Asymmetric oxidation of vinyl- and ethynyl terthiophene ligands in triruthenium complexes

2016 ◽  
Vol 45 (2) ◽  
pp. 768-782 ◽  
Author(s):  
Jing Zhang ◽  
Chao-Fang Sun ◽  
Ming-Xing Zhang ◽  
František Hartl ◽  
Jun Yin ◽  
...  
Keyword(s):  
Asymmetric Oxidation ◽  
Oxidation Processes ◽  
Open Triangle

Newly synthesized open-triangle triruthenium vinyl and ethynyl terthiophene complexes exhibit stepwise laterally localized oxidation processes, as revealed by UV-vis-NIR and IR spectroelectrochemistry.

Studies on the Behavior Some Paints in Electro-insulating Fluid Based on Vegetable Esters

2018 ◽  
Vol 69 (5) ◽  
pp. 1139-1144
Author(s):  
Iosif Lingvay ◽  
Adriana Mariana Bors ◽  
Livia Carmen Ungureanu ◽  
Valerica Stanoi ◽  
Traian Rus
Keyword(s):  
Structural Changes ◽  
Oxidation Processes ◽  
High Oleic ◽  
Painting Materials ◽  
Insulating Paper ◽  
Different Types ◽  
Mechanism And Kinetics ◽  
Kinetics Of ◽  
Natural Ester

For the purpose of using three different types of painting materials for the inner protection of the transformer vats, their behavior was studied under actual conditions of operation in the transformer (thermal stress in electro-insulating fluid based on the natural ester in contact with copper for electro-technical use and electro-insulating paper). By comparing determination of the content in furans products (HPLC technique) and gases formed (by gas-chromatography) in the electro-insulating fluid (natural ester with high oleic content) thermally aged at 130 �C to 1000 hours in closed glass vessels, it have been found that the presence the investigated painting materials lead to a change in the mechanism and kinetics of the thermo-oxidation processes. These changes are supported by oxygen dissolved in oil, what leads to decrease both to gases formation CO2, CO, H2, CH4, C2H4 and C2H6) and furans products (5-HMF, 2-FOL, 2 -FAL and 2-ACF). The painting materials investigated during the heat treatment applied did not suffer any remarkable structural changes affecting their functionality in the electro-insulating fluid based on vegetable esters.

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