scholarly journals High-yield, fluoride-free and large-scale synthesis of MIL-101(Cr)

2015 ◽  
Vol 44 (38) ◽  
pp. 16791-16801 ◽  
Author(s):  
Tian Zhao ◽  
Felix Jeremias ◽  
Ishtvan Boldog ◽  
Binh Nguyen ◽  
Stefan K. Henninger ◽  
...  
Keyword(s):  
Large Scale ◽  
High Yield ◽  
Large Scale Synthesis ◽  
Scientific Fields

MIL-101(Cr), one of the most important prototypical MOFs, is well investigated and widely used in many scientific fields.

A Comparison of Different Preparation Methods of Fe-Mo-Mg-O Catalyst for the Large-Scale Synthesis of Carbon Nanotubes

2006 ◽  
Vol 510-511 ◽  
pp. 66-69 ◽  
Author(s):  
Yan Fang Chen ◽  
Yun Soo Lim
Keyword(s):  
Carbon Nanotubes ◽  
Large Scale ◽  
Sol Gel ◽  
High Yield ◽  
Preparation Methods ◽  
Gel Method ◽  
Sol Gel Method ◽  
Large Scale Synthesis ◽  
Synthesis Of Carbon Nanotubes ◽  
Reaction Routes

Carbon nanotubes (CNTs) in a high yield were synthesized by the decomposition of the methane gas with CCVD, in which two different reaction routes of sol-gel method prepared Fe-Mo- Mg-O catalyst. The two different routs influenced the wall number and defects of CNTs and the formation of CNTs. The concentration of Mo in the catalyst played a very important role in the yield of CNTs.

Large-scale synthesis of soluble graphitic hollow carbon nanorods with tunable photoluminescence for the selective fluorescent detection of DNA

2016 ◽  
Vol 40 (2) ◽  
pp. 1571-1579 ◽  
Author(s):  
Kumud Malika Tripathi ◽  
Amit Kumar Sonker ◽  
Anshu Bhati ◽  
Jagannath Bhuyan ◽  
Anupriya Singh ◽  
...  
Keyword(s):  
Large Scale ◽  
Water Soluble ◽  
Fluorescent Detection ◽  
High Yield ◽  
Dna Molecules ◽  
Selective Determination ◽  
Turn On ◽  
Large Scale Synthesis ◽  
Hollow Carbon

A high-yield synthesis of water-soluble photoluminescent carbon nanorods is described. The wsCNRs were used for the selective determination of DNA molecules via a fluorescent turn-off/turn-on mechanism.

A rapid, high-yield and large-scale synthesis of uniform spherical silver nanoparticles by a microwave-assisted polyol process

RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92144-92150 ◽  
Author(s):  
Jens Helmlinger ◽  
Martin Heise ◽  
Marc Heggen ◽  
Michael Ruck ◽  
Matthias Epple
Keyword(s):  
Silver Nanoparticles ◽  
Medical Devices ◽  
Large Scale ◽  
Consumer Products ◽  
Polyol Process ◽  
High Yield ◽  
Microwave Assisted ◽  
Large Scale Synthesis

Silver nanoparticles, often applied in medical devices and consumer products, can be conveniently prepared by microwave-based synthesis.

High Yield, Large Scale Synthesis of Thiolate-Protected Ag7Clusters

2009 ◽  
Vol 131 (46) ◽  
pp. 16672-16674 ◽  
Author(s):  
Zhikun Wu ◽  
Eric Lanni ◽  
Wenqian Chen ◽  
Mark E. Bier ◽  
Danith Ly ◽  
...  
Keyword(s):  
Large Scale ◽  
High Yield ◽  
Large Scale Synthesis

Exogenous Directing Group Free, Ligand-Enabled gamma-C(sp3)–H Arylation of Free Primary Aliphatic Amines and α-Amino Esters

2019 ◽  
Author(s):  
Yongzheng Ding ◽  
Shuai Fan ◽  
Xiaoxi Chen ◽  
yuzhen gao ◽  
Gang Li
Keyword(s):  
Amino Acids ◽  
Large Scale ◽  
Free Ligand ◽  
Aliphatic Amines ◽  
Rapid Synthesis ◽  
Amino Esters ◽  
Directing Group ◽  
Large Scale Synthesis ◽  
Primary Aliphatic Amines

A Pdᴵᴵ-catalyzed, ligand-enabled gamma-C(sp3)–H arylation of free primary aliphatic amines and amino esters without using an exogenous directing group is reported. This reaction is compatible with unhindered free aliphatic amines, and it is also be applicable to the rapid synthesis of biologically and synthetically valuable unnatural α-amino acids. Large scale synthesis is also feasible using this method.<br>

A Simplified Protocol for the ortho-Deuteration of Acidic Aromatic Compounds in D2O

2019 ◽  
Author(s):  
Alyssa Garreau ◽  
Hanyang Zhou ◽  
Michael Young
Keyword(s):  
Carboxylic Acid ◽  
Aromatic Compounds ◽  
Large Scale ◽  
Simplified Approach ◽  
Directing Group ◽  
Large Scale Synthesis

<div>Methods to catalytically introduce deuterium in synthetically useful yields ortho to a carboxylic acid directing group on arenes typically requires D2 or CD3CO2D, which makes using these approaches cost prohibitive for large scale synthesis (equipment and reagent costs respectively). Herein we present a simplified approach using catalytic RhIII and D2O as deuterium source, and show its application to H/D exchange on various acidic substrates.</div>

A Simplified Protocol for the ortho-Deuteration of Acidic Aromatic Compounds in D2O

2019 ◽  
Author(s):  
Alyssa Garreau ◽  
Hanyang Zhou ◽  
Michael Young
Keyword(s):  
Carboxylic Acid ◽  
Aromatic Compounds ◽  
Large Scale ◽  
Simplified Approach ◽  
Directing Group ◽  
Large Scale Synthesis

<div>Methods to catalytically introduce deuterium in synthetically useful yields ortho to a carboxylic acid directing group on arenes typically requires D2 or CD3CO2D, which makes using these approaches cost prohibitive for large scale synthesis (equipment and reagent costs respectively). Herein we present a simplified approach using catalytic RhIII and D2O as deuterium source, and show its application to H/D exchange on various acidic substrates.</div>

A Simple Synthesis of the Anticancer Drug Altretamine

2020 ◽  
Vol 17 (8) ◽  
pp. 628-630
Author(s):  
Vu Binh Duong ◽  
Pham Van Hien ◽  
Tran Thai Ngoc ◽  
Phan Dinh Chau ◽  
Tran Khac Vu
Keyword(s):  
Aqueous Solution ◽  
Anticancer Drug ◽  
Potassium Hydroxide ◽  
Large Scale ◽  
Synthesis Method ◽  
Practical Method ◽  
Cyanuric Chloride ◽  
Simple Synthesis ◽  
High Yield ◽  
One Step

A simple and practical method for the synthesis on a large scale of altretamine (1), a wellknown antitumor drug, has been successfully developed. The synthesis method involves the conversion of cyanuric chloride (2) into altretamine (1) by dimethylamination of 2 with an aqueous solution of 40% dimethylamine and potassium hydroxide in 1, -dioxan 4in one step to give altretamine (1) in high yield.

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