Metal-free Brønsted acid mediated synthesis of fully substituted thiophenes via chemo- and regioselective intramolecular cyclization of α,α′-bis(β-oxodithioesters) at room temperature

2016 ◽  
Vol 14 (2) ◽  
pp. 434-439 ◽  
Author(s):  
B. Janaki Ramulu ◽  
Suvajit Koley ◽  
Maya Shankar Singh
Keyword(s):  
Intramolecular Cyclization ◽  
Room Temperature ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Brönsted Acid

Metal-free Brønsted acid mediated synthesis of tetrasubstituted thiophenes via intramolecular cyclization of α,α′-bis(β-oxodithioesters) is devised at room temperature.

Brønsted Acid-Catalyzed Solvent-Controlled Regioselective Hydrothiolation and Diastereoselective Cascade Cyclization of Dienes

2021 ◽  
Author(s):  
Kai Ji ◽  
Ka Lu ◽  
Jie Huang ◽  
Zi-Hao Li ◽  
Tong-Mei Ding ◽  
...  
Keyword(s):  
Free Atom ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Cascade Cyclization ◽  
Brönsted Acid ◽  
Acid Catalyzed ◽  
First Time

A highly regio- and diastereo-selective Brønsted acid-catalyzed tandem hydrothiolation/Friedel-Crafts reaction of linear 1,3-dienes has been developed for the first time, which provides a metal-free, atom-economic and concise way of constructing...

scholarly journals Brønsted acid-catalyzed metal-free one-pot synthesis of benzimidazoles via [4+1] heteroannulation of ortho-phenylenediamines with β-oxodithioesters

ARKIVOC ◽  
2017 ◽  
Vol 2018 (2) ◽  
pp. 81-89
Author(s):  
Abhijeet Srivastava ◽  
Gaurav Shukla ◽  
Dhananjay Yadav ◽  
Maya Shankar Singh
Keyword(s):  
Bronsted Acid ◽  
Brønsted Acid ◽  
One Pot ◽  
Metal Free ◽  
One Pot Synthesis ◽  
Brönsted Acid ◽  
Acid Catalyzed

One-Step Conversion of Biomass-Derived Furanics into Aromatics by Brønsted Acid Ionic Liquids at Room Temperature

2018 ◽  
Vol 6 (2) ◽  
pp. 2541-2551 ◽  
Author(s):  
Lingli Ni ◽  
Jiayu Xin ◽  
Kun Jiang ◽  
Lu Chen ◽  
Dongxia Yan ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Room Temperature ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid ◽  
One Step

Organic Photoredox Catalytic α-C(sp3)–H Phosphorylation of Saturated Aza-Heterocycles

2021 ◽  
Author(s):  
Ming-Jun Yi ◽  
Teng-Fei Xiao ◽  
Wen-Hui Li ◽  
Yi-Fan Zhang ◽  
Pen-Ji Yan ◽  
...  
Keyword(s):  
Acid Catalysis ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Mild Conditions ◽  
Brönsted Acid ◽  
Bronsted Acid Catalysis

A metal-free C(sp3)–H phosphorylation of saturated aza-heterocycles via the merger of organic photoredox and Brønsted acid catalysis was established under mild conditions. This protocol provided a straightforward and economic access...

Brønsted acid cocatalysis in photocatalytic intramolecular coupling of tertiary amines: efficient synthesis of 2-arylindols

2016 ◽  
Vol 14 (31) ◽  
pp. 7447-7450 ◽  
Author(s):  
Xiaoqian Yuan ◽  
Xinxin Wu ◽  
Shupeng Dong ◽  
Guibing Wu ◽  
Jinxing Ye
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Coupling Reaction ◽  
Bronsted Acid ◽  
Tertiary Amines ◽  
Brønsted Acid ◽  
Efficient Synthesis ◽  
Unsaturated Ketones ◽  
Brönsted Acid

We report herein a highly efficient intramolecular coupling reaction of tertiary amines and ketones (α,β-unsaturated ketones) by using a Brønsted acid as a cocatalyst, affording 2-arylindols in good to excellent yields (up to 92%) under visible light irradiation at room temperature.

Metal-Free, Brønsted Acid-Catalyzed Formal [3+2] Annulation of Quinone Monoacetals with 2-Naphthols

2017 ◽  
Vol 82 (20) ◽  
pp. 11269-11274 ◽  
Author(s):  
Anu Jacob ◽  
Tony Roy ◽  
Trinadh Kaicharla ◽  
Akkattu T. Biju
Keyword(s):  
Bronsted Acid ◽  
Brønsted Acid ◽  
Metal Free ◽  
Brönsted Acid ◽  
Acid Catalyzed

scholarly journals The Strongest Brønsted Acid: Protonation of Alkanes by H(CHB11F11) at Room Temperature

2013 ◽  
Vol 126 (4) ◽  
pp. 1149-1152 ◽  
Author(s):  
Matthew Nava ◽  
Irina V. Stoyanova ◽  
Steven Cummings ◽  
Evgenii S. Stoyanov ◽  
Christopher A. Reed
Keyword(s):  
Room Temperature ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Brönsted Acid
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