Palladium-catalyzed direct C–H arylation of 3-aryl-2H-benzo[1,2,4]thiadiazine 1,1-dioxides: an efficient strategy to the synthesis of benzothiadiazine-1,1-dioxide derivatives

2016 ◽  
Vol 14 (6) ◽  
pp. 1921-1924 ◽  
Author(s):  
Dongyin Wang ◽  
Wei Liu ◽  
Fei Yi ◽  
Yongli Zhao ◽  
Junmin Chen
Keyword(s):  
Direct Arylation ◽  
Efficient Strategy ◽  
Aryl Iodides ◽  
Palladium Catalyzed

An efficient strategy to the synthesis of 3-aryl-2H-benzo[1,2,4]thiadiazine 1,1-dioxide derivatives via palladium-catalyzed direct arylation of benzothiadiazine-1,1-dioxides with various aryl iodides is described.

scholarly journals Phosphine-Free Palladium-Catalyzed Direct C-3 Arylation of 2-Phenylimidazo[1,2-a]pyridine Using Silver(I) Carboxylate

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Sridevi Kona ◽  
Rama Suresh Ravi ◽  
Manab Chakravarty ◽  
Venkata N. R. Chava
Keyword(s):  
Direct Arylation ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Phosphine-free palladium-catalyzed direct arylation of 2-phenyl-imidazo[1,2-a]pyridine has been developed with the concept of using silver(I) carboxylate. This protocol efficiently catalyzes the C-H arylation of 2-phenyl-imidazo[1,2-a]pyridine with aryl iodides to afford the corresponding 2-phenyl-3-aryl-imidazo[1,2-a]pyridines in moderate to-good yields.

Palladium-catalyzed direct arylation of phenols with aryl iodides

2015 ◽  
Vol 13 (12) ◽  
pp. 3571-3574 ◽  
Author(s):  
Rongrong Long ◽  
Xufei Yan ◽  
Zhiqing Wu ◽  
Zhengkai Li ◽  
Haifeng Xiang ◽  
...  
Keyword(s):  
Direct Arylation ◽  
Mild Conditions ◽  
Aryl Iodides ◽  
Palladium Catalyzed

An efficient protocol of palladium-catalyzed direct para-arylation of unfunctionalized phenols with aryl iodides under mild conditions was reported.

Palladium-Catalyzed Direct Arylation Reaction of 2,3,5-Trisubstituted Furans with Aryl Iodides or Aryl Bromides

Synlett ◽  
2011 ◽  
Vol 2011 (10) ◽  
pp. 1472-1476 ◽  
Author(s):  
Hua Cao ◽  
Dongsheng Shen ◽  
Haiying Zhan ◽  
Liuqing Yang
Keyword(s):  
Direct Arylation ◽  
Aryl Iodides ◽  
Aryl Bromides ◽  
Palladium Catalyzed ◽  
Trisubstituted Furans

Synthesis of S-aryl thioesters via palladium-catalyzed thiocarbonylation of aryl iodides and aryl sulfonyl hydrazides

2020 ◽  
Vol 7 (19) ◽  
pp. 2938-2943
Author(s):  
Yeojin Kim ◽  
Kwang Ho Song ◽  
Sunwoo Lee
Keyword(s):  
Aryl Iodide ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Aryl sulfonyl hydrazide reacted with aryl iodide in the presence of CO to give the corresponding S-aryl thioesters.

Palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides: convenient access to thioesters

2020 ◽  
Vol 7 (6) ◽  
pp. 885-889 ◽  
Author(s):  
Xinxin Qi ◽  
Zhi-Peng Bao ◽  
Xiao-Feng Wu
Keyword(s):  
Sulfonyl Chlorides ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Convenient Access

A palladium-catalyzed carbonylative transformation of aryl iodides and sulfonyl chlorides to thioesters has been studied.

Palladium-Catalyzed Asymmetric Annulation Between Aryl Iodides and Racemic Epoxides Using a Chiral Norbornene Cocatalyst

2018 ◽  
Author(s):  
Guangbin Dong ◽  
Renhe Li
Keyword(s):  
Isopropyl Ester ◽  
Synthetic Route ◽  
Initial Development ◽  
Aryl Iodides ◽  
Palladium Catalyzed

Herein, we describe our initial development of an asymmetric Pd-catalyzed annulation between aryl iodides and racemic epoxides for synthesis of 2,3-dihydrobenzofurans using a chiral norbornene cocatalyst. A series of enantiopure ester-, amide- and imide-substituted norbornenes have been prepared with a reliable synthetic route. Promising enantioselectivity (42-45% ee) has been observed using the isopropyl ester-substituted norbornene (N1*) and the amide-substituted norbornene (N7*).

scholarly journals Selective Synthesis of N-Acylnortropane Derivatives in Palladium-Catalysed Aminocarbonylation

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1813
Author(s):  
László Kollár ◽  
Ádám Erdélyi ◽  
Haroon Rasheed ◽  
Attila Takács
Keyword(s):  
Synthetic Method ◽  
Selective Synthesis ◽  
Varied Structure ◽  
Biological Importance ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Derivatives Of

The aminocarbonylation of various alkenyl and (hetero)aryl iodides was carried out using tropane-based amines of biological importance, such as 8-azabicyclo[3.2.1]octan-3-one (nortropinone) and 3α-hydroxy-8-azabicyclo[3.2.1]octane (nortropine) as N-nucleophile. Using iodoalkenes, the two nucleophiles were selectively converted to the corresponding amide in the presence of Pd(OAc)2/2 PPh3 catalysts. In the presence of several iodo(hetero)arenes, the application of the bidentate Xantphos was necessary to produce the target compounds selectively. The new carboxamides of varied structure, formed in palladium-catalyzed aminocarbonylation reactions, were isolated and fully characterized. In this way, a novel synthetic method has been developed for the producing of N-acylnortropane derivatives of biological importance.

Palladium-catalyzed carbonylative cyclization of 2-alkynylanilines and aryl iodides to access N-acyl indoles

2021 ◽  
Author(s):  
Lingyun Yao ◽  
Yan Shang ◽  
Jian-Shu Wang ◽  
Ailin Pan ◽  
Jun Ying ◽  
...  
Keyword(s):  
Aryl Iodides ◽  
Palladium Catalyzed

A palladium-catalyzed carbonylative synthesis of N-acyl indoles from 2-alkynylanilines and aryl iodides has been developed.

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