scholarly journals Reversible hydrogen activation by a bulky haloborane based FLP system

2016 ◽  
Vol 45 (14) ◽  
pp. 6129-6135 ◽  
Author(s):  
Marc-André Courtemanche ◽  
Étienne Rochette ◽  
Marc-André Légaré ◽  
Wenhua Bi ◽  
Frédéric-Georges Fontaine
Keyword(s):  
Activation Product ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair ◽  
System P

The FLP species bis(2-(TMP)phenyl)chloroborane was prepared as a monomeric Frustrated Lewis Pair displaying no B–N interaction. Species 1 reacts with H2 to generate reversibly the zwitterionic H2 activation product.

scholarly journals A Combined “Electrochemical-Frustrated Lewis Pair” Approach to Hydrogen Activation: Surface Catalytic Effects at Platinum Electrodes

2014 ◽  
Vol 21 (2) ◽  
pp. 900-906 ◽  
Author(s):  
Elliot J. Lawrence ◽  
Robin J. Blagg ◽  
David L. Hughes ◽  
Andrew E. Ashley ◽  
Gregory G. Wildgoose
Keyword(s):  
Platinum Electrodes ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair ◽  
Catalytic Effects

Unique nanocages of 12CaO·7Al2O3 boost heterolytic hydrogen activation and selective hydrogenation of heteroarenes over ruthenium catalyst

2017 ◽  
Vol 19 (3) ◽  
pp. 749-756 ◽  
Author(s):  
Tian-Nan Ye ◽  
Jiang Li ◽  
Masaaki Kitano ◽  
Hideo Hosono
Keyword(s):  
Selective Hydrogenation ◽  
Metal Catalysts ◽  
Solvent Free ◽  
Supported Metal Catalysts ◽  
Support Material ◽  
Hydrogen Activation ◽  
Free System ◽  
Ru Catalyst ◽  
System P ◽  
Solvent Free System

A unique nanoporous 12CaO·7Al2O3 support material for Ru catalyst exhibited highly efficient chemoselective and sustainable for the formation of heterocycle hydrogenated products that surpasses other supported-metal catalysts in a solvent-free system.

ChemInform Abstract: Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins.

ChemInform ◽  
2016 ◽  
Vol 47 (1) ◽  
Author(s):  
Thorsten vom Stein ◽  
Manuel Perez ◽  
Roman Dobrovetsky ◽  
Daniel Winkelhaus ◽  
Christopher B. Caputo ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair

Designing graphene as a new frustrated Lewis pair catalyst for hydrogen activation by co-doping

2016 ◽  
Vol 18 (16) ◽  
pp. 11120-11124 ◽  
Author(s):  
XiaoYing Sun ◽  
Bo Li ◽  
TianFu Liu ◽  
Jian Song ◽  
Dang Sheng Su
Keyword(s):  
Bilayer Graphene ◽  
Hydrogen Activation ◽  
Co Doping ◽  
Frustrated Lewis Pair ◽  
New Strategy

Doping bilayer graphene: a new strategy for FLP catalysts.

Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins

2015 ◽  
Vol 54 (35) ◽  
pp. 10178-10182 ◽  
Author(s):  
Thorsten vom Stein ◽  
Manuel Peréz ◽  
Roman Dobrovetsky ◽  
Daniel Winkelhaus ◽  
Christopher B. Caputo ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair

Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins

2015 ◽  
Vol 127 (35) ◽  
pp. 10316-10320 ◽  
Author(s):  
Thorsten vom Stein ◽  
Manuel Peréz ◽  
Roman Dobrovetsky ◽  
Daniel Winkelhaus ◽  
Christopher B. Caputo ◽  
...  
Keyword(s):  
Catalytic Hydrogenation ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair

scholarly journals Hydrogen activation using a novel tribenzyltin Lewis acid

2017 ◽  
Vol 375 (2101) ◽  
pp. 20170008 ◽  
Author(s):  
Robert T. Cooper ◽  
Joshua S. Sapsford ◽  
Roland C. Turnell-Ritson ◽  
Dong-Hun Hyon ◽  
Andrew J. P. White ◽  
...  
Keyword(s):  
Low Temperature ◽  
Lewis Acid ◽  
Lewis Acids ◽  
Lewis Acidity ◽  
The Novel ◽  
Hydrogen Activation ◽  
Frustrated Lewis Pair

Over the last decade there has been an explosion in the reactivity and applications of frustrated Lewis pair (FLP) chemistry. Despite this, the Lewis acids (LAs) in these transformations are often boranes, with heavier p -block elements receiving surprisingly little attention. The novel LA Bn 3 SnOTf ( 1 ) has been synthesized from simple, inexpensive starting materials and has been spectroscopically and structurally characterized. Subtle modulation of the electronics at the tin centre has led to an increase in its Lewis acidity in comparison with previously reported R 3 SnOTf LAs, and has facilitated low temperature hydrogen activation and imine hydrogenation. Deactivation pathways of the R 3 Sn + LA core have also been investigated. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

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