Isolation and structural characterization of a mainly ligand-based dimetallic radical

2015 ◽  
Vol 44 (46) ◽  
pp. 19754-19757 ◽  
Author(s):  
Shuyu Li ◽  
Xingyong Wang ◽  
Zaichao Zhang ◽  
Yue Zhao ◽  
Xinping Wang
Keyword(s):  
Crystal Structure ◽  
Structural Characterization ◽  
Bond Activation

The isolation and crystal structure of a mainly ligand-based dimetallic radical of ruthenium together with induced sp3 C–H bond activation were described.

scholarly journals KCTD proteins as Cullin3 E3 Ligase adapters

2014 ◽  
Vol 70 (a1) ◽  
pp. C305-C305
Author(s):  
Alan Ji ◽  
Gilbert Privé
Keyword(s):  
Crystal Structure ◽  
Structural Characterization ◽  
Dissociation Constants ◽  
E3 Ligase ◽  
Terminal Region ◽  
Btb Domain ◽  
Substrate Protein ◽  
Ubiquitin E3 Ligase ◽  
Ubiquitin Moiety

Cullin3 (Cul3) is an ubiquitin E3 ligase responsible for catalyzing the transfer of an ubiquitin moiety from an E2 enzyme to a target substrate protein. The C-terminal region of Cul3 binds RBX1/E2-ubiquitin, while, the N-terminal region interacts with various BTB domain proteins which serve as substrate adaptors. Previously, our group determined the crystal structures of the homodimeric BTB proteins SPOP and KLHL3 in complex with the N-terminal domain of Cul3, revealing the determinants responsible for the BTB/Cul3 interaction [1, 2]. A second class of BTB-domain containing proteins, the KCTD proteins, are also Cul3 substrate adaptors but these do not share many of the previously determined features for Cul3 binding. Furthermore, KCTD proteins form homotetramers and homopentamers via BTB oligomerization rather than the previously described homodimers. Despite these differences, many KCTD proteins interact with Cul3 with dissociation constants of approximately 50 nM. While the target substrates for many of the KCTD/Cul3 E3 ligase complexes are unknown, recent studies have implicated the GABAβ2 receptor as an interactor of KCTD 8, 12, 12b and 16. Here, we report the pentameric crystal structure of the KCTD9 BTB domain and our progress on the structural characterization of Cul3/KCTD/substrate complexes.

Structural Systematics of Rare Earth Complexes. VII. Crystal Structure of Bis(2,2'/6',2␛-Terpyridinium) Octaaquaterbium(III) Heptachloride Hydrate

1994 ◽  
Vol 47 (2) ◽  
pp. 391 ◽  
Author(s):  
CJ Kepert ◽  
BW Skeleton ◽  
AH White
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Single Crystal ◽  
Structural Characterization ◽  
Title Compound ◽  
Room Temperature ◽  
Chloride Ions ◽  
Full Matrix ◽  
X Ray

The room-temperature single-crystal X-ray structural characterization of the title compound (tpyH2)2[Tb(OH2)8]Cl7.~2⅓H2O is recorded. Crystals are triclinic, Pī , a 17.063(5), b 16.243(3), c 7.878(3) Ǻ, α 84.78(2), β 84.39(3), γ 87.81(2)°, Z = 2 formula units; 3167 'observed' diffractometer reflections were refined by full-matrix least-squares procedures to a residual of 0.057. Notable features of interest of the compound are the 'chelation' of chloride ions by the terpyridinium cations , and the existence of a free [Tb(OH2)8]2+ cation in the presence of an abundance of chloride ions.

scholarly journals Synthesis and structural characterization of hexa-μ2-chlorido-μ4-oxido-tetrakis{[4-(phenylethynyl)pyridine-κN]copper(II)} dichloromethane monosolvate

2021 ◽  
Vol 77 (1) ◽  
pp. 42-46
Author(s):  
Rayya A. Al Balushi ◽  
Muhammad S. Khan ◽  
Md. Serajul Haque Faizi ◽  
Ashanul Haque ◽  
Kieran Molloy ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Structural Characterization ◽  
Title Compound ◽  
Three Dimensional ◽  
Hirshfeld Surface ◽  
The Core ◽  
Dimensional Network ◽  
Packing Arrangement

