Ru–B nanoparticles on metal–organic frameworks as excellent catalysts for hydrogenation of benzene to cyclohexane under mild reaction conditions

2016 ◽  
Vol 18 (7) ◽  
pp. 2216-2221 ◽  
Author(s):  
Huizi Bi ◽  
Xiaohe Tan ◽  
Rongfei Dou ◽  
Yan Pei ◽  
Minghua Qiao ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Turnover Frequency ◽  
High Turnover ◽  
Reaction Conditions ◽  
Metal Organic

Ru–B/MIL-53(AlCr) affords an exceptionally high turnover frequency (TOF) of 6.4 s−1for hydrogenation of benzene to cyclohexane under mild reaction conditions.

Exfoliation of metal–organic frameworks into efficient single-layer metal–organic nanosheet electrocatalysts by the synergistic action of host–guest interactions and sonication

Nanoscale ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 3623-3629 ◽  
Author(s):  
Wei Pang ◽  
Bing Shao ◽  
Xiao-Qiong Tan ◽  
Cong Tang ◽  
Zhong Zhang ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Metal Organic Frameworks ◽  
Single Layer ◽  
Synergistic Action ◽  
Turnover Frequency ◽  
High Turnover ◽  
Metal Organic

Rapid exfoliation of pillared-layer metal–organic frameworks into single-layer metal–organic nanosheets for a high turnover frequency of water oxidation.

Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO2under Mild Reaction Conditions

2013 ◽  
Vol 126 (4) ◽  
pp. 1052-1056 ◽  
Author(s):  
Sibo Wang ◽  
Wangshu Yao ◽  
Jinliang Lin ◽  
Zhengxin Ding ◽  
Xinchen Wang
Keyword(s):  
Metal Organic Frameworks ◽  
Reaction Conditions ◽  
Metal Organic

Conformational isomerism involving carboxylate groups of a linker in metal organic frameworks and its distinctive influence on the detection of ketones

2021 ◽  
Author(s):  
Sandeep Kumar ◽  
Himanshi Bhambri ◽  
Sanjay Mandal
Keyword(s):  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Product Formation ◽  
Conformational Isomerism ◽  
Reaction Conditions ◽  
Carboxylate Groups ◽  
Metal Organic ◽  
Influence Of Solvent

In this work, the influence of solvent and reaction conditions (solvothermal vs room temperature) on the product formation is analyzed with two Zn(II) MOFs, {[Zn(bpaipa)]·DMF·2H2O}n (1) and {[Zn(bpaipa)]·5H2O}n (2), where...

Cobalt Imidazolate Metal-Organic Frameworks Photosplit CO2under Mild Reaction Conditions

2013 ◽  
Vol 53 (4) ◽  
pp. 1034-1038 ◽  
Author(s):  
Sibo Wang ◽  
Wangshu Yao ◽  
Jinliang Lin ◽  
Zhengxin Ding ◽  
Xinchen Wang
Keyword(s):  
Metal Organic Frameworks ◽  
Reaction Conditions ◽  
Metal Organic

Constructing novel Cd(ii) metal–organic frameworks based on different highly connected secondary building units via alteration of reaction conditions

2015 ◽  
Vol 44 (47) ◽  
pp. 20361-20366 ◽  
Author(s):  
Yan-Qing Liu ◽  
Guo-Jian Ren ◽  
Ying-Hui Zhang ◽  
Jian Xu ◽  
Xian-He Bu
Keyword(s):  
Metal Organic Frameworks ◽  
Reaction Conditions ◽  
Secondary Building Units ◽  
Metal Organic

Upon the reaction of Cd(ii) ions and 4-Ptz ligands under different conditions, three new Cd(ii) metal–organic frameworks were constructed based on different highly connected secondary building units.

Organically-functionalised supertetrahedra as building blocks for hybrid materials

2008 ◽  
Vol 1148 ◽  
Author(s):  
Paz Vaqueiro ◽  
M Lucia Romero
Keyword(s):  
Crystal Structures ◽  
Hybrid Materials ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Organic Ligands ◽  
Reaction Conditions ◽  
Metal Centers ◽  
Covalently Bonded ◽  
Metal Organic ◽  
Solvothermal Conditions

AbstractThe crystal structures of gallium sulfides prepared under solvothermal conditions, using 4-picoline as a solvent, are described. These materials contain [Ga10S16(NC6H7)4]2− clusters, in which the terminal S2− anions have been replaced by covalently bonded 4-picoline molecules. Whilst these phases contain isolated supertetrahedral clusters separated by organic moieties, linkage of such clusters via organic ligands is possible under suitable reaction conditions. These organically-functionalised supertetrahedra could therefore be used to design novel Metal-Organic frameworks (MOFs) in which the normally-encountered metal centers are replaced by supertetrahedral clusters.

The effect of reaction conditions on the nature of cadmium 1,3,5-benzenetricarboxylate metal–organic frameworks

2011 ◽  
Vol 366 (1) ◽  
pp. 303-309 ◽  
Author(s):  
Andrew D. Burrows ◽  
Christopher G. Frost ◽  
Mathivathani Kandiah ◽  
Luke L. Keenan ◽  
Mary F. Mahon ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Reaction Conditions ◽  
Metal Organic

Rational design and synthesis of a series of 3D lanthanide metal–organic frameworks with different structures driven by reaction conditions

CrystEngComm ◽  
2014 ◽  
Vol 16 (44) ◽  
pp. 10181-10188 ◽  
Author(s):  
Tingting Zhao ◽  
Lirong Zhang ◽  
Dongmei Wang ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Frameworks ◽  
Luminescence Properties ◽  
Reaction Conditions ◽  
Design And Synthesis ◽  
Metal Organic ◽  
Lanthanide Metal

A series of novel lanthanide metal–organic frameworks with three types of structures, moc, dia and a new topology, have been constructed and their luminescence properties were investigated.

scholarly journals Triazolium-Containing Metal–Organic Frameworks: Control of Catenation in 2D Copper(II) Paddlewheel Structures

2013 ◽  
Vol 66 (4) ◽  
pp. 409 ◽  
Author(s):  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
Christopher J. Sumby
Keyword(s):  
Benzoic Acid ◽  
Heterogeneous Catalyst ◽  
Click Reaction ◽  
Metal Organic Frameworks ◽  
Ester Hydrolysis ◽  
Charge Balance ◽  
Reaction Conditions ◽  
Metal Organic ◽  
Methyl Triflate

One approach to exploit metal–organic frameworks (MOFs) as heterogeneous catalyst platforms requires the development of materials containing groups that can be utilised to anchor a catalytic moiety into the links within the structure. Here we report the synthesis of the first integrated triazolium-containing MOF linker and the first MOFs containing linkers of this type. 1,4-Bis(4-benzoic acid)-1-methyl-1H-1,2,3-triazolium chloride, H2L1Me, was synthesised in three steps by a ‘click’ reaction of methyl 4-ethynylbenzoate with methyl 4-azidobenzoate, methylation using methyl triflate, followed by ester hydrolysis in overall 74 % yield. The equivalent neutral triazole precursor, 1,4-bis(4-benzoic acid)-1H-1,2,3-triazole hydrochloride, H2L1(HCl), was also prepared and a comparison of the chemistry with Zn(NO3)2·6H2O and Cu(NO3)2·3H2O is presented. The results support the use of reaction conditions to control interpenetration and provide additional evidence that the charge on structurally similar ligands can drastically alter the types of structures that are accessible due to the requirements for charge balance in the final product.

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