Facile and cost-effective branched acrylic copolymers from multifunctional comonomers and multifunctional chain transfer agents

2015 ◽  
Vol 6 (41) ◽  
pp. 7333-7341 ◽  
Author(s):  
M. S. Chisholm ◽  
I. K. Martin ◽  
A. T. Slark
Keyword(s):  
Free Radical ◽  
Functional Groups ◽  
Chain Transfer ◽  
Cost Effective ◽  
High Conversion ◽  
Acrylic Copolymers ◽  
Transfer Agents

Branched acrylic copolymers were synthesised via facile conventional free-radical polymerisations taken to high conversion using comonomers containing 2-6 acrylate functional groups and chain transfer agents containing 1-8 thiol functional groups.

In situ xanthate deprotection to generate thiol chain transfer agents for conventional free radical linear and branched vinyl polymerization

2017 ◽  
Vol 55 (24) ◽  
pp. 3963-3967 ◽  
Author(s):  
Sean Flynn ◽  
Simon D. Dale ◽  
Andrew B. Dwyer ◽  
Pierre Chambon ◽  
Steve P. Rannard
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Vinyl Polymerization ◽  
Transfer Agents

New chain transfer agents for free radical polymerizations

1991 ◽  
Vol 26 (4) ◽  
pp. 239-244 ◽  
Author(s):  
Gordon F. Meijs ◽  
Ezio Rizzardo ◽  
Tam P. T. Le
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Radical Polymerizations ◽  
Transfer Agents

Thiols as chain transfer agents in free radical polymerization in aqueous solution

Polymer ◽  
2003 ◽  
Vol 44 (19) ◽  
pp. 5559-5561 ◽  
Author(s):  
C. Henrı́quez ◽  
C. Bueno ◽  
E.A. Lissi ◽  
M.V. Encinas
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Transfer Agents

Role of Chain Transfer Agents in Free Radical Polymerization Kinetics

2010 ◽  
Vol 43 (4) ◽  
pp. 1823-1835 ◽  
Author(s):  
T. Furuncuoğlu ◽  
İ. Uğur ◽  
İ. Değirmenci ◽  
V. Aviyente
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Polymerization Kinetics ◽  
Transfer Agents
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