Polystyrene trimethyl ammonium chloride impregnated Rh(0) (Rh@PMe3NCl) as a catalyst and methylating agent for esterification of alcohols through selective oxidation of methanol

2015 ◽  
Vol 5 (5) ◽  
pp. 2575-2580 ◽  
Author(s):  
Nitul Ranjan Guha ◽  
Dhananjay Bhattacherjee ◽  
Pralay Das
Keyword(s):  
Selective Oxidation ◽  
Ammonium Chloride ◽  
Trimethyl Ammonium Chloride ◽  
Ester Synthesis ◽  
Acetate Ester ◽  
Oxidation Of Methanol ◽  
Dehydrogenative Coupling

Rh@PMe3NCl acts as a cross-dehydrogenative coupling-methylating agent for the selective oxidation of methanol and it's in situ reaction with benzyl/alkyl alcohols for acetate ester synthesis is presented.

scholarly journals In situ spectroscopic investigations of MoOx/Fe2O3 catalysts for the selective oxidation of methanol

2016 ◽  
Vol 6 (3) ◽  
pp. 722-730 ◽  
Author(s):  
Catherine Brookes ◽  
Michael Bowker ◽  
Emma K. Gibson ◽  
Diego Gianolio ◽  
Khaled M. H. Mohammed ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Spectroscopic Investigations ◽  
Oxidation Of Methanol

Methoxy adsorbed on MoOx/Fe2O3 surfaces.

scholarly journals Correction: In situ spectroscopic investigations of MoOx/Fe2O3 catalysts for the selective oxidation of methanol

2018 ◽  
Vol 8 (11) ◽  
pp. 2998-2998
Author(s):  
Catherine Brookes ◽  
Michael Bowker ◽  
Emma K. Gibson ◽  
Diego Gianolio ◽  
Khaled M. H. Mohammed ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Spectroscopic Investigations ◽  
Oxidation Of Methanol

Correction for ‘In situ spectroscopic investigations of MoOx/Fe2O3 catalysts for the selective oxidation of methanol’ by Catherine Brookes et al., Catal. Sci. Technol., 2016, 6, 722–730.

scholarly journals A cross-dehydrogenative C(sp3)−H heteroarylation via photo-induced catalytic chlorine radical generation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chia-Yu Huang ◽  
Jianbin Li ◽  
Chao-Jun Li
Keyword(s):  
Hydrogen Atom ◽  
Hydrogen Evolution ◽  
Alkyl Radical ◽  
Cobalt Catalyst ◽  
Alkylation Reaction ◽  
Hydrogen Atom Abstraction ◽  
Dehydrogenative Coupling ◽  
Radical Generation ◽  
Limited Scope

AbstractHydrogen atom abstraction (HAT) from C(sp3)–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs since involving stoichiometric oxidants, excessive alkane loading, and limited scope are common drawbacks. Here we report a photo-induced and chemical oxidant-free cross-dehydrogenative coupling (CDC) between alkanes and heteroarenes using catalytic chloride and cobalt catalyst. Couplings of strong C(sp3)–H bond-containing substrates and complex heteroarenes, have been achieved with satisfactory yields. This dual catalytic platform features the in situ engendered chlorine radical for alkyl radical generation and exploits the cobaloxime catalyst to enable the hydrogen evolution for catalytic turnover. The practical value of this protocol was demonstrated by the gram-scale synthesis of alkylated heteroarene with merely 3 equiv. alkane loading.

Active site densities, oxygen activation and adsorbed reactive oxygen in alcohol activation on npAu catalysts

2016 ◽  
Vol 188 ◽  
pp. 57-67 ◽  
Author(s):  
Lu-Cun Wang ◽  
C. M. Friend ◽  
Rebecca Fushimi ◽  
Robert J. Madix
Keyword(s):  
Selective Oxidation ◽  
Activation Barrier ◽  
Initial Step ◽  
Temporal Analysis ◽  
Adsorbed Oxygen ◽  
Transient Pressure ◽  
Pulse Reaction ◽  
Dissociation Probability ◽  
Oxidation Of Methanol ◽  
Oxygen Atoms

The activation of molecular O2 as well as the reactivity of adsorbed oxygen species is of central importance in aerobic selective oxidation chemistry on Au-based catalysts. Herein, we address the issue of O2 activation on unsupported nanoporous gold (npAu) catalysts by applying a transient pressure technique, a temporal analysis of products (TAP) reactor, to measure the saturation coverage of atomic oxygen, its collisional dissociation probability, the activation barrier for O2 dissociation, and the facility with which adsorbed O species activate methanol, the initial step in the catalytic cycle of esterification. The results from these experiments indicate that molecular O2 dissociation is associated with surface silver, that the density of reactive sites is quite low, that adsorbed oxygen atoms do not spill over from the sites of activation onto the surrounding surface, and that methanol reacts quite facilely with the adsorbed oxygen atoms. In addition, the O species from O2 dissociation exhibits reactivity for the selective oxidation of methanol but not for CO. The TAP experiments also revealed that the surface of the npAu catalyst is saturated with adsorbed O under steady state reaction conditions, at least for the pulse reaction.

scholarly journals Understanding the Reaction Crystallization Process of Glycidyl Trimethyl Ammonium Chloride

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 449
Author(s):  
Shuai Yu ◽  
Hui Chen ◽  
Xujie Gao ◽  
Weichun Feng ◽  
Wenguo Xing ◽  
...  
Keyword(s):  
Ammonium Chloride ◽  
Crystallization Process ◽  
Crystal Form ◽  
Trimethyl Ammonium Chloride ◽  
Key Factors ◽  
Factors Affecting ◽  
Seed Dispersion ◽  
Seed Growth ◽  
Seed Method ◽  
Crystal Seed

Reaction crystallization to produce glycidyl trimethyl ammonium chloride (GTA) via epichlorohydrin with gas-state trimethylamine was investigated. The crystallization process of the GTA gas-liquid reaction was optimized by a seed method. The optimized technology can prepare GTA products with crystal form and purity greater than 97%. The crystallization process of GTA consists of four steps (i.e., addition of seed, dispersion of seed, growth of crystals on the seed surfaces, agglomeration and growth of crystal). Seed method and flow rate are the key factors affecting purity. The purity and particle size of GTA crystals were satisfactory as long as the operation was kept within the defined envelope. The experiments were conducted on a 1 L reactor and successfully scaled-up to 3000 L in industry.

scholarly journals Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 2701-2714
Author(s):  
Caitlin M. Crombie ◽  
Richard J. Lewis ◽  
Rebekah L. Taylor ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
H2o2 Production ◽  
Oxidation Of Benzyl Alcohol ◽  
Supported Pd
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