A thermoresponsive polymer supporter for concerted catalysis of ferrocene with a ruthenium catalyst in living radical polymerization: high activity and efficient removal of metal residues

2015 ◽  
Vol 6 (45) ◽  
pp. 7821-7826 ◽  
Author(s):  
Kojiro Fujimura ◽  
Makoto Ouchi ◽  
Mitsuo Sawamoto
Keyword(s):  
High Activity ◽  
Radical Polymerization ◽  
Supported Catalyst ◽  
Living Radical Polymerization ◽  
Ruthenium Catalyst ◽  
Efficient Removal ◽  
Thermoresponsive Polymer ◽  
Removal Of Metal ◽  
Polymer Supported

A thermoresponsive polymer-supported catalyst consisting of a ruthenium (Ru) main catalyst and a ferrocene (Fc) cocatalyst was designed to realize both high activity and efficient removal of metal residues.

Design of a hydrophilic ruthenium catalyst for metal-catalyzed living radical polymerization: highly active catalysis in water

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6577-6582 ◽  
Author(s):  
Keita Nishizawa ◽  
Makoto Ouchi ◽  
Mitsuo Sawamoto
Keyword(s):  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Phosphine Ligand ◽  
Ruthenium Catalyst ◽  
Highly Active ◽  
Metal Catalyzed

A novel hydrophilic phosphine ligand for a ruthenium catalyst was synthesized towards useful living radical polymerization in water.

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

Chemoenzymatic cascade for stilbene production from cinnamic acid catalyzed by ferulic acid decarboxylase and an artificial metathease

2019 ◽  
Vol 9 (20) ◽  
pp. 5572-5576 ◽  
Author(s):  
M. A. Stephanie Mertens ◽  
Daniel F. Sauer ◽  
Ulrich Markel ◽  
Johannes Schiffels ◽  
Jun Okuda ◽  
...  
Keyword(s):  
Ferulic Acid ◽  
Cinnamic Acid ◽  
Olefin Metathesis ◽  
Metal Contamination ◽  
Cascade Reaction ◽  
Acid Decarboxylase ◽  
Efficient Removal ◽  
Ferulic Acid Decarboxylase ◽  
Acid Catalyzed ◽  
Removal Of Metal

We report a chemoenzymatic cascade reaction for stilbene production combining decarboxylation and olefin metathesis with efficient removal of metal contamination.

AGET ATRP of water-soluble PEGMA: Fast living radical polymerization mediated by iron catalyst

2012 ◽  
Vol 50 (11) ◽  
pp. 2194-2200 ◽  
Author(s):  
Jie Miao ◽  
Weiwei He ◽  
Lifen Zhang ◽  
Yi Wang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Iron Catalyst ◽  
Living Radical Polymerization ◽  
Water Soluble ◽  
Aget Atrp
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