Controllable synthesis of Zn/Cd(ii) coordination polymers: dual-emissive luminescent properties, and tailoring emission tendency under varying excitation energies

2016 ◽  
Vol 45 (11) ◽  
pp. 4863-4878 ◽  
Author(s):  
Kai Xing ◽  
Ruiqing Fan ◽  
Song Gao ◽  
Xinming Wang ◽  
Xi Du ◽  
...  

With the help of rationally selected N-donor ligands, different dimensional architectures 1–5 have been synthesized and they display dual-emission properties.

2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Huiyuan Kou ◽  
Shujie Pang ◽  
Boyu Yang ◽  
Mao Wang ◽  
Juan Ding ◽  
...  

In this work, a new type of ratiometric fluorescent nanoprobe with dual-emission properties is designed and constructed. The dual-emission nanoprobe is prepared from fluorescent silicon nanoparticles (Si NPs) and carbon...


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