Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework

2015 ◽  
Vol 44 (31) ◽  
pp. 13809-13813 ◽  
Author(s):  
Juan Wang ◽  
Zhen Wei ◽  
Fengwan Guo ◽  
Chenyang Li ◽  
Pengfei Zhu ◽  
...  

Synthesis, crystal structure and luminescence properties of uranyl chiral coordination polymers from achiral ligands.

2018 ◽  
Vol 42 (8) ◽  
pp. 6408-6415 ◽  
Author(s):  
Marina O. Barsukova ◽  
Sergey A. Sapchenko ◽  
Konstantin A. Kovalenko ◽  
Denis G. Samsonenko ◽  
Andrei S. Potapov ◽  
...  

A synergistic effect causes MOF materials to demonstrate excellent iodine vapor retention and luminescence properties.


Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 303 ◽  
Author(s):  
Jan Rohlíček ◽  
Daniel Bůžek ◽  
Petr Brázda ◽  
Libor Kobera ◽  
Jan Hynek ◽  
...  

The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce2(C8H10P2O4)3, containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal–organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m2 g-1.


Polyhedron ◽  
2015 ◽  
Vol 99 ◽  
pp. 1-6 ◽  
Author(s):  
Qiu-Yan Li ◽  
Ying Quan ◽  
Wei Wei ◽  
Jian Li ◽  
Han Lu ◽  
...  

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