The synthesis of shape-controlled α-MoO3/graphene nanocomposites for high performance supercapacitors

2015 ◽  
Vol 39 (11) ◽  
pp. 8780-8786 ◽  
Author(s):  
Jinhua Zhou ◽  
Juan Song ◽  
Huihua Li ◽  
Xiaomiao Feng ◽  
Zhendong Huang ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Cycle Stability ◽  
Graphene Nanocomposites ◽  
Shape Controlled

Novel nanoflake-like α-MoO3/graphene nanocomposites were synthesized and exhibited a high specific capacitance of up to 360 F g−1 and excellent long term cycle stability.

Facile synthesis of exfoliated Co–Al LDH–carbon nanotube composites with high performance as supercapacitor electrodes

2014 ◽  
Vol 16 (33) ◽  
pp. 17936-17942 ◽  
Author(s):  
Lei Yu ◽  
Nannan Shi ◽  
Qi Liu ◽  
Jun Wang ◽  
Bin Yang ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Cycle Stability ◽  
Facile Synthesis ◽  
Nanotube Composites ◽  
Carbon Nanotube Composites

A novel sandwich-like structured Co–Al LDH–CNT composite has been successfully synthesized. The as-prepared Co–Al LDHs–CNTs composite exhibites a high specific capacitance and a good cycle stability over 2000 cycles

A three-dimensional graphene aerogel containing solvent-free polyaniline fluid for high performance supercapacitors

Nanoscale ◽  
2017 ◽  
Vol 9 (45) ◽  
pp. 17710-17716 ◽  
Author(s):  
Zhaodongfang Gao ◽  
Junwei Yang ◽  
Jing Huang ◽  
Chuanxi Xiong ◽  
Quanling Yang
Keyword(s):  
Specific Capacitance ◽  
Conducting Polymer ◽  
High Performance ◽  
Three Dimensional ◽  
High Specific Capacitance ◽  
Solvent Free ◽  
Graphene Aerogel ◽  
Term Stability ◽  
Long Term Stability

Conducting polymer based supercapacitors usually suffer from the difficulty of achieving high specific capacitance and good long-term stability simultaneously.

A cost effective, highly porous, manganese oxide/carbon supercapacitor material with high rate capability

2016 ◽  
Vol 4 (15) ◽  
pp. 5390-5394 ◽  
Author(s):  
Rongfang Wang ◽  
Yuanyuan Ma ◽  
Hui Wang ◽  
Julian Key ◽  
Dan Brett ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Carbon Material ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Cost Effective ◽  
High Rate ◽  
Cycle Stability ◽  
High Rate Capability ◽  
Highly Porous

A porous, cube-shaped, Mn2O3/carbon material has been prepared and it shows a high specific capacitance of 349.6 F g−1 at 50 mA g−1 and excellent long-term cycle stability after 2000 cycles.

Poly(aniline-co-pyrrole)-coated Ni-doped manganese dioxide as electrode materials for supercapacitors

2020 ◽  
Vol 13 (02) ◽  
pp. 2051007
Author(s):  
Jie Dong ◽  
Qinghao Yang ◽  
Qiuli Zhao ◽  
Zhenzhong Hou ◽  
Yue Zhou ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Manganese Dioxide ◽  
Specific Capacitance ◽  
Electrode Materials ◽  
High Specific Capacitance ◽  
Cycle Stability ◽  
Mass Ratio ◽  
Scan Rate ◽  
Poly Aniline ◽  
Inorganic And Organic

Electrode materials with a high specific capacitance, outstanding reversibility and excellent cycle stability are constantly pursued for supercapacitors. In this paper, we present an approach to improve the electrochemical performance by combining the advantages of both inorganic and organic. Ni-MnO2/PANi-co-PPy composites are synthesized, with the copolymer of aniline/pyrrole being coated on the surface of Ni-doped manganese dioxide nanospheres. The inorganic–organic composite enables a substantial increase in its specific capacitance and cycle stability. When the mass ratio of Ni-MnO2 to aniline and pyrrole mixed monomer is 1:5, the composite delivers high specific capacitance of 445.49[Formula: see text]F/g at a scan rate of 2[Formula: see text]mV/s and excellent cycle stability of 61.65% retention after 5000 cycles. The results indicate that the Ni-MnO2/PANi-co-PPy composites are promising electrode materials for future supercapacitors application.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

scholarly journals Atomic Modulation of 3D Conductive Frameworks Boost Performance of MnO2 for Coaxial Fiber-Shaped Supercapacitors

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Xiaona Wang ◽  
Zhenyu Zhou ◽  
Zhijian Sun ◽  
Jinho Hah ◽  
Yagang Yao ◽  
...  
Keyword(s):  
Energy Density ◽  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Superior Performance ◽  
High Mass ◽  
Mass Loading ◽  
Energy Storage Devices ◽  
Free Standing ◽  
Cell Potential

