scholarly journals Site-specific metal and ligand substitutions in a microporous Mn2+-based metal–organic framework

2016 ◽  
Vol 45 (10) ◽  
pp. 4431-4438 ◽  
Author(s):  
Michael Huxley ◽  
Campbell J. Coghlan ◽  
Alexandre Burgun ◽  
Andrew Tarzia ◽  
Kenji Sumida ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Structure Type ◽  
Mixed Ligand ◽  
Metal Exchange ◽  
Framework Structure ◽  
Site Specific ◽  
Metal Organic ◽  
Synthetic Metal ◽  
Specific Metal ◽  
Organic Framework

Mixed-ligand syntheses and post-synthetic metal exchange performed on the Mn3L3 structure type results in site-specific manipulations to the framework structure.

Mixed-Ligand Metal–Organic Framework for Two-Photon Responsive Photocatalytic C–N and C–C Coupling Reactions

ACS Catalysis ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 422-430 ◽  
Author(s):  
Hanning Li ◽  
Yang Yang ◽  
Cheng He ◽  
Le Zeng ◽  
Chunying Duan
Keyword(s):  
Metal Organic Framework ◽  
Mixed Ligand ◽  
Coupling Reactions ◽  
Two Photon ◽  
Metal Organic ◽  
Organic Framework

A Solvothermally in Situ Generated Mixed-ligand Approach for NLO-Active Metal−Organic Framework Materials

2005 ◽  
Vol 44 (12) ◽  
pp. 4148-4150 ◽  
Author(s):  
Yong-Tao Wang ◽  
Hai-Hua Fan ◽  
He-Zhou Wang ◽  
Xiao-Ming Chen
Keyword(s):  
Metal Organic Framework ◽  
Mixed Ligand ◽  
Framework Materials ◽  
Active Metal ◽  
Metal Organic ◽  
Organic Framework

Enantiopure vs. racemic metalloligands: impact on metal–organic framework structure and synthesis

2007 ◽  
pp. 4881 ◽  
Author(s):  
Sergio J. Garibay ◽  
Jay R. Stork ◽  
Zhenqiang Wang ◽  
Seth M. Cohen ◽  
Shane G. Telfer
Keyword(s):  
Metal Organic Framework ◽  
Framework Structure ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Metal–Organic‐Framework‐Derived Carbon Nanostructures for Site‐Specific Dual‐Modality Photothermal/Photodynamic Thrombus Therapy

2019 ◽  
Vol 6 (17) ◽  
pp. 1901378 ◽  
Author(s):  
Fengrong Zhang ◽  
Yuehong Liu ◽  
Jiani Lei ◽  
Shunhao Wang ◽  
Xunming Ji ◽  
...  
Keyword(s):  
Carbon Nanostructures ◽  
Metal Organic Framework ◽  
Site Specific ◽  
Dual Modality ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Facile isolation of a stable S6-symmetric methanol hexamer using the guest-free microporous metal-organic framework: zinc 5-tert-butyl isophthalate

2018 ◽  
Vol 233 (6) ◽  
pp. 429-435
Author(s):  
Samaila A. Jovial ◽  
James Raftery ◽  
Michael W. Anderson ◽  
Martin P. Attfield
Keyword(s):  
Metal Organic Framework ◽  
Structural Effect ◽  
Molecular Clusters ◽  
Ordered Structure ◽  
Framework Structure ◽  
Void Space ◽  
Tert Butyl ◽  
Metal Organic ◽  
Organic Framework

Abstract The ordered structure of the guest-free microporous metal-organic framework zinc 5-tert-butyl isophthalate {Zn[(CH3)3CC6H3(CO2)2]} has been determined and shown to be easily loaded with methanol to form {Zn[(CH3)3CC6H3(CO2)2]}·CH3OH. The methanol forms a S6-symmetric hexamer within the pores of the material that is uniquely defined by the void space and exerts a subtle structural effect on the framework structure of the host. The work demonstrates the use of this type of metal-organic framework as a matrix to isolate unique molecular clusters in a facile manner.

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