High charge mobility polymers based on a new di(thiophen-2-yl)thieno[3,2-b]thiophene for transistors and solar cells

2015 ◽  
Vol 6 (44) ◽  
pp. 7684-7692 ◽  
Author(s):  
Lie Chen ◽  
Feiyan Wu ◽  
Zhiqiang Deng ◽  
Linlin Feng ◽  
Pengcheng Gu ◽  
...  

A novel random copolymer of di(thiophen-2-yl)thieno[3,2-b]thiophene (DTTT) with DPP achieved a high hole mobility of 0.627 cm2 V−1 s−1.

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2592 ◽  
Author(s):  
Funeka Matebese ◽  
Raymond Taziwa ◽  
Dorcas Mutukwa

P-type wide bandgap semiconductor materials such as CuI, NiO, Cu2O and CuSCN are currently undergoing intense research as viable alternative hole transport materials (HTMs) to the spiro-OMeTAD in perovskite solar cells (PSCs). Despite 23.3% efficiency of PSCs, there are still a number of issues in addition to the toxicology of Pb such as instability and high-cost of the current HTM that needs to be urgently addressed. To that end, copper thiocyanate (CuSCN) HTMs in addition to robustness have high stability, high hole mobility, and suitable energy levels as compared to spiro-OMeTAD HTM. CuSCN HTM layer use affordable materials, require short synthesis routes, require simple synthetic techniques such as spin-coating and doctor-blading, thus offer a viable way of developing cost-effective PSCs. HTMs play a vital role in PSCs as they can enhance the performance of a device by reducing charge recombination processes. In this review paper, we report on the current progress of CuSCN HTMs that have been reported to date in PSCs. CuSCN HTMs have shown enhanced stability when exposed to weather elements as the solar devices retained their initial efficiency by a greater percentage. The efficiency reported to date is greater than 20% and has a potential of increasing, as well as maintaining thermal stability.


2006 ◽  
Vol 128 (29) ◽  
pp. 9304-9305 ◽  
Author(s):  
Hong Meng ◽  
Fangping Sun ◽  
Marc B. Goldfinger ◽  
Feng Gao ◽  
David J. Londono ◽  
...  

2020 ◽  
Vol 11 (13) ◽  
pp. 3418-3426 ◽  
Author(s):  
Niansheng Xu ◽  
Aibin Zheng ◽  
Yuefang Wei ◽  
Yi Yuan ◽  
Jing Zhang ◽  
...  

A thia[5]helicene based molecular semiconductor maintains π–π stacking, ensuring a large domain of molecular aggregates and a high hole mobility.


2016 ◽  
Vol 129 (3) ◽  
pp. 740-745 ◽  
Author(s):  
Mengyun Chen ◽  
Yang Zhao ◽  
Lijia Yan ◽  
Shuai Yang ◽  
Yanan Zhu ◽  
...  

Author(s):  
Shangwen Lu ◽  
Shengchun Qu ◽  
Yingying Deng ◽  
Yueyue Gao ◽  
Gentian Yue ◽  
...  

Herein, two simple furan-based polymers PFO3 and PFO4 grafting oligoethylene glycol (OEG) side chains are developed. PFO3 and PFO4 feature high hole mobility, large dielectric constant and good solubility. Compared...


Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 354
Author(s):  
Shaoxi Wang ◽  
He Guan ◽  
Yue Yin ◽  
Chunfu Zhang

With the continuous development of solar cells, the perovskite solar cells (PSCs), whose hole transport layer plays a vital part in collection of photogenerated carriers, have been studied by many researchers. Interface transport layers are important for efficiency and stability enhancement. In this paper, we demonstrated that lithium (Li) and cobalt (Co) codoped in the novel inorganic hole transport layer named NiOx, which were deposited onto ITO substrates via solution methods at room temperature, can greatly enhance performance based on inverted structures of planar heterojunction PSCs. Compared to the pristine NiOx films, doping a certain amount of Li and Co can increase optical transparency, work function, electrical conductivity and hole mobility of NiOx film. Furthermore, experimental results certified that coating CH3NH3PbIxCl3−x perovskite films on Li and Co- NiOx electrode interlayer film can improve chemical stability and absorbing ability of sunlight than the pristine NiOx. Consequently, the power conversion efficiency (PCE) of PSCs has a great improvement from 14.1% to 18.7% when codoped with 10% Li and 5% Co in NiOx. Moreover, the short-circuit current density (Jsc) was increased from 20.09 mA/cm2 to 21.7 mA/cm2 and the fill factor (FF) was enhanced from 0.70 to 0.75 for the PSCs. The experiment results demonstrated that the Li and Co codoped NiOx can be a effective dopant to improve the performance of the PSCs.


2019 ◽  
Vol 7 (27) ◽  
pp. 8344-8349 ◽  
Author(s):  
Xianglan Tang ◽  
Shuqin Xiao ◽  
Qingxia Fu ◽  
Yiwang Chen ◽  
Ting Hu

A PCBM:ITIC mixture interlayer was formed on perovskite to improve charge mobility and device stability.


2020 ◽  
Vol 240 ◽  
pp. 122058 ◽  
Author(s):  
Jiaren Guo ◽  
Yan Zhang ◽  
Wanlin Cai ◽  
Zemin Zhang ◽  
Rongxing He ◽  
...  

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