Varying the ionic functionalities of conjugated polyelectrolytes leads to both p- and n-type carbon nanotube composites for flexible thermoelectrics

2015 ◽  
Vol 8 (8) ◽  
pp. 2341-2346 ◽  
Author(s):  
Cheng-Kang Mai ◽  
Boris Russ ◽  
Stephanie L. Fronk ◽  
Nan Hu ◽  
Mary B. Chan-Park ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Single Walled Carbon Nanotubes ◽  
Conjugated Polyelectrolytes ◽  
Selective Doping ◽  
Single Walled Carbon ◽  
Nanotube Composites ◽  
Carbon Nanotube Composites ◽  
Walled Carbon Nanotubes

Selective doping of single-walled carbon nanotubes can be achieved by varying pendant ionic functionalities of conjugated polyelectrolytes.

Lipase on carbon nanotube - An active, selective, stable and easy to optimize nanobiocatalyst for kinetic resolutions

2021 ◽  
Author(s):  
Cristian Andrei Gal ◽  
Laura Edit Barabas ◽  
Judith Hajnal Bartha-Vari ◽  
Madalina Elena Moisa ◽  
Diana Balogh-Weiser ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Covalent Binding ◽  
Single Walled Carbon Nanotubes ◽  
Candida Antarctica ◽  
Flow Mode ◽  
Lipase B ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes ◽  
Kinetic Resolutions

An efficient nanobioconjugate of lipase B from Candida antarctica was prepared by the covalent binding on carboxy-functionalized single-walled carbon nanotubes and tested in batch and flow mode for the enzymatic...

scholarly journals Switching the optical and electrical properties of carbon nanotube hybrid films using a photoresponsive dispersant as a dopant

RSC Advances ◽  
2018 ◽  
Vol 8 (20) ◽  
pp. 11186-11190 ◽  
Author(s):  
H. Jintoku ◽  
Y. Matsuzawa ◽  
M. Yoshida
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Electrical Properties ◽  
Single Walled Carbon Nanotubes ◽  
Optical And Electrical Properties ◽  
Hybrid Films ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

The light-induced switching of the optical and electrical properties of single-walled carbon nanotubes hybrid films with photoresponsive dispersant.

Synthesis of flexible nanotweezers with various metals and their application in carbon nanotube extraction

2018 ◽  
Vol 42 (10) ◽  
pp. 7592-7594 ◽  
Author(s):  
Yuya Miyake ◽  
Alejandro López-Moreno ◽  
Jian Yang ◽  
Hai-Jun Xu ◽  
Nicolas Desbois ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Single Walled Carbon Nanotubes ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Flexible nanotweezers including Co(ii) dispersed single-walled carbon nanotubes in methanol.

Enhancing the Thermoelectric Performance through the Mutual Interaction between Conjugated Polyelectrolytes and Single-walled Carbon Nanotubes

2022 ◽  
Author(s):  
Shuxun Wan ◽  
Zhongming Chen ◽  
Liping Hao ◽  
Shichao Wang ◽  
Benzhang Li ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Thermoelectric Properties ◽  
Thermoelectric Generator ◽  
Composite Films ◽  
Single Walled Carbon Nanotubes ◽  
Conjugated Polyelectrolytes ◽  
High Performing ◽  
Single Walled Carbon ◽  
Electrical Conductivities ◽  
Walled Carbon Nanotubes

Abstract We present a method of constructing composites composed of conjugated polyelectrolytes (CPEs) and single-walled carbon nanotubes (SWCNTs) to obtain a high-performing flexible thermoelectric generator. In this approach, three kinds of polymers, namely, poly[(1,4-(2,5-didodecyloxybenzene)-alt-2,5-thiophene] (P1), poly[(1,4-(2,5-bis-sodium butoxysulfonate-phenylene)-alt-2,5-thiophene] (P2), and poly[(1,4-(2,5-bis-acid butoxysulfonic-phenylene)-alt-2,5-thiophene] (P3) are designed, synthesized and complexed with SWCNTs as thermoelectric composites. The electrical conductivities of CPEs/SWCNTs (P2/SWCNTs, and P3/SWCNTs) nanocomposites are much higher than those of non-CPEs/SWCNTs (P1/SWCNTs) nanocomposites. Among them, the electrical conductivity of P2/SWCNTs with a ratio of 1:4 reaches 3686 S cm-1, which is 12.4 times that of P1/SWCNTs at the same SWCNT mass ratio. Moreover, CPEs/SWCNTs composites (P2/SWCNTs) display remarkably improved thermoelectric properties with the highest power factor (PF) of 163 μW m-1 K-2. In addition, a thermoelectric generator is fabricated with P2/SWCNTs composite films, and the output power and power density of this generator reach 1.37 μW and 1.4 W m-2 (cross-section) at ΔT=70 K. This result is over three times that of the thermoelectric generator composed of non-CPEs/SWCNTs composite films (P1/SWCNTs, 0.37 μW). The remarkably improved electrical conductivities and thermoelectric properties of the CPEs/SWCNTs composites (P2/SWCNTs) are attributed to the enhanced interaction. This method for constructing CPEs/SWCNTs composites can be applied to produce thermoelectric materials and devices.

