Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines

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Half-sandwich Y/Li ate complex displays better catalytic activity for phosphaguanylation reaction of phosphines with carbodiimides than the neutral yttrium complexes.

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Rare earth metal doped ZrO2 can promote the formation of oxygen vacancies in zirconia, which enhances the metal–support interaction, finally promoting catalytic activity of FA dehydrogenation.


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