Formation of Pt decorated Ni–Pt nanocubes through low temperature atomic diffusion – time-resolved elemental analysis of nanoparticle formation

Nanoscale ◽  
2015 ◽  
Vol 7 (21) ◽  
pp. 9927-9934 ◽  
Author(s):  
A. Nagao ◽  
K. Higashimine ◽  
J. L. Cuya Huaman ◽  
T. Iwamoto ◽  
T. Matsumoto ◽  
...  
Keyword(s):  
Low Temperature ◽  
Elemental Analysis ◽  
Diffusion Time ◽  
Atomic Diffusion ◽  
Pt Catalysts ◽  
Time Resolved ◽  
Nanoparticle Formation ◽  
The Core ◽  
Temperature Diffusion

Low temperature diffusion of Pt atoms from the core to the corners and edges of the Ni cube results in the preparation of potential novel cage-structured Pt catalysts.

Exsolution and inversion in pigeonite from the Whin Sill, Northern England

1978 ◽  
Vol 36 (1) ◽  
pp. 474-475
Author(s):  
P.P.K. Smith
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Homogeneous Nucleation ◽  
Silicate Mineral ◽  
Antiphase Boundaries ◽  
Two Phase ◽  
Primitive Form ◽  
The Core ◽  
Nucleation Mechanisms ◽  
And Inversion

Grains of pigeonite, a calcium-poor silicate mineral of the pyroxene group, from the Whin Sill dolerite have been ion-thinned and examined by TEM. The pigeonite is strongly zoned chemically from the composition Wo8En64FS28 in the core to Wo13En34FS53 at the rim. Two phase transformations have occurred during the cooling of this pigeonite:- exsolution of augite, a more calcic pyroxene, and inversion of the pigeonite from the high- temperature C face-centred form to the low-temperature primitive form, with the formation of antiphase boundaries (APB's). Different sequences of these exsolution and inversion reactions, together with different nucleation mechanisms of the augite, have created three distinct microstructures depending on the position in the grain.In the core of the grains small platelets of augite about 0.02μm thick have farmed parallel to the (001) plane (Fig. 1). These are thought to have exsolved by homogeneous nucleation. Subsequently the inversion of the pigeonite has led to the creation of APB's.

The promises and perfidy of cryomicroscopy and analysis

1994 ◽  
Vol 52 ◽  
pp. 382-383
Author(s):  
Patrick Echlin
Keyword(s):  
Low Temperature ◽  
High Energy ◽  
Short Paper ◽  
List Type ◽  
Time Resolved ◽  
Energy Beam ◽  
Cellular Analysis ◽  
Dissolved Ions ◽  
Embedding Medium ◽  
Low Temperature Microscopy

The unusual title of this short paper and its accompanying tutorial is deliberate, because the intent is to investigate the effectiveness of low temperature microscopy and analysis as one of the more significant elements of the less interventionist procedures we can use to prepare, examine and analyse hydrated and organic materials in high energy beam instruments. The promises offered by all these procedures are well rehearsed and the litany of petitions and responses may be enunciated in the following mantra.Vitrified water can form the perfect embedding medium for bio-organic samples.Frozen samples provide an important, but not exclusive, milieu for the in situ sub-cellular analysis of the dissolved ions and electrolytes whose activities are central to living processes.The rapid conversion of liquids to solids provides a means of arresting dynamic processes and permits resolution of the time resolved interactions between water and suspended and dissolved materials.The low temperature environment necessary for cryomicroscopy and analysis, diminish, but alas do not prevent, the deleterious side effects of ionizing radiation.Sample contamination is virtually eliminated.

scholarly journals Preparation and application of carbon and hollow TiO2 microspheres by microwave heating at a low temperature

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 200-209
Author(s):  
Caiyun Zhang ◽  
Chunhong Li ◽  
Bolin Ji ◽  
Zhaohui Jiang
Keyword(s):  
Low Temperature ◽  
Microwave Heating ◽  
Raw Material ◽  
Carbon Microspheres ◽  
Microwave Assisted ◽  
The Core ◽  
Good Crystallinity ◽  
Carbon Core ◽  
Microwave Assisted Method ◽  
Uniform Particle Size