Holey single-walled carbon nanotubes for ultra-fast broadband bolometers

Nanoscale ◽  
2018 ◽  
Vol 10 (39) ◽  
pp. 18665-18671 ◽  
Author(s):  
Daria S. Kopylova ◽  
Fedor S. Fedorov ◽  
Alena A. Alekseeva ◽  
Evgenia P. Gilshteyn ◽  
Alexey P. Tsapenko ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Temperature Coefficient ◽  
Single Walled Carbon Nanotubes ◽  
Temperature Coefficient Of Resistance ◽  
Single Walled Carbon ◽  
Carbon Nanotube Network ◽  
Walled Carbon Nanotubes

A holey carbon nanotube network is designed to improve the performance of bolometers. The material possesses a temperature coefficient of resistance up to −2.8% K−1.

Vibrational analysis of sandwich sectorial plates with functionally graded sheets reinforced by aggregated carbon nanotube

2018 ◽  
Vol 22 (5) ◽  
pp. 1496-1541 ◽  
Author(s):  
Vahid Tahouneh
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
Boundary Conditions ◽  
Single Walled Carbon Nanotubes ◽  
Functionally Graded ◽  
Constitutive Law ◽  
Two Dimensional ◽  
Simply Supported ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

In the present work, by considering the agglomeration effect of single-walled carbon nanotubes, free vibration characteristics of functionally graded nanocomposite sandwich sectorial plates are presented. The volume fractions of randomly oriented agglomerated single-walled carbon nanotubes are assumed to be graded in the thickness direction. To determine the effect of carbon nanotube agglomeration on the elastic properties of carbon nanotube-reinforced composites, a two-parameter micromechanical model of agglomeration is employed. In this research work, an equivalent continuum model based on the Eshelby–Mori–Tanaka approach is considered to estimate the effective constitutive law of the elastic isotropic medium (matrix) with oriented straight carbon nanotubes. The two-dimensional generalized differential quadrature method as an efficient and accurate numerical tool is used to discretize the equations of motion and to implement the various boundary conditions. The proposed sectorial plates are simply supported at radial edges, while all possible combinations of free, simply supported, and clamped boundary conditions are applied to the other two circular edges. The benefit of using the considered power-law distribution is to illustrate and present useful results arising from symmetric and asymmetric profiles. The effects of agglomeration, geometrical, and material parameters together with the boundary conditions on the frequency parameters of the sandwich functionally graded nanocomposite plates are investigated. It is shown that the natural frequencies of structure are seriously affected by the influence of carbon nanotubes agglomeration. This study serves as a benchmark for assessing the validity of numerical methods or two-dimensional theories used to analyze the sandwich sectorial plates.

Highly efficient thermophones based on freestanding single-walled carbon nanotube films

2019 ◽  
Vol 4 (5) ◽  
pp. 1158-1163 ◽  
Author(s):  
Stepan A. Romanov ◽  
Ali E. Aliev ◽  
Boris V. Fine ◽  
Anton S. Anisimov ◽  
Albert G. Nasibulin
Keyword(s):  
Carbon Nanotubes ◽  
Carbon Nanotube ◽  
State Of The Art ◽  
Single Walled Carbon Nanotubes ◽  
The State ◽  
Single Walled Carbon Nanotube ◽  
Single Walled Carbon ◽  
Highly Efficient ◽  
Art Performance ◽  
Walled Carbon Nanotubes

We present the state-of-the-art performance of air-coupled thermophones made of thin, freestanding films of randomly oriented single-walled carbon nanotubes (SWCNTs).

Molecular dynamics simulations of single-walled carbon nanotubes and polynylon66

2019 ◽  
Vol 33 (23) ◽  
pp. 1950258 ◽  
Author(s):  
Danhui Zhang ◽  
Houbo Yang ◽  
Zhongkui Liu ◽  
Anmin Liu
Keyword(s):  
Carbon Nanotubes ◽  
Molecular Dynamics ◽  
Carbon Nanotube ◽  
High Performance ◽  
Single Walled Carbon Nanotubes ◽  
Md Simulations ◽  
Interfacial Interaction ◽  
Radius Of Gyration ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Polynylon66, as a kind of important engineering plastics, is widely used in various fields. In this work, we studied the interfacial interactions between polynylon66 and single-walled carbon nanotubes (SWCNTs) using molecular dynamics (MD) simulations. The results showed that the polynylon66 could interact with the SWCNTs and the mechanism of interfacial interaction between polynylon66 and SWCNTs was also discussed. Furthermore, the morphology of polynylon66 adsorbed to the surface of SWCNTs was investigated by the radius of gyration. Influence factors such as the initial angle between polynylon66 chain and nanotube axis, SWCNT radius and length of polynylon66 on interfacial adhesion of single-walled carbon nanotube-polymer and the radius of gyration of the polymers were studied. These results will help to better understand the interfacial interaction between polymer and carbon nanotube (CNT) and also guide the fabrication of high performance polymer/carbon nanotube nanocomposites.

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