The preparation of modified boehmite/PMMA nanocomposites by in situ polymerization and the assessment of their capability for Cu2+ ion removal

2016 ◽  
Vol 40 (4) ◽  
pp. 3612-3621 ◽  
Author(s):  
Gholamhossein Mohammadnezhad ◽  
Mohammad Dinari ◽  
Roozbeh Soltani
Keyword(s):  
Thermal Properties ◽  
Polymer Matrix ◽  
Active Sites ◽  
In Situ Polymerization ◽  
Ion Removal

The addition of nanoboehmite as a nanofiller into the polymer matrix led to the improvement of the thermal properties and increased the active sites of nanocomposites for Cu(ii) removal.

Synthesis and Characterizations of Poly(Butylene Succinate) Copolyester

2014 ◽  
Vol 1015 ◽  
pp. 381-384
Author(s):  
Li Liu ◽  
Li Hai Cai ◽  
Dan Liu ◽  
Jun Xu ◽  
Bao Hua Guo
Keyword(s):  
Mechanical Properties ◽  
Polymer Matrix ◽  
Crystallization Temperature ◽  
In Situ Polymerization ◽  
Nucleating Agent ◽  
Single Fiber ◽  
Butylene Succinate ◽  
Crystallization Behaviors ◽  
Polymerization Method

The poly (butylene succinate) (PBS) and 3 wt% attapulgite (ATP) reinforced PBS/ATP nanocomposites with 1,6-hexanediol were fabricated using an in situ polymerization method. The crystallization behaviors indicated that ATP had effectively acted as nucleating agent, resulting in the enhancement on the crystallization temperature. The SEM results showed a superior interfacial linkage between ATP and PBS. Also, ATP could disperse as a single fiber and embed in the polymer matrix, which resulted in the improved mechanical properties.

Development of Some Promising Approaches for The Toughening of High-Temperature Polymers

1998 ◽  
Vol 519 ◽  
Author(s):  
C. Kumudinie ◽  
J. K. Premachandra ◽  
J. E. Mark ◽  
T. D. Dang ◽  
M. R. Unroe ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Optical Properties ◽  
Thermal Properties ◽  
High Temperature ◽  
Polymer Matrix ◽  
Hybrid Material ◽  
Arylene Ether ◽  
Rubbery Phase ◽  
Maximum Extensibility

AbstractHigh-temperature poly(arylene ether) and hydroxypolybenzoxazole polymers were toughened using dispersed rubbery phases. This rubbery phase was a hybrid material which was in-situ generated within the polymer matrix using mixtures of partially-hydrolyzable trialkoxy and dialkoxy organosilanes with a fully hydrolyzable tetraalkoxysilane. The resulting materials were characterized with regard to their structures, mechanical properties (modulus, ultimate strength, maximum extensibility, and toughness), thermal properties, optical properties, and tendencies to absorb water. Some of the results are presented here.

scholarly journals Structural, morphological and thermal properties of nanocomposites poly(GMA)/clay prepared by ultrasound and in-situ polymerization

2018 ◽  
Vol 48 ◽  
pp. 188-198 ◽  
Author(s):  
Zakaria Cherifi ◽  
Bouhadjar Boukoussa ◽  
Aniss Zaoui ◽  
Mohammed Belbachir ◽  
Rachid Meghabar
Keyword(s):  
Thermal Properties ◽  
In Situ Polymerization

scholarly journals PA6 and Halloysite Nanotubes Composites with Improved Hydrothermal Ageing Resistance: Role of Filler Physicochemical Properties, Functionalization and Dispersion Technique

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 211 ◽  
Author(s):  
Valentina Sabatini ◽  
Tommaso Taroni ◽  
Riccardo Rampazzo ◽  
Marco Bompieri ◽  
Daniela Maggioni ◽  
...  
Keyword(s):  
Physicochemical Properties ◽  
Polymer Matrix ◽  
In Situ Polymerization ◽  
Cost Effective ◽  
Polyamide 6 ◽  
Halloysite Nanotubes ◽  
Amide Bonds ◽  
Molecular Weights ◽  
Dispersion Technique

Polyamide 6 (PA6) suffers from fast degradation in humid conditions due to hydrolysis of amide bonds, which limits its durability. The addition of nanotubular fillers represents a viable strategy for overcoming this issue, although the additive/polymer interface at high filler content can become privileged site for moisture accumulation. As a cost-effective and versatile material, halloysite nanotubes (HNT) were investigated to prepare PA6 nanocomposites with very low loadings (1–45% w/w). The roles of the physicochemical properties of two differently sourced HNT, of filler functionalization with (3-aminopropyl)triethoxysilane and of dispersion techniques (in situ polymerization vs. melt blending) were investigated. The aspect ratio (5 vs. 15) and surface charge (−31 vs. −59 mV) of the two HNT proved crucial in determining their distribution within the polymer matrix. In situ polymerization of functionalized HNT leads to enclosed and well-penetrated filler within the polymer matrix. PA6 nanocomposites crystal growth and nucleation type were studied according to Avrami theory, as well as the formation of different crystalline structures (α and γ forms). After 1680 h of ageing, functionalized HNT reduced the diffusion of water into polymer, lowering water uptake after 600 h up to 90%, increasing the materials durability also regarding molecular weights and rheological behavior.

