Polymeric palladium-mediated carbene polymerization

2015 ◽  
Vol 6 (34) ◽  
pp. 6163-6170 ◽  
Author(s):  
Feifei Li ◽  
Longqiang Xiao ◽  
Lijian Liu
Keyword(s):  
Radical Polymerization ◽  
Polymerization Mechanism

A newly-developed metal-carbene radical polymerization mechanism is proposed for poly(imidazole-Pd)-mediated carbene polymerization, which could produce stereoregular polycarbenes besides atactic polycarbenes.

Specific Polymerization Mechanism Involving β-Scission of Mid-Chain Radical Yielding Oligomers in the Free-Radical Polymerization of Vinyl Ethers

2008 ◽  
Vol 41 (20) ◽  
pp. 7347-7351 ◽  
Author(s):  
Takeo Kumagai ◽  
Chihiro Kagawa ◽  
Hiroyuki Aota ◽  
Yoshiki Takeda ◽  
Hideya Kawasaki ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Vinyl Ethers ◽  
Polymerization Mechanism

Reactive separation of β-bromoethylbenzene from α-β-bromoethylbenzene mixtures: A Zn2+-mediated radical polymerization mechanism

2022 ◽  
Author(s):  
Tianyu Deng ◽  
Jiaming Tian ◽  
Junqiu Zhu ◽  
Binhang Yan
Keyword(s):  
Radical Polymerization ◽  
Separation Method ◽  
Radical Mechanism ◽  
Polymerization Mechanism ◽  
Reactive Separation

A Zn2+-induced reactive separation method for the purification of β-bromoethylbenzene from α-β-bromoethylbenzene mixtures is discovered, where the selective decomposition of α-bromoethylbenzene follows a radical mechanism. Zn2+ facilitates the homolysis of...

Synthesis of block copolymers by combination of an activated monomer and free radical polymerization mechanism

1993 ◽  
Vol 26 (10) ◽  
pp. 2397-2399 ◽  
Author(s):  
Yusuf Yagci ◽  
I. Ersin Serhatli ◽  
Przemyslaw Kubisa ◽  
Tadeusz Biedron
Keyword(s):  
Free Radical ◽  
Block Copolymers ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Polymerization Mechanism

Comment on radical polymerization mechanism of vinyl benzoate

1979 ◽  
Vol 1 (8) ◽  
pp. 581-584 ◽  
Author(s):  
M. Kamachi ◽  
J. Satoh ◽  
D. J. Liaw
Keyword(s):  
Radical Polymerization ◽  
Polymerization Mechanism
Sign in / Sign up

Export Citation Format

Share Document