Oxidation-resistant hybrid metal oxides/metal nanodots/silver nanowires for high performance flexible transparent heaters

Nanoscale ◽  
2016 ◽  
Vol 8 (6) ◽  
pp. 3307-3313 ◽  
Author(s):  
A-Young Kim ◽  
Min Kyu Kim ◽  
Chairul Hudaya ◽  
Ji Hun Park ◽  
Dongjin Byun ◽  
...  

The FTO/NiCr/AgNW hybrid heater exhibits excellent optoelectronic and thermal properties, oxidation-resistance, and high durability over 10 000 bending cycles.

2014 ◽  
Author(s):  
J. Peter Ault ◽  
Pete Lockwood ◽  
Robert Cloutier ◽  
David Kinee

Polysiloxane coatings are the most recent high performance coatings developed to take advantage of the heat and oxidation resistant properties of silicone-based materials. Commercially available polysiloxane coatings predominately consist of organic-inorganic siloxane materials (though some pure siloxane materials are available). Recently, the US Navy has approved polysiloxane coatings as “High Durability” in their specification for exterior weather resistant coatings (MIL-PRF-24635 Type V and VI). Navy approval comes after over 20 years of industry development of polysiloxane coatings for high performance industrial and marine applications, yet issues remain with their cost-effective implementation in the Navy fleet. This paper will review experiences of the offshore and marine industry with polysiloxane coatings and provide an update on the Navy adoption of the technology.


Author(s):  
C. S. Giggins ◽  
J. K. Tien ◽  
B. H. Kear ◽  
F. S. Pettit

The performance of most oxidation resistant alloys and coatings is markedly improved if the oxide scale strongly adheres to the substrate surface. Consequently, in order to develop alloys and coatings with improved oxidation resistance, it has become necessary to determine the conditions that lead to spallation of oxides from the surfaces of alloys. In what follows, the morphological features of nonadherent Al2O3, and the substrate surfaces from which the Al2O3 has spalled, are presented and related to oxide spallation.The Al2O3, scales were developed by oxidizing Fe-25Cr-4Al (w/o) and Ni-rich Ni3 (Al,Ta) alloys in air at 1200°C. These scales spalled from their substrates upon cooling as a result of thermally induced stresses. The scales and the alloy substrate surfaces were then examined by scanning and replication electron microscopy.The Al2O3, scales from the Fe-Cr-Al contained filamentary protrusions at the oxide-gas interface, Fig. 1(a). In addition, nodules of oxide have been developed such that cavities were formed between the oxide and the substrate, Fig. 1(a).


Alloy Digest ◽  
2001 ◽  
Vol 50 (1) ◽  

Abstract Sandvik 7RE10 is a 25Cr/20Ni oxidation-resistant alloy with good carburization and oxidation resistance. It is typically used as furnace tubing. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-812. Producer or source: Sandvik.


2007 ◽  
Vol 336-338 ◽  
pp. 1159-1163 ◽  
Author(s):  
Guo Jun Zhang ◽  
Wen Wen Wu ◽  
Yan Mei Kan ◽  
Pei Ling Wang

Current high temperature ceramics, such as ZrO2, Si3N4 and SiC, cannot be used at temperatures over 1600°C due to their low melting temperature or dissociation temperature. For ultrahigh temperature applications over 1800°C, materials with high melting points, high phase composition stability, high thermal conductivity, good thermal shock and oxidation resistance are needed. The transition metal diborides, mainly include ZrB2 and HfB2, have melting temperatures of above 3000°C, and can basically meet the above demands. However, the oxidation resistance of diboride monolithic ceramics at ultra-high temperatures need to be improved for the applications in thermal protection systems for future aerospace vehicles and jet engines. On the other hand, processing science for making high performance UHTCs is another hot topic in the UHTC field. Densification of UHTCs at mild temperatures through reactive sintering is an attracting way due to the chemically stable phase composition and microstructure as well as clean grain boundaries in the obtained materials. Moreover, the stability studies of the materials in phase composition and microstructures at ultra high application temperatures is also critical for materials manufactured at relatively low temperature. Furthermore, the oxidation resistance in simulated reentry environments instead of in static or flowing air of ambient pressure should be evaluated. Here we will report the concept, advantages and some recent progress on the reactive sintering of diboride–based composites at mild temperatures.


2018 ◽  
Vol 199 ◽  
pp. 09001
Author(s):  
Renaud Franssen ◽  
Serhan Guner ◽  
Luc Courard ◽  
Boyan Mihaylov

The maintenance of large aging infrastructure across the world creates serious technical, environmental, and economic challenges. Ultra-high performance fibre-reinforced concretes (UHPFRC) are a new generation of materials with outstanding mechanical properties as well as very high durability due to their extremely low permeability. These properties open new horizons for the sustainable rehabilitation of aging concrete structures. Since UHPFRC is a young and evolving material, codes are still either lacking or incomplete, with recent design provisions proposed in France, Switzerland, Japan, and Australia. However, engineers and public agencies around the world need resources to study, model, and rehabilitate structures using UHPFRC. As an effort to contribute to the efficient use of this promising material, this paper presents a new numerical modelling approach for UHPFRC-strengthened concrete members. The approach is based on the Diverse Embedment Model within the global framework of the Disturbed Stress Field Model, a smeared rotating-crack formulation for 2D modelling of reinforced concrete structures. This study presents an adapted version of the DEM in order to capture the behaviour of UHPFRC by using a small number of input parameters. The model is validated with tension tests from the literature and is then used to model UHPFRC-strengthened elements. The paper will discuss the formulation of the model and will provide validation studies with various tests of beams, columns and walls from the literature. These studies will demonstrate the effectiveness of the proposed modelling approach.


2021 ◽  
pp. 095400832110130
Author(s):  
Hailong Li ◽  
Sipei Zhao ◽  
Li Pei ◽  
Zihe Qiao ◽  
Ding Han ◽  
...  

Polybenzoxazines are emerging as a class of high-performance thermoset polymers that can find their applications in various fields. However, its practical application is limited by its low toughness. The cyclic β-cyclodextrin and a newly synthesized derivative (β-cyclodextrin-MAH) were separately blended with benzoxazine to improve the toughness of polybenzoxazine. The results revealed that the maximum impact strength of the blend was 12.24 kJ·m−2 and 14.29 kJ·m−2 when 1 wt.% of β-Cyclodextrin and β-Cyclodextrin-MAH, respectively, were used. The strengths were 53% and 86% higher than that of pure polybenzoxazine. The curing reaction, possible chemical structures, and fractured surface were examined using differential scanning calorimetry, Fourier transform infrared spectroscopy, and scanning electron microscopy techniques to understand the mechanism of generation of toughness. The results revealed that the sea-island structure and the presence of hydrogen bonds between polybenzoxazine and β-cyclodextrin and β-cyclodextrin-MAH resulted in the generation of toughness. Furthermore, the curves generated during thermogravimetric analysis did not significantly change, revealing the good thermal properties of the system. The phase-separated structure and the hydrogen bonds present in the system can be exploited to prepare synergistically tough polybenzoxazine exhibiting excellent thermal properties. This can be a potential way of modifying the thermoset resins.


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