Synthesis and self-assembly of CO2-responsive dendronized triblock copolymers

2015 ◽  
Vol 6 (42) ◽  
pp. 7427-7435 ◽  
Author(s):  
Meng Huo ◽  
Qiquan Ye ◽  
Hailong Che ◽  
Mengzhen Sun ◽  
Jinying Yuan ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Assembly Behavior

Dendronized amphiphilic block copolymers POEGMA-b-P(Gn)-b-PDEAEMA were synthesized, and their self-assembly behavior could be regulated by the dendron generation, the type of common solvent, and CO2-stimulus.

scholarly journals A facile strategy for manipulating micellar size and morphology through intramolecular cross-linking of amphiphilic block copolymers

2017 ◽  
Vol 8 (23) ◽  
pp. 3647-3656 ◽  
Author(s):  
Ryoto Tanaka ◽  
Kodai Watanabe ◽  
Takuya Yamamoto ◽  
Kenji Tajima ◽  
Takuya Isono ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Self Assembly ◽  
Amphiphilic Block Copolymers ◽  
Amphiphilic Block Copolymer ◽  
Cross Linking ◽  
Micellar Size ◽  
System P ◽  
Assembly Behavior ◽  
Size And Morphology

The effect of intramolecular cross-linking on aqueous self-assembly behavior was systematically investigated based on an amphiphilic block copolymer system.

Self-Assembly of ABC-Type Amphiphilic Fluorinated Triblock Copolymers in Different Mixed Solutions

2010 ◽  
Vol 663-665 ◽  
pp. 880-882
Author(s):  
Xin De Tang ◽  
Jing Xu
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymer ◽  
Triblock Copolymers ◽  
Ionic Concentration ◽  
The Self ◽  
Amphiphilic Block Copolymers ◽  
Mixed Solutions

The behavior of amphiphilic block copolymers in solution has attracted considerable attention in recent years. In this paper, the self-assembly behaviors of the amphiphilic fluorinated ABC-type triblock copolymer (MeOPEO16-PSt220-PFHEA22) in different mixed solutions were studied. Also, the effect of ionic concentration on the self-assembly aggregates of the copolymer in toluene-ethanol-water was studied.

Unique self-assembly behavior of amphiphilic block copolymers at liquid/liquid interfaces

RSC Advances ◽  
2015 ◽  
Vol 5 (6) ◽  
pp. 4334-4342 ◽  
Author(s):  
Mei Liu ◽  
Yuanyuan Geng ◽  
Qian Wang ◽  
Yong-Ill Lee ◽  
Jingcheng Hao ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Amphiphilic Block Copolymers ◽  
Liquid Interfaces ◽  
Assembly Behavior

Various microstructures of amphiphilic block copolymers were fabricated at the liquid/liquid interfaces.

scholarly journals Self-Assembly Behavior and pH-Stimuli-Responsive Property of POSS-Based Amphiphilic Block Copolymers in Solution

Micromachines ◽  
2018 ◽  
Vol 9 (6) ◽  
pp. 258 ◽  
Author(s):  
Yiting Xu ◽  
Kaiwei He ◽  
Hongchao Wang ◽  
Meng Li ◽  
Tong Shen ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Amphiphilic Block Copolymers ◽  
Stimuli Responsive ◽  
Assembly Behavior

Self-Assembly of Hydrogels From Elastin-Mimetic Block Copolymers

2002 ◽  
Vol 724 ◽  
Author(s):  
Elizabeth R. Wright ◽  
R. Andrew McMillan ◽  
Alan Cooper ◽  
Robert P. Apkarian ◽  
Vincent P. Conticello
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Variable Temperature ◽  
Inverse Temperature ◽  
Temperature Transition ◽  
Scanning Calorimetry ◽  
Design Synthesis ◽  
Inverse Temperature Transition ◽  
Functional Biomaterials

AbstractTriblock copolymers have traditionally been synthesized with conventional organic components. However, triblock copolymers could be synthesized by the incorporation of two incompatible protein-based polymers. The polypeptides would differ in their hydrophobicity and confer unique physiochemical properties to the resultant materials. One protein-based polymer, based on a sequence of native elastin, that has been utilized in the synthesis of biomaterials is poly (Valine-Proline-Glycine-ValineGlycine) or poly(VPGVG) [1]. This polypeptide has been shown to have an inverse temperature transition that can be adjusted by non-conservative amino acid substitutions in the fourth position [2]. By combining polypeptide blocks with different inverse temperature transition values due to hydrophobicity differences, we expect to produce amphiphilic polypeptides capable of self-assembly into hydrogels. Our research examines the design, synthesis and characterization of elastin-mimetic block copolymers as functional biomaterials. The methods that are used for the characterization include variable temperature 1D and 2D High-Resolution-NMR, cryo-High Resolutions Scanning Electron Microscopy and Differential Scanning Calorimetry.

Self-Assembly of Single Chain Janus Nanoparticles from Azobenzene-Containing Block Copolymers and Reversible Photoinduced Morphology Transition

2021 ◽  
Author(s):  
Wei Wen ◽  
Aihua Chen
Keyword(s):  
Block Copolymers ◽  
Experimental Research ◽  
Self Assembly ◽  
The Self ◽  
Single Chain ◽  
Morphology Transition ◽  
Janus Nanoparticles ◽  
Assembly Behavior

Self-assembly of amphiphilic single chain Janus nanoparticles (SCJNPs) is a novel and promising approach to fabricate assemblies with diversified morphologies. However, the experimental research of the self-assembly behavior of SCJNPs...

scholarly journals Polymerisation-induced self-assembly (PISA) as a straightforward formulation strategy for stimuli-responsive drug delivery systems and biomaterials: recent advances

2021 ◽  
Vol 9 (1) ◽  
pp. 38-50
Author(s):  
Hien Phan ◽  
Vincenzo Taresco ◽  
Jacques Penelle ◽  
Benoit Couturaud
Keyword(s):  
Drug Delivery ◽  
Block Copolymers ◽  
Drug Release ◽  
Self Assembly ◽  
Drug Delivery Systems ◽  
Amphiphilic Block Copolymers ◽  
Stimuli Responsive ◽  
Site Specific ◽  
On Demand ◽  
Redox Agents

Stimuli-responsive amphiphilic block copolymers obtained by PISA have emerged as promising nanocarriers for enhancing site-specific and on-demand drug release in response to a range of stimuli such as pH, redox agents, light or temperature.

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