Facile anionic synthesis of a well-controlled thermally cross-linkable block copolymer for polymer-based resistive memory device applications

2015 ◽  
Vol 6 (23) ◽  
pp. 4264-4270 ◽  
Author(s):  
Beom-Goo Kang ◽  
Jingon Jang ◽  
Younggul Song ◽  
Myung-Jin Kim ◽  
Takhee Lee ◽  
...  

A well-defined block copolymer containing a thermally cross-linkable ethynyl group has been synthesized by living anionic polymerization for polymer-based resistive memory device applications.

2012 ◽  
Vol 45 (2) ◽  
pp. 125-128 ◽  
Author(s):  
Yanfen Huang ◽  
Xinghai Liu ◽  
Fangfang Zhang ◽  
Jinfeng Dong ◽  
Yunbai Luo ◽  
...  

Author(s):  
Yu-Che Chen ◽  
Yan-Cheng Lin ◽  
Hui-Ching Hsieh ◽  
Li-Che Hsu ◽  
Wei-Chen Yang ◽  
...  

We report the synthesis, morphology and photo-memory device applications of a block copolymer (BCP) consisting of poly(9,9-dioctylfluorene) (PFO) and polystyrene (PS).


1999 ◽  
Vol 561 ◽  
Author(s):  
J. Mays ◽  
K. Hong ◽  
Y. Wang ◽  
R.C. Advincula

ABSTRACTConjugated polymers have been used as solid-state materials for a variety of opto-electronic applications. Thus, their processability in a number of device fabrication protocols is an important consideration. In this report, we indicate our results on the synthesis of conjugated poly-p-phenylene (PPP) materials derived from poly(1,3-cyclohexadiene) (PCHD). The precursor PCHD polymers were synthesized by living anionic polymerization to produce homo-and block copolymer configurations with polystyrene. We have used a variety of initiators, solvent, and temperature conditions to determine the right parameters for obtaining narrow MWD polymers. The conditions for polymerization determined the ratio of 1,2 and 1,4 isomers in the microstructure. We then proceeded with conversion to PPP derivatives using a dehydrogenation reaction with chloranil. Our results indicate a systematic conversion to a conjugated polymer with increased solubility and photoluminescence properties. The microstructure, MW and block copolymer composition affecting the processability and conversion properties dramatically.


Polymer ◽  
2007 ◽  
Vol 48 (9) ◽  
pp. 2489-2495 ◽  
Author(s):  
Xifei Yu ◽  
Guo Zhang ◽  
Tongfei Shi ◽  
Yanchun Han ◽  
Lijia An

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