Abstract Coaxial fiber-shaped supercapacitors are a promising class of energy storage devices requiring high performance for flexible and miniature electronic devices. Yet, they are still struggling from inferior energy density, which comes from the limited choices in materials and structure used. Here, Zn-doped CuO nanowires were designed as 3D framework for aligned distributing high mass loading of MnO2 nanosheets. Zn could be introduced into the CuO crystal lattice to tune the covalency character and thus improve charge transport. The Zn–CuO@MnO2 as positive electrode obtained superior performance without sacrificing its areal and gravimetric capacitances with the increasing of mass loading of MnO2 due to 3D Zn–CuO framework enabling efficient electron transport. A novel category of free-standing asymmetric coaxial fiber-shaped supercapacitor based on Zn0.11CuO@MnO2 core electrode possesses superior specific capacitance and enhanced cell potential window. This asymmetric coaxial structure provides superior performance including higher capacity and better stability under deformation because of sufficient contact between the electrodes and electrolyte. Based on these advantages, the as-prepared asymmetric coaxial fiber-shaped supercapacitor exhibits a high specific capacitance of 296.6 mF cm−2 and energy density of 133.47 μWh cm−2. In addition, its capacitance retention reaches 76.57% after bending 10,000 times, which demonstrates as-prepared device’s excellent flexibility and long-term cycling stability.

Hierarchical NiCo2O4 nanosheets@hollow microrod arrays for high-performance asymmetric supercapacitors

2014 ◽  
Vol 2 (13) ◽  
pp. 4706-4713 ◽  
Author(s):  
Xue-Feng Lu ◽  
Dong-Jun Wu ◽  
Run-Zhi Li ◽  
Qi Li ◽  
Sheng-Hua Ye ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Thermal Annealing ◽  
High Performance ◽  
Cycle Stability ◽  
Asymmetric Supercapacitors ◽  
Environmental Friendly ◽  
Nico2o4 Nanosheets

Novel NiCo2O4 NSs@HNRAs are fabricated via a simple and environmental friendly template-assisted electrodeposition followed by thermal annealing and they exhibit predominant electrochemical properties and long-term cycle stability.

scholarly journals Dissected carbon nanotubes functionalized by 1-hydroxyanthraquinone for high-performance asymmetric supercapacitors

RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 48341-48353 ◽  
Author(s):  
Xia Yang ◽  
Yuying Yang ◽  
Quancai Zhang ◽  
Xiaotong Wang ◽  
Yufeng An ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Graphene Oxide ◽  
Specific Capacitance ◽  
Reduced Graphene Oxide ◽  
High Performance ◽  
Rate Capability ◽  
High Specific Capacitance ◽  
Covalent Modification ◽  
Asymmetric Supercapacitors ◽  
Reduced Graphene

1-Hydroxyanthraquinone (HAQ) is selected to functionalize the dissected carbon nanotubes (rDCNTs) with reduced graphene oxide layers through non-covalent modification. The composite achieves high specific capacitance and ultrahigh rate capability.

Unique MOF-derived hierarchical MnO2 nanotubes@NiCo-LDH/CoS2 nanocage materials as high performance supercapacitors

2019 ◽  
Vol 7 (19) ◽  
pp. 12018-12028 ◽  
Author(s):  
Xiuhua Wang ◽  
Feifei Huang ◽  
Fang Rong ◽  
Peng He ◽  
Ronghui Que ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
High Performance ◽  
High Stability ◽  
High Specific Capacitance ◽  
One Dimensional

A new one-dimensional hierarchical hollow MnO2 nanotubes@NiCo-LDH/CoS2 nanocage supercapacitor, MnO2@NiCo-LDH/CoS2, achieves a high specific capacitance and high stability.

Facile Preparation of Holey Anderson-type Polyoxometalate/Polyaniline/Graphene Nanocomposites for Supercapacitors

NANO ◽  
2019 ◽  
Vol 14 (04) ◽  
pp. 1950049 ◽  
Author(s):  
Jingjing Lin ◽  
Song Yan ◽  
Xiaojie Zhang ◽  
Yueran Liu ◽  
Jun Lian ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
High Performance ◽  
High Specific Capacitance ◽  
High Energy ◽  
Cycling Stability ◽  
High Energy Density ◽  
Graphene Nanocomposites ◽  
Graphene Layers ◽  
Cycle Times ◽  
Excellent Electrochemical Performance

Holey Fe-Anderson-type polyoxometalate/polyaniline/graphene (PPG) hybrid materials were first prepared by anchoring Anderson-type polyoxometalates [FeMo6O[Formula: see text]H6][Formula: see text] (FeMo[Formula: see text] onto graphene modified with polyaniline via a facile hydrothermal treatment. The as-prepared materials exhibited an excellent electrochemical performance with a high specific capacitance of 1366 F g[Formula: see text] at 1 A g[Formula: see text] and outstanding cycling stability (97.6% capacitance retention after 5000 cycle times). The uptake of polyaniline/FeMo6 nanoparticles on graphene not only provided the pseudocapacitance but also weakened the aggregation between the graphene layers, resulting in a higher surface area compared with pure graphene. In addition, the AC//PPG-15 asymmetric supercapacitor device showed a high energy density of 24.65[Formula: see text]W h kg[Formula: see text] at a low power density of 326.25[Formula: see text]W kg[Formula: see text] and good cycling stability (94.82% capacitance retention after 5000 cycles). Hence, the as-prepared PPG hybrid materials in this work possess tremendous potential as electrodes for high-performance supercapacitors.

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