Ionophore silica-coated magnetite nanoparticles as a recyclable heterogeneous catalyst for one-pot green synthesis of 2,4,5-trisubstituted imidazoles

2016 ◽  
Vol 45 (3) ◽  
pp. 1243-1253 ◽  
Author(s):  
Hossein Naeimi ◽  
Dorsa Aghaseyedkarimi
Keyword(s):  
Ionic Liquid ◽  
Green Synthesis ◽  
Heterogeneous Catalyst ◽  
Magnetite Nanoparticles ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Recyclable Heterogeneous Catalyst

Novel multi-SO3H functionalized strong Brønsted acidic ionic liquid coated magnetite nanoparticles has been prepared and applied as catalyst for the synthesis of 2,4,5-trisubstituted imidazoles.

MOR zeolite supported Brønsted acidic ionic liquid: an efficient and recyclable heterogeneous catalyst for ketalization

RSC Advances ◽  
2014 ◽  
Vol 4 (24) ◽  
pp. 12160-12167 ◽  
Author(s):  
Zhang-Min Li ◽  
Yan Zhou ◽  
Duan-Jian Tao ◽  
Wei Huang ◽  
Xiang-Shu Chen ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Heterogeneous Catalyst ◽  
Heterogeneous Catalysts ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Recyclable Heterogeneous Catalyst ◽  
Supported Ionic Liquids

In order to widen the application of ionic liquids as efficient and renewable heterogeneous catalysts, supported ionic liquids (SILs) have received considerable attention.

scholarly journals A Brønsted acidic ionic liquid anchored to magnetite nanoparticles as a novel recoverable heterogeneous catalyst for the Biginelli reaction

RSC Advances ◽  
2021 ◽  
Vol 11 (13) ◽  
pp. 7271-7279
Author(s):  
Hourieh Sadat Oboudatian ◽  
Hossein Naeimi ◽  
Mohsen Moradian
Keyword(s):  
Ionic Liquid ◽  
Heterogeneous Catalyst ◽  
Magnetite Nanoparticles ◽  
Biginelli Reaction ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid

In this study, morpholine sulfate acidic ionic liquid bonded on magnetite nanoparticles (Mag@Morph-AIL) has been used as a catalyst for the preparation of 3,4-dihydropyrimidinones.

1, 1’-Sulfinyldiethylammonium Bis (Hydrogen Sulfate) as a Recyclable Dicationic Ionic Liquid Catalyst for the Efficient Solvent-free Synthesis of 3, 4-Dihydropyrimidin-2(1H)-ones via Biginelli Reaction

2020 ◽  
Vol 23 (2) ◽  
pp. 157-167
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Biginelli Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
Hydrogen Sulfate ◽  
One Pot ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
Solvent Free Conditions ◽  
Dicationic Ionic Liquid

Objective: A facile and efficient method for synthesis of 3, 4-dihydropyrimidin-2(1H)-ones via Biginelli reaction catalyzed by a novel dicationic Brönsted acidic ionic liquid, [(EtNH2)2SO][HSO4]2, has been successfully developed. Material and Method:: 3, 4-Dihydropyrimidin-2(1H)-ones were synthesized through one-pot condensation of aromatic aldehydes, ethyl acetoacetate, and urea under solvent-free conditions using [(EtNH2)2SO][HSO4]2 as a novel catalyst. The progress of the reaction was monitored by thin-layer chromatography (ethyl acetate / n-hexane = 1 / 5). The products have been characterized by IR, 1H NMR, 13C NMR, and also by their melting points. Results: In this research, a library of dihydropyrimidinone derivatives was synthesized via Biginelli reaction under solvent-free conditions at 120oC using [(EtNH2)2SO][HSO4]2 as a catalyst. Various aromatic aldehydes, as well as heteroaromatic aldehydes, were employed, affording good to high yields of the corresponding products and illustrating the substrate generality of the present method. In addition, the prepared dicationic Brönsted acidic ionic liquid can be easily recovered and reused. Conclusion: 1, 1’-Sulfinyldiethylammonium bis (hydrogen sulfate), as a novel dicationic ionic liquid, can act as a highly efficient catalyst for the synthesis of 3, 4-dihydropyrimidin-2(1H)-ones under solvent-free conditions.

Efficient pseudo five-component synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives promoted by a novel ionic liquid catalyst

2018 ◽  
Vol 73 (3-4) ◽  
pp. 191-195 ◽  
Author(s):  
Zahra Abshirini ◽  
Abdolkarim Zare
Keyword(s):  
Ionic Liquid ◽  
Disulfonic Acid ◽  
Thermal Gravimetric ◽  
One Pot ◽  
Mild Conditions ◽  
Acidic Ionic Liquid ◽  
Brønsted Acidic Ionic Liquid ◽  
The One ◽  
C Nmr

AbstractIn this research, initial production and characterization of a novel Brønsted-acidic ionic liquid, namely,N,N,N′,N′-tetramethylethylenediaminium-N,N′-disulfonic acid hydrogen sulfate ([TMEDSA][HSO4]2), has been described (characterization was achieved using Fourier-transform infrared spectroscopy,1H nuclear magnetic resonance (NMR),13C NMR, and mass and thermal gravimetric spectra). Thereafter, utilization of [TMEDSA][HSO4]2as a highly effectual catalyst for the synthesis of 4,4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol) derivatives through the one-pot pseudo five-component reaction of phenylhydrazine (2 eq.) with ethyl acetoacetate (2 eq.) and arylaldehydes (1 eq.) in relatively mild conditions, has been reported.

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