In the crystal structure of the title compound, [Cu4Cl6O(C13H9N)4]·CH2Cl2, the core molecular structure consists of a Cu4 tetrahedron with a central interstitial O atom. Each edge of the Cu4 tetrahedron is bridged by a chlorido ligand. Each copper(II) cation is coordinated to the central O atom, two chlorido ligands and one N atom of the 4-phenylethynylpyridine ligand. In the crystal, the molecules are linked by intermolecular C—H...Cl interactions. Furthermore, C—H...π and π–π interactions also connect the molecules, forming a three-dimensional network. Hirshfeld surface analysis indicates that the most important contributions for the packing arrangement are from H...H and C...H/H...C interactions.

scholarly journals Transition metal complexes with thiosemicarbazide-based ligands. Part 60. Reactions of copper(II) bromide with pyridoxal S-methylisothiosemicarbazone (PLITSC). Crystal structure of [Cu(PLITSC−H)H2O]Br•H2O

2014 ◽  
Vol 79 (3) ◽  
pp. 291-302 ◽  
Author(s):  
Vukadin Leovac ◽  
Ljiljana Vojinovic-Jesic ◽  
Sonja Ivkovic ◽  
Marko Rodic ◽  
Ljiljana Jovanovic ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Elemental Analysis ◽  
Structural Characterization ◽  
Electronic Spectra ◽  
Square Planar

The synthesis and structural characterization of a square-planar copper(II) complex with pyridoxal S-methylisothiosemicarbazone (PLITSC) of the formula [Cu(PLITSC?H)H2O]Br?H2O (1) as the first Cu(II) complex with monoanionic form of this ligand were described. Complex 1 together with two previously synthesized complexes [Cu(PLITSC)Br2] (2) and [Cu(PLITSC)Br(MeOH)]Br (3) were characterized by elemental analysis, IR and electronic spectra and also by the methods of thermal analysis, conductometry and magnetochemistry.

First structural characterization of an α-diazophosphane: crystal structure of bis[bis(diisopropylamino)phosphanyl]diazomethane [(i-Pr2N)2P]2CN2

1989 ◽  
Vol 372 (2) ◽  
pp. 201-206 ◽  
Author(s):  
M.J. Menu ◽  
M. Dartiguenave ◽  
Y. Dartiguenave ◽  
J.J. Bonnet ◽  
G. Bertrand ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Structural Characterization

Preparation and structural characterization of new alkoxo- and (alkoxo)(amido)(imido)-niobium(V) compounds. Crystal structure of [NbCl(μ-OMe)[N(SiMe3)2](NSiMe3)]2

1988 ◽  
Vol 350 (1) ◽  
pp. 25-34 ◽  
Author(s):  
A. Antiñolo ◽  
A. Otero ◽  
F. Urbanos ◽  
S. Garcia-Blanco ◽  
S. Martinez-Carrera ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Structural Characterization

Erste strukturelle Charakterisierung eines leicht oxidierbaren 1,4-Dihydrochinoxalin-Derivats / First Structural Characterization of an Easily Oxidized Derivative of 1,4-Dihydroquinoxaline

1993 ◽  
Vol 48 (6) ◽  
pp. 713-718 ◽  
Author(s):  
Alexander Lichtblau ◽  
Hans-Dieter Hausen ◽  
Wolfgang Kaim
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Dihedral Angle ◽  
Structural Characterization ◽  
Crystal Structure Analysis ◽  
Ring System ◽  
Structural Flexibility ◽  
Steric Repulsion ◽  
Alkyl Groups

The first crystal structure analysis of a 1,4-dihydroquinoxaline is described by example of the 1,4-bis(tert-butyldimethylsilyl) derivative. In the solid state, this molecule exhibits a nonplanar heterocycle with a dihedral angle of 156.3° along the N—N axis in the boat-shaped 8π electron ring system. The alkyl groups of the Si(tert-Bu)Me2 substituents are arranged as to minimize steric repulsion. Despite the reduced π electron conjugation due to non-planarity, the compound is oxidized reversibly to an EPR detectable radical cation at —0.59 V vs. ferrocene in dichloromethane. However, the second oxidation to the fully aromatic dication is electrochemically irreversible. A comparison with previously obtained results illustrates the structural flexibility of the non-aromatic 1,4-dihydro-1,4-diazine ring system which is strongly affected by rather weak non-bonded interactions.

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