Vol 44 (6) ◽  
pp. 1227-1229 ◽  
Author(s):  
Didier Gigmes ◽  
Denis Bertin ◽  
Sylvain Marque ◽  
Olivier Guerret ◽  
Paul Tordo
Keyword(s):  
Radical Polymerization ◽  
Controlled Radical Polymerization
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