scholarly journals Energy transfer and unusual decay behaviour of BaCa2Si3O9:Eu2+,Mn2+ phosphor

2015 ◽  
Vol 44 (22) ◽  
pp. 10368-10376 ◽  
Author(s):  
Matthias Müller ◽  
Thomas Jüstel

In this work the photoluminescence (PL) of BaCa2Si3O9:Eu2+, Mn2+ and the energy transfer between Eu2+ and Mn2+ were examined. Further, PL as well as luminescence lifetime measurements were performed at various temperatures.

RSC Advances ◽  
2015 ◽  
Vol 5 (83) ◽  
pp. 67979-67987 ◽  
Author(s):  
Matthias Müller ◽  
Stefan Fischer ◽  
Thomas Jüstel

The photoluminescence (PL) of co-doped Sr5MgLa2(BO3)6:Ce3+,Mn2+ and energy transfer from Ce3+ to Mn2+ were studied. PL and fluorescence lifetime measurements were performed at various temperatures. External quantum efficiencies and chromaticity coordinates were obtained.


2019 ◽  
Vol 96 (5) ◽  
pp. 1046-1050 ◽  
Author(s):  
Steven M. Drew ◽  
Deborah S. Gross ◽  
William E. Hollingsworth ◽  
Thomas Baraniak ◽  
Christopher M. Zall ◽  
...  

Author(s):  
M. RAVIKUMAR ◽  
R. P. PANDIAN ◽  
T. K. CHANDRASHEKAR

The singlet and triplet excited state properties of two diporphyrins, H 2- H and Zn - H , are described. Steady state fluorescence studies indicate that the emission of the H 2- H diporphyrin is dependent on the excitation wavelength and is dominated by the emission of the individual constituent monomers at their respective excitation. Time-resolved studies show two lifetimes ascribable to the normal and thiaporphyrin subunits. However, the emission of the Zn - H diporphyrin is dominated by the thiaporphyrin subunit irrespective of the wavelength of excitation, suggesting an energy transfer from the Zn porphyrin subunit to the thiaporphyrin subunit. Lifetime measurements in toluene show two lifetimes due to open and folded conformations, while in DMF an additional component due to axial ligation is observed. The efficiency of energy transfer is moderately higher in DMF (72%) than in toluene (68%). Triplet ESR studies on the H 2- H dimer reveal a localized triplet with ZFS parameters and ESP pattern the same as for the individual monomers. On the other hand, triplet ESR of the Zn - H diporphyrin reveals triplet characteristics of the thiaporphyrin subunit, indicating an energy transfer in the triplet state.


1985 ◽  
Vol 57 (12) ◽  
pp. 2304-2308 ◽  
Author(s):  
E. R. Carraway ◽  
B. L. Hauenstein ◽  
J. N. Demas ◽  
B. A. DeGraff

2008 ◽  
Vol 62 (12) ◽  
pp. 1395-1399 ◽  
Author(s):  
A. Romani ◽  
C. Clementi ◽  
C. Miliani ◽  
B. G. Brunetti ◽  
A. Sgamellotti ◽  
...  

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