Bioinspired nanophotosensitizers: synthesis and characterization of porphyrin–noble metal nanoparticle conjugates

2016 ◽  
Vol 40 (1) ◽  
pp. 724-731 ◽  
Author(s):  
Jayeeta Bhaumik ◽  
Gitanjali Gogia ◽  
Seema Kirar ◽  
Lekshmi Vijay ◽  
Neeraj S. Thakur ◽  
...  

Conjugatable and compact porphyrinic photosensitizer nanoparticle conjugates were developed through rational synthesis followed by conjugation with noble metal nanoparticles.

2009 ◽  
Vol 620-622 ◽  
pp. 185-188 ◽  
Author(s):  
Yamato Hayashi ◽  
Masahiro Inoue ◽  
Ichitito Narita ◽  
Katsuaki Suganuma ◽  
Hirotsugu Takizawa

Applications of various noble metal nanoparticles were investigated for newly, ecology and economy home electric appliances (microwave, ultrasonic) used system. Noble metal oxides have merit in metal particles fabrication, as one of these example example, there are decomposed by only heating in air. That is, noble metal oxide don't use strong reduction atmosphere. This reduction is ecologically clean, because many noble metal oxides are not toxic and during decomposition O2 is evolved. We have reduced noble metal oxides by microwave and ultrasound, and tried to fabricate noble metal nanoparticles, and investigated various processing. These energy are widely used by home electric appliances. By choosing suitable process and conditions, it is reasonable to expect that home electric appliances ecology and economy fabrications can be extended to obtain simply various noble metal nanoparticles related materials.


2014 ◽  
Vol 5 ◽  
pp. 2413-2423 ◽  
Author(s):  
Rudolf Herrmann ◽  
Markus Rennhak ◽  
Armin Reller

The present review article covers work done in the cluster NPBIOMEM in the DFG priority programme SPP 1313 and focuses on synthesis and characterization of fluorescent silica and ceria nanoparticles. Synthetic methods for labelling of silica and polyorganosiloxane/silica core–shell nanoparticles with perylenediimide derivatives are described, as well as the modification of the shell with thiol groups. Photometric methods for the determination of the number of thiol groups and an estimate for the number of fluorescent molecules per nanoparticles, including a scattering correction, have been developed. Ceria nanoparticles decorated with noble metals (Pt, Pd, Rh) are models for the decomposition products of automobile catalytic converters which appear in the exhaust gases and finally interact with biological systems including humans. The control of the degree of agglomeration of small ceria nanoparticles is the basis for their synthesis. Almost monodisperse agglomerates (40 ± 4–260 ± 40 nm diameter) can be prepared and decorated with noble metal nanoparticles (2–5 nm diameter). Fluorescence labelling with ATTO 647N gave the model particles which are now under biophysical investigation.


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