A study on the chain propagation of benzoxazine

2016 ◽  
Vol 7 (4) ◽  
pp. 860-866 ◽  
Author(s):  
Hongyuan Wang ◽  
Rongqi Zhu ◽  
Po Yang ◽  
Yi Gu
Keyword(s):  
Chain Propagation ◽  
Curing Process ◽  
Chain Polymerization ◽  
Step Polymerization

Variation of Tg with conversion of step polymerization, living chain polymerization and non-living chain polymerization of benzoxazine during the curing process.

Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds

2019 ◽  
Author(s):  
Melanie Short ◽  
Mina Shehata ◽  
Matthew Sanders ◽  
Jennifer Roizen
Keyword(s):  
Hydrogen Atom ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Chain Propagation ◽  
Propagation Mechanism ◽  
Atom Transfer ◽  
Radical Chain ◽  
Radical Intermediates ◽  
Transfer Processes ◽  
Unusual Position

Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.

Sulfamides Direct Radical-Mediated Chlorination of Aliphatic C–H Bonds

2019 ◽  
Author(s):  
Melanie Short ◽  
Mina Shehata ◽  
Matthew Sanders ◽  
Jennifer Roizen
Keyword(s):  
Hydrogen Atom ◽  
Transfer Reaction ◽  
Hydrogen Atom Transfer ◽  
Chain Propagation ◽  
Propagation Mechanism ◽  
Atom Transfer ◽  
Radical Chain ◽  
Radical Intermediates ◽  
Transfer Processes ◽  
Unusual Position

Sulfamides guide intermolecular chlorine transfer to gamma-C(sp<sup>3</sup>) centers. This unusual position-selectivity arises because accessed sulfamidyl radical intermediates engage in otherwise rare 1,6-hydrogen-atom transfer processes. The disclosed chlorine-transfer reaction relies on a light-initiated radical chain-propagation mechanism to oxidize C(sp<sup>3</sup>)-H bonds.

Research of the effect of bacterial preparation "LRR" on the functional and technological parameters of meat during curing process

2018 ◽  
Vol 6 (11) ◽  
pp. 41-47
Author(s):  
Liubov Voytsekhivska ◽  
◽  
Larysa Borsolyuk ◽  
Tetiana Schelkova ◽  
Anna Gavrylenko ◽  
...  
Keyword(s):  
Curing Process ◽  
Technological Parameters ◽  
Bacterial Preparation

scholarly journals Improved Processing and Properties for Polyphenylene Oxide Modified by Diallyl Orthophthalate Prepolymer

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2016
Author(s):  
Honghua Wang ◽  
Qilin Mei ◽  
Yujie Ding ◽  
Zhixiong Huang ◽  
Minxian Shi
Keyword(s):  
Differential Scanning Calorimetry ◽  
Thermal Properties ◽  
Phase Separation ◽  
Dilution Effect ◽  
Gradual Decrease ◽  
Gel Point ◽  
Dynamic Mode ◽  
Curing Process ◽  
Scanning Calorimetry ◽  
Polyphenylene Oxide

Diallyl orthophthalate (DAOP) prepolymer was investigated as a reactive plasticizer to improve the processability of thermoplastics. The rheology of blends of DAOP prepolymer initiated by 2,3-dimethyl-2,3-diphenylbutane (DMDPB) and polyphenylene oxide (PPO) was monitored during the curing process, and their thermal properties and morphology in separated phases were also studied. Differential scanning calorimetry (DSC) results showed that the cure degree of the reactively plasticized DAOP prepolymer was reduced with increasing PPO due to the dilution effect. The increasing amount of the DAOP prepolymer led to a gradual decrease in the viscosity of the blends and the rheology behavior was consistent with the chemical gelation of DAOP prepolymer in blends. This indicated that the addition of the DAOP prepolymer effectively improved processability. The phase separation occurring during curing of the blend and the transition from the static to dynamic mode significantly influences the development of the morphology of the blend corresponding to limited evolution of the conversion around the gel point.

A dynamic DSC study of the curing process of epoxy resin

1997 ◽  
Vol 49 (1) ◽  
pp. 123-129 ◽  
Author(s):  
Susumu Tatsumiya ◽  
Katsumasa Yokokawa ◽  
Kyosuke Miki
Keyword(s):  
Epoxy Resin ◽  
Curing Process

scholarly journals Research on the Manufacturing Quality of Co-Cured Hat-Stiffened Composite Structure

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2747
Author(s):  
Xiangwen Ju ◽  
Jun Xiao ◽  
Dongli Wang ◽  
Cong Zhao ◽  
Xianfeng Wang
Keyword(s):  
Composite Structures ◽  
Sound Pressure ◽  
Integration Method ◽  
Complex Geometry ◽  
Sound Field ◽  
Thickness Measurement ◽  
Curing Process ◽  
The Finite Element Method ◽  
Manufacturing Quality

The stringer-stiffened structure is widely used due to its excellent mechanical properties. Improving the manufacturing quality of stringer-stiffened structure which have complex geometry is important to ensure the bearing capacity of aviation components. Herein, composite hat-stiffened composite structures were manufactured by different filling forms and bladders with various properties, the deformation of silicone rubber bladder in co-curing process was studied by using the finite element method. The thickness measurement at different positions of the hat-stiffened structure was performed to determine the best filling form and bladder property. Moreover, in view of the detection difficulties in R-zone of stringer, numerical simulation was performed to get the sound pressure and impulse response of at the R-zone of stringer by Rayleigh integration method, and an effective equipment which could stably detect the manufacturing quality of R-zone was designed to verify the correctness of sound field simulation and realize the detection of stringer. With the optimum filling form and bladder properties, hat-stiffened composites can be manufactured integrally with improved surface quality and geometric accuracy, based on co-curing process.

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