Excited-state dynamics of Si–rhodamine and its aggregates: versatile fluorophores for NIR absorption

2016 ◽  
Vol 18 (3) ◽  
pp. 2097-2103 ◽  
Author(s):  
Sooyeon Kim ◽  
Mamoru Fujitsuka ◽  
Mikiji Miyata ◽  
Tetsuro Majima
Keyword(s):  
Excited State ◽  
Excited States ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Excited State Dynamics ◽  
Nir Absorption ◽  
First Time

The properties of SiR monomers and aggregates in the excited states are thoroughly characterized for the first time using time-resolved spectroscopy.

Excited state dynamics of nanocrystalline VO 2 with white light continuum time resolved spectroscopy

2014 ◽  
Vol 333 ◽  
pp. 109-114 ◽  
Author(s):  
Ulaş Kürüm ◽  
H. Gul Yaglioglu ◽  
Betül Küçüköz ◽  
R. Mustafa Oksuzoglu ◽  
Mustafa Yıldırım ◽  
...  
Keyword(s):  
Excited State ◽  
White Light ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Excited State Dynamics ◽  
White Light Continuum

Planar hexaphyrin-like macrocycles turning into bis-BODIPYs with box-shaped structures exhibiting excitonic coupling

2021 ◽  
Author(s):  
Arumugam Kalaiselvan ◽  
Shaina Dhamija ◽  
Chakrapani Aswathi ◽  
Arijit K. De ◽  
Sabapathi Gokulnath
Keyword(s):  
Electronic Structure ◽  
Excited State ◽  
Electronic Structure Calculations ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Excited State Dynamics ◽  
Structure Calculations ◽  
Excitonic Coupling

This present study reveals the synthesis and excited-state dynamics of carbazole embedded hexaphyrin-like macrocycles and their bis-BODIPY complexes. Time-resolved spectroscopy was performed to elucidate the excitonic coupling in conjunction with electronic structure calculations.

Excited state dynamics and conformations of a Cu(ii)-phthalocyanine-perylenebisimide dyad

2017 ◽  
Vol 19 (33) ◽  
pp. 22169-22176 ◽  
Author(s):  
K. Wilma ◽  
T. Unger ◽  
S. Tuncel Kostakoğlu ◽  
M. Hollfelder ◽  
C. Hunger ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Excited State ◽  
Molecular Dynamics Simulations ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Excited State Dynamics ◽  
Donor Acceptor ◽  
Dynamics Simulations

We present a full characterisation of a new donor–acceptor CuPc-PBI-dyad using time-resolved spectroscopy as well as molecular dynamics simulations.

Mode-specific excited-state dynamics of N-methylpyrrole

2019 ◽  
Vol 21 (26) ◽  
pp. 14387-14393 ◽  
Author(s):  
Kyung Chul Woo ◽  
Sang Kyu Kim
Keyword(s):  
Excited State ◽  
Physical Properties ◽  
Excited States ◽  
Time Resolved ◽  
Excited State Dynamics

A picosecond time-resolved dynamics study unravels the photo-physical properties of N-methylpyrrole in excited-states in a mode-specific way.

Time-resolved spectroscopy of the singlet excited state of betanin in aqueous and alcoholic solutions

2015 ◽  
Vol 17 (27) ◽  
pp. 18152-18158 ◽  
Author(s):  
Monika Wendel ◽  
Stanislaw Nizinski ◽  
Dorota Tuwalska ◽  
Karolina Starzak ◽  
Dominika Szot ◽  
...  
Keyword(s):  
Excited State ◽  
Singlet Excited State ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Nir Absorption

Transient UV-vis-NIR absorption of betanin in water.

scholarly journals Excited State Dynamics of Perylenediimide films with Isopropyl phenyl- and Undecane-Substitution

2020 ◽  
Author(s):  
Qiu-Shi Ma ◽  
Cheng-Wei Ju ◽  
Ruihua Pu ◽  
Wenjie Zhang ◽  
Xian Lin ◽  
...  
Keyword(s):  
Excited State ◽  
Excited States ◽  
Transient Absorption ◽  
Amorphous Film ◽  
Singlet Fission ◽  
Amorphous Films ◽  
Time Resolved ◽  
Excited State Dynamics ◽  
Coating Method ◽  
Time Resolved Photoluminescence