Abstract A fast, simple, and energy-saving microwave-assisted approach was successfully developed to prepare carbon microspheres. The carbon microspheres with a uniform particle size and good dispersity were prepared using glucose as the raw material and HCl as the dehydrating agent at low temperature (90°C) in an open system with the assistance of microwave heating. The carbon microspheres were characterized by elemental analysis, XRD, SEM, FTIR, TG, and Raman. The results showed that the carbon microspheres prepared under the condition of 18.5% (v/v) HCl and heating for 30 min by microwave had a narrow size distribution. The core–shell structure of the carbon core and TiO2 shell was prepared with (NH4)2TiF6, H3BO3 using the microwave-assisted method. The hollow TiO2 microspheres with good crystallinity and high photocatalytic properties were successfully prepared by sacrificing the carbon microspheres.

Photophysical properties of N719 and Z907 dyes, benchmark sensitizers for dye-sensitized solar cells, at room and low temperature

2021 ◽  
Vol 23 (10) ◽  
pp. 6182-6189
Author(s):  
Dariusz M. Niedzwiedzki
Keyword(s):  
Solar Cells ◽  
Low Temperature ◽  
Optical Spectroscopy ◽  
Room Temperature ◽  
Photophysical Properties ◽  
Dye Sensitized Solar Cells ◽  
Time Resolved ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Photophysical properties of N719 and Z907, benchmark Ru-dyes used as sensitizers in dye-sensitized solar cells, were studied by static and time-resolved optical spectroscopy at room temperature and 160 K.

In situ time-resolved DXAFS study of Rh nanoparticle formation mechanism in ethylene glycol at elevated temperature

2012 ◽  
Vol 14 (9) ◽  
pp. 2983 ◽  
Author(s):  
Hiroyuki Asakura ◽  
Kentaro Teramura ◽  
Tetsuya Shishido ◽  
Tsunehiro Tanaka ◽  
Ning Yan ◽  
...  
Keyword(s):  
Elevated Temperature ◽  
Ethylene Glycol ◽  
Formation Mechanism ◽  
Time Resolved ◽  
Nanoparticle Formation

Low temperature diffusion measurements on d.c. sputtered multilayers of Nb/Ta

1984 ◽  
Vol 3 (3) ◽  
pp. 217-220 ◽  
Author(s):  
R. E. Somekh ◽  
Z. H. Barber ◽  
C. S. Baxter ◽  
P. E. Donovan ◽  
J. E. Evetts ◽  
...  
Keyword(s):  
Low Temperature ◽  
Temperature Diffusion

Nano-Goethite (α-FeOOH) Magnetic Structure Investigated Using Ising Core-Shell Model: Preliminary Study

2021 ◽  
Vol 1028 ◽  
pp. 193-198
Author(s):  
Budi Adiperdana ◽  
Nadya Larasati Kartika ◽  
Risdiana
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Shell Model ◽  
Magnetic Structure ◽  
Paramagnetic State ◽  
Core Shell ◽  
The Core ◽  
Preliminary Study

Ising core-shell model was proposed to reconstruct superparamagnetism hysteresis in nano-goethite (α-FeOOH). Core and shell set as antiferromagnetic and paramagnetic state respectively. Core and shell radius varies until the theoretical hysteresis fit with experiment hysteresis. At low temperature, the hysteresis reconstructed nicely with 55% antiferromagnetic core contribution and 45% paramagnetic shell contribution. At high temperature, the core-shell model show unrealistic result compared to the pure paramagnetic state.

Low-temperature diffusion of phosphorus in silicon

1988 ◽  
Vol 31 (9) ◽  
pp. 737-740 ◽  
Author(s):  
A. N. Gorban' ◽  
V. A. Gorodokin
Keyword(s):  
Low Temperature ◽  
Temperature Diffusion ◽  
Phosphorus In Silicon
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