scholarly journals Parameterizing and grading hydrolytic stability in metal–organic frameworks

2016 ◽  
Vol 45 (9) ◽  
pp. 3668-3678 ◽  
Author(s):  
Benjamin S. Gelfand ◽  
George K. H. Shimizu
Keyword(s):  
Hydrolytic Stability ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Characterization Methods ◽  
Metal Organic

Water stability of MOFs is reviewed including exposure techniques, characterization methods, and ultimately more consistent definitions of water stability.

Enhanced water stability and high CO2 storage capacity of Lewis basic sites containing zirconium metal–organic framework

2021 ◽  
Author(s):  
Selcuk Demir ◽  
Nuray Bilgin ◽  
H. Merve Cepni ◽  
Hiroyasu Furukawa ◽  
Fatih Yilmaz ◽  
...  
Keyword(s):  
Metal Ions ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
High Co2 ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Selection Of

Metal–organic frameworks (MOFs) are an emerging class of materials employed for custom-designed purposes by judicious selection of the linker and the metal ions. Among the MOFs composed of carboxylate linkers,...

Critical role of water stability in metal–organic frameworks and advanced modification strategies for the extension of their applicability

2020 ◽  
Vol 7 (5) ◽  
pp. 1319-1347 ◽  
Author(s):  
Botao Liu ◽  
Kumar Vikrant ◽  
Ki-Hyun Kim ◽  
Vanish Kumar ◽  
Suresh Kumar Kailasa
Keyword(s):  
Drug Delivery ◽  
Water Purification ◽  
Gas Adsorption ◽  
Critical Role ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Metal Organic

Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).

scholarly journals Cyclodextrins Modified/Coated Metal–Organic Frameworks

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1273 ◽  
Author(s):  
Huacheng Zhang ◽  
Zhaona Liu ◽  
Jian Shen
Keyword(s):  
Hybrid Materials ◽  
Metal Organic Frameworks ◽  
Supramolecular Interactions ◽  
Future Research ◽  
Covalent Bonds ◽  
Characterization Methods ◽  
Coated Metal ◽  
Metal Organic ◽  
Future Research Directions ◽  
External Stimuli

Recent progress about a novel organic–inorganic hybrid materials, namely cyclodextrins (CDs) modified/coated metal–organic frameworks (MOFs) is summarized by using a special categorization method focusing on the interactions between CDs and MOFs moieties, such as ligand–metal cations interactions, supramolecular interactions including host–guest interactions and hydrogen bonding, as well as covalent bonds. This review mainly focuses on the interactions between CDs and MOFs and the strategy of combining them together, diverse external stimuli responsiveness of CDs-modified/coated MOFs, as well as applications of these hybrid materials to drug delivery and release system, catalysis and detection materials. Additionally, due to the importance of investigating advanced chemical architectures and physiochemical properties of CDs-modified/coated MOFs, a separate section is involved in diverse characterization methods and instruments. Furthermore, this minireview also foresees future research directions in this rapidly developing field.

scholarly journals Probing the Water Stability Limits and Degradation Pathways of Metal–Organic Frameworks

2020 ◽  
Vol 26 (31) ◽  
pp. 7109-7117 ◽  
Author(s):  
Mohamed E. A. Safy ◽  
Muhamed Amin ◽  
Rana R. Haikal ◽  
Basma Elshazly ◽  
Junjun Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Water Stability ◽  
Degradation Pathways ◽  
Metal Organic ◽  
Stability Limits

The applications and prospects of hydrophobic metal–organic frameworks in catalysis

2021 ◽  
Vol 50 (1) ◽  
pp. 39-58
Author(s):  
Lin Liu ◽  
Zhi-Peng Tao ◽  
Hao-Ran Chi ◽  
Bing Wang ◽  
Shi-Ming Wang ◽  
...  
Keyword(s):  
Hydrolytic Stability ◽  
Metal Organic Frameworks ◽  
Lower Affinity ◽  
Structural Variety ◽  
Metal Organic

These hydrophobic MOFs not only retain rich structural variety, highly crystalline frameworks, but also lower affinity toward water and boost hydrolytic stability. Hydrophobic MOFs catalysts showed unique advantages to various reactions.

scholarly journals METAL-ORGANIC FRAMEWORKS APPLIED FOR WATER PURIFICATION

2018 ◽  
pp. 1-16
Author(s):  
Open Journal Systems TPU Administrator
Keyword(s):  
Porous Materials ◽  
Water Purification ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Inorganic Contaminants ◽  
Ligand Modification ◽  
Metal Organic ◽  
Promising Application ◽  
Adsorbent Materials ◽  
Purification Of Water

Metal-organic frameworks (MOFs) which are materials constructed from metal ions/clusters bridged with organic linkers have emerged as an important family of porous materials for widely varying applications. The purification of water polluted with both of organic and inorganic contaminants is a potentially promising application of MOFs since the chemical and thermal properties of the porous materials are easily tunable, e.g. ligand modification, different metal, etc. The demonstration of alignment and the obtained insights facilitate the direction of designing ideal MOF materials with improved water stability for application in water purification. This review gives a brief overview and will be beneficial to the design, functionalization, and promotion of the development of MOFs as adsorbent materials for applications in water purification.

The role of photoinduced charge transfer for photocatalysis, photoelectrocatalysis and luminescence sensing in metal–organic frameworks

2020 ◽  
Vol 49 (37) ◽  
pp. 12892-12917
Author(s):  
Xinlin Li ◽  
Sreehari Surendran Rajasree ◽  
Jierui Yu ◽  
Pravas Deria
Keyword(s):  
Charge Transfer ◽  
Recent Progress ◽  
State Of The Art ◽  
Metal Organic Frameworks ◽  
Photoinduced Charge Transfer ◽  
Characterization Methods ◽  
Luminescent Sensors ◽  
Metal Organic ◽  
Photoinduced Charge

Understanding PCT taking place within MOFs is crucial for designing porous photo/electrocatalysts and luminescent sensors. Unique features of PCT in MOFs and recent progress along with state-of-the-art characterization methods are discussed in the context of its applications.

Prediction of water stability of metal–organic frameworks using machine learning

2020 ◽  
Vol 2 (11) ◽  
pp. 704-710
Author(s):  
Rohit Batra ◽  
Carmen Chen ◽  
Tania G. Evans ◽  
Krista S. Walton ◽  
Rampi Ramprasad
Keyword(s):  
Machine Learning ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Metal Organic
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