scholarly journals J-aggregation, its impact on excited state dynamics and unique solvent effects on macroscopic assembly of a core-substituted naphthalenediimide

Nanoscale ◽  
2015 ◽  
Vol 7 (15) ◽  
pp. 6729-6736 ◽  
Author(s):  
Haridas Kar ◽  
Dominik W. Gehrig ◽  
Frédéric Laquai ◽  
Suhrit Ghosh
Keyword(s):  
Excited State ◽  
Solvent Effects ◽  
Excited State Dynamics

QM/MM Study of Substituent and Solvent Effects on the Excited State Dynamics of the Photoactive Yellow Protein Chromophore

2017 ◽  
Vol 13 (2) ◽  
pp. 737-748 ◽  
Author(s):  
Francisco F. García-Prieto ◽  
Aurora Muñoz-Losa ◽  
Ignacio Fdez. Galván ◽  
M. Luz Sánchez ◽  
Manuel A. Aguilar ◽  
...  
Keyword(s):  
Excited State ◽  
Solvent Effects ◽  
Photoactive Yellow Protein ◽  
Excited State Dynamics

scholarly journals Breaking the Symmetry of Pyrimidine: Solvent Effects and Core-Excited State Dynamics

2021 ◽  
pp. 8637-8643
Author(s):  
Sebastian Eckert ◽  
Vinícius Vaz da Cruz ◽  
Miguel Ochmann ◽  
Inga von Ahnen ◽  
Alexander Föhlisch ◽  
...  
Keyword(s):  
Excited State ◽  
Solvent Effects ◽  
Excited State Dynamics

Excited-State Dynamics in the RNA Nucleotide Uridine 5’-Monophosphate Investigated by Femtosecond Broadband Transient Absorption Spectroscopy

2019 ◽  
Author(s):  
Matthew M. Brister ◽  
Carlos Crespo-Hernández
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Transient Absorption ◽  
Electronic Energy ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Vibrationally Excited ◽  
Excited State Dynamics ◽  
Π State

<p></p><p> Damage to RNA from ultraviolet radiation induce chemical modifications to the nucleobases. Unraveling the excited states involved in these reactions is essential, but investigations aimed at understanding the electronic-energy relaxation pathways of the RNA nucleotide uridine 5’-monophosphate (UMP) have not received enough attention. In this Letter, the excited-state dynamics of UMP is investigated in aqueous solution. Excitation at 267 nm results in a trifurcation event that leads to the simultaneous population of the vibrationally-excited ground state, a longlived <sup>1</sup>n<sub>O</sub>π* state, and a receiver triplet state within 200 fs. The receiver state internally convert to the long-lived <sup>3</sup>ππ* state in an ultrafast time scale. The results elucidate the electronic relaxation pathways and clarify earlier transient absorption experiments performed for uracil derivatives in solution. This mechanistic information is important because long-lived nπ* and ππ* excited states of both singlet and triplet multiplicities are thought to lead to the formation of harmful photoproducts.</p><p></p>

Modulation of Excited State Dynamics in Lead Halide Perovskite Films with Electrical Bias

2019 ◽  
Author(s):  
Gergely Samu ◽  
R.A. Scheidt ◽  
A. Balog ◽  
C. Janáky ◽  
P.V. Kamat
Keyword(s):  
Excited State ◽  
Excited State Dynamics ◽  
Halide Perovskite ◽  
Electrical Bias ◽  
Lead Halide
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