scholarly journals A trinuclear CuII complex with functionalized s-heptazine N-ligands: molecular chemistry from a g-C3N4 fragment

2015 ◽  
Vol 44 (36) ◽  
pp. 15761-15763 ◽  
Author(s):  
Lindley Maxwell ◽  
Silvia Gómez-Coca ◽  
Thomas Weyhermüller ◽  
David Panyella ◽  
Eliseo Ruiz
Keyword(s):  
Metal Complex ◽  
Synthesis And Characterization ◽  
Molecular Chemistry ◽  
New Type ◽  
Photochemical Properties

Synthesis and characterization of a new type of metal complex and N-ligand based on heptazine derivatives with appealing photochemical properties.

scholarly journals Synthesis and characterization of novel oxo-bridged, trinuclear mixed-metal complexes of Cr(III) and Fe(III)

2009 ◽  
Vol 74 (4) ◽  
pp. 401-406 ◽  
Author(s):  
Mohammad Yazdanbakhsh ◽  
Iman Khosravi ◽  
Haman Tavakkoli
Keyword(s):  
Metal Complex ◽  
Infrared Spectra ◽  
Carboxylate Ligand ◽  
Synthesis And Characterization ◽  
Chlorobenzoic Acid ◽  
Mixed Metal ◽  
Elemental Analyses ◽  
New Type ◽  
Mixed Metal Complexes

Two new heterotrinuclear p-chlorobenzoates, [Fe2CrO(C7H4O2Cl)6(py)3]NO3 (1) and [Cr2FeO(C7H4O2Cl)6(py)3]NO3 (2) were prepared as nitrate salts and characterized by elemental analyses (CHN), spectroscopic (infrared, electronic) studies and atomic absorption spectroscopy. These complexes are a new type of oxo-bridged mixed-metal complex in which the carboxylate ligand is p-chlorobenzoic acid. Bridging coordination modes for the carboxylates were indicated by the presence of ?asym (M2M'O) vibrations in the infrared spectra.

Synthesis and Characterization of Foamed Cassava Starch Material

2012 ◽  
Vol 262 ◽  
pp. 405-409
Author(s):  
Yang Liu ◽  
Shan Shan Li ◽  
Xin Yan Yang ◽  
Chong Xing Huang
Keyword(s):  
Reaction Time ◽  
Cassava Starch ◽  
Synthesis And Characterization ◽  
Compression Stress ◽  
Static Compression ◽  
Foaming Agent ◽  
New Type ◽  
Analysis System ◽  
Central Composite

A new-type foam composites were fabricated by baking method from a mixture of cassava starch. A central composite design was constructed using the software Statistics Analysis System 9.0 to evaluate the static compression stress of foamed material. The optimum dosages of adhesive, foaming agent, catalyst were 2.0g, 6.0g, 2.4g, respectively; reaction temperature 65°C; reaction time 16 hour.

New peripherally substituted lutetium mono and bis phthalocyanines: Synthesis and comparative photophysical and photochemical properties

2019 ◽  
Vol 23 (11n12) ◽  
pp. 1542-1550
Author(s):  
Nagihan Kocaağa ◽  
Öznur Dülger Kutlu ◽  
Ali Erdoğmuş
Keyword(s):  
Mass Spectrometry ◽  
Photodynamic Therapy ◽  
Singlet Oxygen ◽  
Photophysical Properties ◽  
Quantum Yields ◽  
Synthesis And Characterization ◽  
Type Ii ◽  
H Nmr ◽  
Photochemical Properties

In this study, the synthesis and characterization of mono-(phthalocyaninato) lutetium(III) (1-Cl and 1-F) [Lu[Formula: see text](AcO)(Pc)] (Pc [Formula: see text] phthalocyaninato, AcO [Formula: see text] acetate) and bis-(phthalocyaninato) lutetium(III) (2-Cl and 2-Br) [Lu[Formula: see text]Pc[Formula: see text]] bearing halogenated (F, Cl and Br) phenoxy–phenoxy groups are described and verified by IR, [Formula: see text]H-NMR, UV-vis and mass spectrometry. Photochemical and photophysical properties of 1-F, 1-Cl 2-Cl and 2-Br in DMSO are also presented. A comparison between photophysical and photochemical parameters of mono and bis derivatives showed that mono phthalocyanines are better photosensitizers than bis phthalocyanines. Photophysical and photochemical properties of phthalocyanines are very useful for photodynamic therapy applications. Singlet oxygen quantum yields [Formula: see text] give an indication of the potential of the complexes as photosensitizers in photodynamic therapy applications. The chloro, fluoro, bromo-phenoxy–phenoxy substituted mono-(phthalocyaninato) lutetium(III) complexes (1-Cl and 1-F) gave good singlet oxygen quantum yields (from 0.86 to 0.80) in DMSO. Thus, these complexes show potential as Type II photosensitizers for PDT of cancer.

Synthesis and characterization of novel 7-oxy-3-ethyl-6-hexyl-4-methylcoumarin substituted metallo phthalocyanines and investigation of their photophysical and photochemical properties

2019 ◽  
Vol 48 (34) ◽  
pp. 13046-13056 ◽  
Author(s):  
Mücahit Özdemir ◽  
Begümhan Karapınar ◽  
Bahattin Yalçın ◽  
Ümit Salan ◽  
Mahmut Durmuş ◽  
...  
Keyword(s):  
Singlet Oxygen ◽  
Quantum Yields ◽  
Synthesis And Characterization ◽  
Photochemical Properties ◽  
Lipophilic Groups

Coumarin functionalized metallo phthalocyanines shows increased singlet oxygen quantum yields when included lipophilic groups.

Synthesis, characterization and application of anionic metal complex azo dyes as potential substitutes for Cr-complex dyes

2014 ◽  
Vol 84 (19) ◽  
pp. 2036-2044 ◽  
Author(s):  
Zarkogianni Maria ◽  
Eleftheriadis Ioannis ◽  
Nikolaidis Nikolaos ◽  
Tsasaroni Eforia
Keyword(s):  
Metal Complex ◽  
Azo Dyes ◽  
Synthesis And Characterization ◽  
Fastness Properties ◽  
Drastic Reduction ◽  
Filtration Process ◽  
Lower Toxicity ◽  
Ultra Filtration ◽  
Free Metal

The synthesis and characterization of Cu-, Al-, Zn-, Ni-, Mn- complexes as substitutes for the Cr- and Co-complex acid azo dyes with lower toxicity was carried out and the subsequent use of ultra-filtration was studied with the aim of purifying the metal complex dyes and thus increasing dye strength and solubility and additionally reducing the free metal present in the final dye. A drastic reduction in the content of inorganic additives and free metal was achieved by the ultra-filtration process. The ultra-filtrated and non-ultra-filtrated dyes were used to dye wool and nylon fabrics. Color measurements and fastness properties were performed on the dyeings produced on wool and polyamide and compared with the Cr-complex dyeing, thus examining the possibility of using successfully these complex dyes as possible replacement of the Cr- and Co-complex dyes.

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