<p>The aggregation of Perylene Diimide (PDI) and its derivatives strongly depends on the molecular structure, and therefore has great impact on the excited states. By regulating the molecular stacking such as monomer, dimer, J- and/or H-aggregate, the formation of different excited states is adjustable and controllable. In this study, we have synthesized two kinds of PDI derivatives - undecane-substituted PDI (PDI-1) and diisopropylphenyl-substituted PDI (PDI-2), and the films are fabricated with spin-coating method. By employing photoluminescence (PL), time-resolved photoluminescence (TRPL) and transient absorption (TA) spectroscopy, the excited-state dynamics of two PDI amorphous films have been investigated systematically. The result reveals that both films have formed excimer after photoexcitation mainly due to the stronger electronic coupling among molecule aggregate in the amorphous film. It should be noted that the excited state dynamics in PDI-2 shows a singlet fission like process, which is evidenced by the appearance of triplet state absorption. This study provides the dynamics of excited state in amorphous PDI films, and pave the way for better understanding and adjusting the excited state of amorphous films. </p>

Excited State Dynamics of Isocyano Rhenium(I) Phenanthroline Complexes from Time‐Resolved Spectroscopy

ChemPhysChem ◽  
2019 ◽  
Vol 20 (15) ◽  
pp. 1946-1953 ◽  
Author(s):  
Shun‐Cheung Cheng ◽  
Wing‐Kin Chu ◽  
Chi‐Chiu Ko ◽  
David Lee Phillips
Keyword(s):  
Excited State ◽  
Time Resolved ◽  
Time Resolved Spectroscopy ◽  
Excited State Dynamics

Excited State Dynamics of Perylenediimide films with Isopropyl phenyl- and Undecane-Substitution

2020 ◽  
Author(s):  
Qiu-Shi Ma ◽  
Cheng-Wei Ju ◽  
Ruihua Pu ◽  
Wenjie Zhang ◽  
Xian Lin ◽  
...  
Keyword(s):  
Excited State ◽  
Excited States ◽  
Transient Absorption ◽  
Amorphous Film ◽  
Singlet Fission ◽  
Amorphous Films ◽  
Time Resolved ◽  
Excited State Dynamics ◽  
Coating Method ◽  
Time Resolved Photoluminescence

<p>The aggregation of Perylene Diimide (PDI) and its derivatives strongly depends on the molecular structure, and therefore has great impact on the excited states. By regulating the molecular stacking such as monomer, dimer, J- and/or H-aggregate, the formation of different excited states is adjustable and controllable. In this study, we have synthesized two kinds of PDI derivatives - undecane-substituted PDI (PDI-1) and diisopropylphenyl-substituted PDI (PDI-2), and the films are fabricated with spin-coating method. By employing photoluminescence (PL), time-resolved photoluminescence (TRPL) and transient absorption (TA) spectroscopy, the excited-state dynamics of two PDI amorphous films have been investigated systematically. The result reveals that both films have formed excimer after photoexcitation mainly due to the stronger electronic coupling among molecule aggregate in the amorphous film. It should be noted that the excited state dynamics in PDI-2 shows a singlet fission like process, which is evidenced by the appearance of triplet state absorption. This study provides the dynamics of excited state in amorphous PDI films, and pave the way for better understanding and adjusting the excited state of amorphous films. </p>

Excited-State Dynamics in the RNA Nucleotide Uridine 5’-Monophosphate Investigated by Femtosecond Broadband Transient Absorption Spectroscopy

2019 ◽  
Author(s):  
Matthew M. Brister ◽  
Carlos Crespo-Hernández
Keyword(s):  
Excited State ◽  
Excited States ◽  
Ground State ◽  
Transient Absorption ◽  
Electronic Energy ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Vibrationally Excited ◽  
Excited State Dynamics ◽  
Π State

<p></p><p> Damage to RNA from ultraviolet radiation induce chemical modifications to the nucleobases. Unraveling the excited states involved in these reactions is essential, but investigations aimed at understanding the electronic-energy relaxation pathways of the RNA nucleotide uridine 5’-monophosphate (UMP) have not received enough attention. In this Letter, the excited-state dynamics of UMP is investigated in aqueous solution. Excitation at 267 nm results in a trifurcation event that leads to the simultaneous population of the vibrationally-excited ground state, a longlived <sup>1</sup>n<sub>O</sub>π* state, and a receiver triplet state within 200 fs. The receiver state internally convert to the long-lived <sup>3</sup>ππ* state in an ultrafast time scale. The results elucidate the electronic relaxation pathways and clarify earlier transient absorption experiments performed for uracil derivatives in solution. This mechanistic information is important because long-lived nπ* and ππ* excited states of both singlet and triplet multiplicities are thought to lead to the formation of harmful photoproducts.</p><p></p>

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