scholarly journals One-pot synthesis and self-assembly of supramolecular dendritic polymers

2015 ◽  
Vol 6 (46) ◽  
pp. 7988-7994 ◽  
Author(s):  
Senbin Chen ◽  
Matthias Schulz ◽  
Bob-Dan Lechner ◽  
Clement Appiah ◽  
Wolfgang H. Binder

A X–Y2 type heterotropic single-chain polymer, Ba-(PnBuA-HW)2, is prepared in a one-pot two-step reaction, subsequently self-assembling into supramolecular dendrimers, which are displaying solvent-dependent disc-like hierarchical nanoscopic structures as evidenced by AFM.

RSC Advances ◽  
2015 ◽  
Vol 5 (44) ◽  
pp. 34942-34948 ◽  
Author(s):  
Sayantan Mazumdar ◽  
Aninda J. Bhattacharyya

An unprecedented morphology of a titanium dioxide (TiO2) and cadmium sulfide (CdS) self-assembly obtained using a ‘truly’ one-pot and highly cost effective method with a multi-gram scale yield is reported here.


2020 ◽  
Vol 55 (24) ◽  
pp. 10910-10921
Author(s):  
Zi-Kun Rao ◽  
Hai-liang Ni ◽  
Yu Liu ◽  
Yang Li ◽  
Hong-Yu Zhu ◽  
...  

ChemInform ◽  
2014 ◽  
Vol 45 (15) ◽  
pp. no-no
Author(s):  
C. Parashiva Prabhu ◽  
Prasad P. Phadnis ◽  
Amey Wadawale ◽  
K. Indira Priyadarsini ◽  
Vimal K. Jain

2016 ◽  
Vol 7 (29) ◽  
pp. 4761-4770 ◽  
Author(s):  
Jianbing Huang ◽  
Hanjun Zhu ◽  
Hui Liang ◽  
Jiang Lu

Salicylaldehyde-functionalized nano-objects are prepared via RAFT-mediated polymerization-induced self-assembly. Their simultaneous stabilization and fluorescence modification can be achieved by one-step reaction.


2017 ◽  
Vol 8 (2) ◽  
pp. 370-374 ◽  
Author(s):  
Yang Zheng ◽  
Yucheng Huang ◽  
Zaid M. Abbas ◽  
Brian C. Benicewicz

The first case of surface-initiated polymerization-induced self-assembly (SI-PISA) of inorganic nanoparticles (NPs) into single-walled vesicles is reported.


2019 ◽  
Vol 131 (12) ◽  
pp. 3925-3929 ◽  
Author(s):  
Bin Li ◽  
Bin Wang ◽  
Xiayang Huang ◽  
Lu Dai ◽  
Lei Cui ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2190
Author(s):  
Tai-Lam Nghiem ◽  
Deniz Coban ◽  
Stefanie Tjaberings ◽  
André H. Gröschel

Catalysis is one of the most important processes in nature, science, and technology, that enables the energy efficient synthesis of essential organic compounds, pharmaceutically active substances, and molecular energy sources. In nature, catalytic reactions typically occur in aqueous environments involving multiple catalytic sites. To prevent the deactivation of catalysts in water or avoid unwanted cross-reactions, catalysts are often site-isolated in nanopockets or separately stored in compartments. These concepts have inspired the design of a range of synthetic nanoreactors that allow otherwise unfeasible catalytic reactions in aqueous environments. Since the field of nanoreactors is evolving rapidly, we here summarize—from a personal perspective—prominent and recent examples for polymer nanoreactors with emphasis on their synthesis and their ability to catalyze reactions in dispersion. Examples comprise the incorporation of catalytic sites into hydrophobic nanodomains of single chain polymer nanoparticles, molecular polymer nanoparticles, and block copolymer micelles and vesicles. We focus on catalytic reactions mediated by transition metal and organocatalysts, and the separate storage of multiple catalysts for one-pot cascade reactions. Efforts devoted to the field of nanoreactors are relevant for catalytic chemistry and nanotechnology, as well as the synthesis of pharmaceutical and natural compounds. Optimized nanoreactors will aid in the development of more potent catalytic systems for green and fast reaction sequences contributing to sustainable chemistry by reducing waste of solvents, reagents, and energy.


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