Isopropylmagnesium chloride-promoted unilateral addition of Grignard reagents to β-diketones: one-pot syntheses of β-tertiary hydroxyl ketones or 3-substituted cyclic-2-enones

2016 ◽  
Vol 14 (2) ◽  
pp. 724-728 ◽  
Author(s):  
Rui Yuan ◽  
Dan Zhao ◽  
Li-Yuan Zhang ◽  
Xiang Pan ◽  
Yan Yang ◽  
...  
Keyword(s):  
Tertiary Alcohol ◽  
Grignard Reagents ◽  
One Pot ◽  
Tertiary Hydroxyl

Regioselective unilateral additions of Grignards to acyclic or cyclic β-diketones were effectively promoted by sub-stoichiometric amounts of i-PrMgCl to afford β-tertiary alcohol ketones or 3-substituted cyclic-2-enones, respectively.

ChemInform Abstract: A Convenient One-Pot Method for the Hydroxymethylation of Grignard Reagents.

ChemInform ◽  
1990 ◽  
Vol 21 (42) ◽  
Author(s):  
C. A. OGLE ◽  
T. E. WILSON ◽  
J. A. STOWE
Keyword(s):  
Grignard Reagents ◽  
One Pot

ChemInform Abstract: Enantioselective One-Pot Conjugate Addition of Grignard Reagents to Cyclic Enones Followed by Amidomethylation.

ChemInform ◽  
2012 ◽  
Vol 43 (18) ◽  
pp. no-no
Author(s):  
Filip Bilcik ◽  
Michal Drusan ◽  
Jozef Marak ◽  
Radovan Sebesta
Keyword(s):  
Conjugate Addition ◽  
Grignard Reagents ◽  
One Pot ◽  
Cyclic Enones

One-pot three-component polymerization for in situ generation of AIE-active poly(tetraarylethene)s using Grignard reagents as building blocks

2020 ◽  
Vol 11 (35) ◽  
pp. 5601-5609
Author(s):  
Zijie Qiu ◽  
Qingqing Gao ◽  
Ting Han ◽  
Xiaolin Liu ◽  
Jacky W. Y. Lam ◽  
...  
Keyword(s):  
Building Blocks ◽  
Grignard Reagents ◽  
One Pot ◽  
Aggregation Induced Emission ◽  
In Situ Generation

A facile polymerization route for in situ generation of polymers with aggregation-induced emission (AIE) characteristics has been developed.

ChemInform Abstract: One-Pot Synthesis of Aromatic Homoallylic Alcohols from Aldehydes and Grignard Reagents Promoted by Titanium(IV) Tetraisopropanolate.

ChemInform ◽  
2015 ◽  
Vol 46 (10) ◽  
pp. no-no
Author(s):  
Xiao-Nan Song ◽  
Lei Lu ◽  
Si-Kai Hua ◽  
Wei-Dong Chen ◽  
Jiangmeng Ren
Keyword(s):  
Grignard Reagents ◽  
One Pot ◽  
One Pot Synthesis ◽  
Homoallylic Alcohols

ChemInform Abstract: One-Pot Synthesis of Cyclobutanols by Ring Expansion of Oxaspiropentanes Induced by Grignard Reagents.

ChemInform ◽  
2010 ◽  
Vol 29 (39) ◽  
pp. no-no
Author(s):  
A. M. BERNARD ◽  
C. FLORIS ◽  
A. FRONGIA ◽  
P. P. PIRAS
Keyword(s):  
Ring Expansion ◽  
Grignard Reagents ◽  
One Pot ◽  
One Pot Synthesis
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