scholarly journals Delaminated Polymer/Lamellar Aluminophosphate Nanocomposites Prepared via in SITU Polymerization

2006 ◽  
Vol 15 (5) ◽  
pp. 096369350601500 ◽  
Author(s):  
Jingyu Wang ◽  
Guoping Chen ◽  
Quan Zhou
Keyword(s):  
Polymer Matrix ◽  
In Situ Polymerization ◽  
Short Chain ◽  
Long Chain

A method to synthesize completely delaminated polymer/lamellar aluminophosphate (Mu-4) nanocomposites has been successfully developed, wherein organo-modification of Mu-4 followed by in situ polymerization was applied. It can be found that the long chain n-dodecylamine molecules can favor the intercalation of Mu-4 and thus readily make the Mu-4 layers delaminated in the polymer matrix compared with the short chain N,N-dimethylpropane-1,3-diamine.

Fabrication Polyurethane/Expanded Graphite Powder Composite Antistatic Sponge by In Situ Polymerization

2012 ◽  
Vol 479-481 ◽  
pp. 395-398
Author(s):  
Dan Qing Chen
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
In Situ Polymerization ◽  
Expanded Graphite ◽  
Graphite Powder ◽  
Polymeric Matrix ◽  
Powder Composite

This document explains and demonstrates how to prepare Polyurethane(PU)/Expanded Graphite powder(EGp) composite antistatic sponge by in situ polymerization. The morphology、mechanical、electrical and thermal properties of the PU/EGp composite antistatic sponge have been investigated. PU/ EGp composite sponge have better mechanical properties than that of CB composite. The resistivity of PU/EGp composite antistatic sponge can reach at about 108Ω•cm at the content around 5wt% of the EGp. EGp can stably exist in PU sponge and has little influence to the polymeric matrix while being heated.

Characterization and Thermal Properties of the Microencapsulated PCM Slurry

2011 ◽  
Vol 284-286 ◽  
pp. 940-944 ◽  
Author(s):  
Yan Lai Zhang ◽  
Zhong Hao Rao ◽  
Shuang Feng Wang ◽  
Hong Zhang ◽  
Li Jun Li ◽  
...  
Keyword(s):  
Thermal Properties ◽  
In Situ Polymerization ◽  
Membrane Thickness ◽  
Fluid Behavior ◽  
Microencapsulated Phase Change Material ◽  
Paraffin Waxes ◽  
Latent Heats ◽  
Change Material ◽  
Polymerization Method

The microencapsulated phase change material (PCM) slurry is a kind of mixture with the PCM microcapsule particles and water. The actual PCM in the microcapsule is composed of several kinds of paraffin waxes (mainly nonadecane), and the membrane is a type of melamine resin. This study is focused on preparation, characterization, and thermal properties of the microencapsulated (PCM) slurry. The microencapsulated PCM particles are prepared by in-situ polymerization method. Four different levels of mass concentration Cm of the PCM will be used such as Cm=10%, 20%, 30% and 40%, respectively. The diameter of the particles is distributed in the range of 0µm~4.5µm, and most (61%) of them occur in the range of 0.5µm~1.5µm. The average volumetric diameter of the PCM microcapsule particle is about 0.78µm. And the average membrane thickness is about 11nm.Thermal properties of the microencapsulated PCM slurry are determined using differential scanning calorimeter (DSC). From DSC analysis, the melting and freezing temperatures and the latent heats of Cm=30% are measured as 38°C and 25°C, and 37.9 kJ/kg, respectively. The rheological properties are measured by a rotating cylinder type of rheometer, which the slurry shows the pseudo plastic non-Newtonian fluid behavior with the power-law fluid index n.

Mechanical and thermal properties of hybrid nanocomposites prepared by in situ polymerization

Polimery ◽  
2016 ◽  
Vol 61 (03) ◽  
pp. 172-180 ◽  
Author(s):  
Sandra Paszkiewicz ◽  
Iwona Pawelec ◽  
Anna Szymczyk ◽  
Zbigniew Roslaniec
Keyword(s):  
Thermal Properties ◽  
In Situ Polymerization ◽  
Hybrid Nanocomposites ◽  
Mechanical And Thermal Properties
Sign in / Sign up

Export Citation Format

Share Document