Eco-friendly Suzuki–Miyaura coupling of arylboronic acids to aromatic ketones catalyzed by the oxime-palladacycle in biosolvent 2-MeTHF

2016 ◽  
Vol 40 (4) ◽  
pp. 3119-3123 ◽  
Author(s):  
Manoj Mondal ◽  
Utpal Bora
Keyword(s):  
Green Chemistry ◽  
Sugar Cane ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Aromatic Ketones ◽  
Acyl Chlorides ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction ◽  
Reaction Proceeds ◽  
Aryl Ketones

Oxime-palladacycle catalyzed aerobic cross-coupling reaction of arylboronic acids and acyl chlorides to yield aryl ketones was developed. The reaction proceeds efficiently in 2-MeTHF, which is derived from corncobs, sugar cane, and fulfils the 3rd, 5th and 7th principles of Green Chemistry.

scholarly journals A phosphine-free, atom-efficient cross-coupling reaction of triorganoindiums with acyl chlorides catalyzed by immobilization of palladium(0) in MCM-41

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42570-42578 ◽  
Author(s):  
Jiankang Miao ◽  
Bin Huang ◽  
Haiyi Liu ◽  
Mingzhong Cai
Keyword(s):  
Schiff Base ◽  
Schiff Base Complex ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Free Atom ◽  
Acyl Chlorides ◽  
Base Complex ◽  
Cross Coupling Reaction ◽  
Mcm 41

The phosphine-free, atom-efficient cross-coupling of triorganoindiums with acyl chlorides has been achieved using a recyclable MCM-41-immobilized palladium(0)–Schiff base complex.

scholarly journals Efficient in situ N-heterocyclic carbene palladium(ii) generated from Pd(OAc)2 catalysts for carbonylative Suzuki coupling reactions of arylboronic acids with 2-bromopyridine under inert conditions leading to unsymmetrical arylpyridine ketones: synthesis, characterization and cytotoxic activities

RSC Advances ◽  
2018 ◽  
Vol 8 (70) ◽  
pp. 40000-40015 ◽  
Author(s):  
Nedra Touj ◽  
Abdullah S. Al-Ayed ◽  
Mathieu Sauthier ◽  
Lamjed Mansour ◽  
Abdel Halim Harrath ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Suzuki Coupling ◽  
Boronic Acids ◽  
Cytotoxic Activities ◽  
Coupling Reactions ◽  
Component System ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction

The in situ prepared four component system Pd(OAc)2, 1,3-dialkylbenzimidazolium halides 2a–i and 4a–i, K2CO3 under CO atmosphere catalyses carbonylative cross-coupling reaction of 2-bromopyridine with various boronic acids to yield unsymmetrical arylpyridine ketones.

Cross-coupling reaction between arylboronic acids and carboranyl iodides catalyzed by graphene oxide (GO)-supported Pd(0) recyclable nanoparticles for the synthesis of carboranylaryl ketones

2014 ◽  
Vol 43 (13) ◽  
pp. 5014-5020 ◽  
Author(s):  
Algin Oh Biying ◽  
Venu R. Vangala ◽  
Chia Sze Chen ◽  
Ludger Paul Stubs ◽  
Narayan S. Hosmane ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction ◽  
Supported Pd
Sign in / Sign up

Export Citation Format

Share Document