A high-performance sandwiched-porous polybenzimidazole membrane with enhanced alkaline retention for anion exchange membrane fuel cells

2015 ◽  
Vol 8 (9) ◽  
pp. 2768-2774 ◽  
Author(s):  
L. Zeng ◽  
T. S. Zhao ◽  
L. An ◽  
G. Zhao ◽  
X. H. Yan

Polybenzimidazole (PBI)-based membrane electrode assemblies are fabricated with a sandwiched-porous PBI as the membrane and a new catalyst structure using PBI-decorated reduced graphene oxide as the supporting material for anion exchange membrane fuel cells.

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 690
Author(s):  
Ji Eon Chae ◽  
So Young Lee ◽  
Sung Jong Yoo ◽  
Jin Young Kim ◽  
Jong Hyun Jang ◽  
...  

Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel–Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the membrane electrode assembly in anion-exchange membrane fuel cells (AEMFCs). Structural analyses reveal that the molecular weight of the polystyrene backbone ranges from 10,000 to 63,000 g mol−1, while the ion exchange capacity of quaternary-ammonium-group-bearing ionomers ranges from 1.44 to 1.74 mmol g−1. The performance of AEMFCs constructed using the prepared electrode ionomers is affected by several ionomer properties, and a maximal power density of 407 mW cm−2 and a durability exceeding that of a reference cell with a commercially available ionomer are achieved under optimal conditions. Thus, the developed approach is concluded to be well suited for the fabrication of next-generation electrode ionomers for high-performance AEMFCs.


2021 ◽  
Vol 512 ◽  
pp. 230474
Author(s):  
Nanjun Chen ◽  
Sun Pyo Kim ◽  
Chuan Hu ◽  
Ho Hyun Wang ◽  
Jong Hyeong Park ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (31) ◽  
pp. 19153-19161 ◽  
Author(s):  
Xueqiang Gao ◽  
Hongmei Yu ◽  
Jia Jia ◽  
Jinkai Hao ◽  
Feng Xie ◽  
...  

The anion exchange ionomer incorporated into the electrodes of an anion exchange membrane fuel cell (AEMFC) enhances anion transport in the catalyst layer of the electrode, and thus improves performance and durability of the AEMFC.


2012 ◽  
Vol 202 ◽  
pp. 70-77 ◽  
Author(s):  
Lu Sun ◽  
Junsong Guo ◽  
Jie Zhou ◽  
Qingming Xu ◽  
Deryn Chu ◽  
...  

2013 ◽  
Vol 221 ◽  
pp. 247-251 ◽  
Author(s):  
Yun Zhao ◽  
Hongmei Yu ◽  
Donglei Yang ◽  
Jin Li ◽  
Zhigang Shao ◽  
...  

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