Deviation of polarity from linearity in liquid mixtures containing an ionic liquid

2015 ◽  
Vol 17 (47) ◽  
pp. 31613-31617 ◽  
Author(s):  
Vijay Beniwal ◽  
Shashi K. Shukla ◽  
Anil Kumar
Keyword(s):  
Ionic Liquid ◽  
Intermolecular Interactions ◽  
Chemical Properties ◽  
Liquid Mixtures ◽  
Physico Chemical ◽  
Different Types ◽  
Linear Behaviour

The physico-chemical properties of liquid mixtures, in general, exhibit deviations from linear behaviour with respect to their composition, arising out of different types of cross-intermolecular interactions (both specific and non-specific).

Understanding positive and negative deviations in polarity of ionic liquid mixtures by pseudo-solvent approach

2016 ◽  
Vol 18 (34) ◽  
pp. 23853-23863 ◽  
Author(s):  
Vijay Beniwal ◽  
Anil Kumar
Keyword(s):  
Ionic Liquid ◽  
Large Deviations ◽  
Intermolecular Interactions ◽  
Chemical Properties ◽  
Liquid Mixtures ◽  
Physico Chemical ◽  
Linear Behaviour

Physico-chemical properties of liquid mixtures in general display large deviations from linear behaviour, arising out of complex specific and non-specific intermolecular interactions.

scholarly journals Optimization of Electrolysis Parameters for Green Sanitation Chemicals Production Using Response Surface Methodology

Processes ◽  
2020 ◽  
Vol 8 (7) ◽  
pp. 792
Author(s):  
Nurul Izzah Khalid ◽  
Nurul Shaqirah Sulaiman ◽  
Norashikin Ab Aziz ◽  
Farah Saleena Taip ◽  
Shafreeza Sobri ◽  
...  
Keyword(s):  
Escherichia Coli ◽  
Food Industry ◽  
Chemical Properties ◽  
Bactericidal Effect ◽  
Electrolyzed Water ◽  
Optimum Parameters ◽  
Physico Chemical ◽  
Different Types ◽  
Different Temperatures ◽  
Optimized Conditions

Electrolyzed water (EW) shows great potential as a green and economical sanitation solution for the food industry. However, only limited studies have investigated the optimum electrolysis parameters and the bactericidal effect of acidic electrolyzed water (AcEW) and alkaline electrolyzed water (AlEW). Here, the Box–Behnken experimental design was used to identify the optimum parameters. The tests were conducted with different types of electrodes, electrical voltages, electrolysis times, and NaCl concentrations. There were no obvious differences observed in the physico-chemical properties of EW when different electrodes were used. However, stainless steel was chosen as it meets most of the selection criteria. The best-optimized conditions for AcEW were at 11.39 V, 0.65 wt.% NaCl, and 7.23 min, while the best-optimized conditions for AlEW were at 10.32 V, 0.6 wt.% NaCl, and 7.49 min. The performance of the optimum EW (AcEW and AlEW) compared with commercial cleaning detergents for the food industry was then evaluated. The bactericidal activity of AcEW and AlEW was examined against Escherichia coli ATCC 10536 at different temperatures (30 °C and 50 °C) for 30 s. The results show that both AcEW and AlEW have the ability to reduce the Escherichia coli to non-detectable levels (less than 2 log CFU/mL).

Density Measurement of Pyridine Based Ionic Liquids and Methanol Binary Mixtures

2013 ◽  
Vol 675 ◽  
pp. 248-251
Author(s):  
Zhuo Li ◽  
Chang Ping Li
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Energy Storage ◽  
Binary Mixtures ◽  
Density Measurement ◽  
Chemical Properties ◽  
Storage Material ◽  
Physico Chemical ◽  
New Energy ◽  
Energy Storage Material

As a new environmentally friendly solvent, ionic liquids have been investigated widely. The lack of physico-chemical properties data of ionic liquids has become a bottleneck that restricts their applications. In this study, the investigation of the density for binary mixtures of CnpyNTf2 (n = 2, 4, 5) and methanol is measured using Westphal balance. This study would be very important for the application of binary mixtures of ionic liquid and methanol in developing new energy storage material.

Tailoring ionic liquid catalysts: structure, acidity and catalytic activity of protonic ionic liquids based on anionic clusters, [(HSO4)(H2SO4)x]− (x = 0, 1, or 2)

2014 ◽  
Vol 16 (7) ◽  
pp. 3463-3471 ◽  
Author(s):  
Karolina Matuszek ◽  
Anna Chrobok ◽  
Fergal Coleman ◽  
Kenneth R. Seddon ◽  
Małgorzata Swadźba-Kwaśny
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Esterification Reaction ◽  
Anionic Clusters ◽  
Physico Chemical

The speciation of a family of inexpensive, easily prepared protonic ionic liquids, their physico-chemical properties and their performance as catalysts in the model esterification reaction have been correlated.

scholarly journals Influence of Ionic Liquid 1- butyl-3-methylimidazolium Chloride on the Soil Micro-Ecological System

2012 ◽  
Vol 6 (1) ◽  
pp. 1-4 ◽  
Author(s):  
Yanjie Tong ◽  
Qijun Wang ◽  
Yafan Bi ◽  
Mingke Lei ◽  
Yezi Lv ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Soil Microorganisms ◽  
Vibrio Fischeri ◽  
Chemical Properties ◽  
Ecological System ◽  
Pseudokirchneriella Subcapitata ◽  
Test Results ◽  
Ph Change ◽  
Soil System ◽  
Physico Chemical

In order to evaluate the influence of ionic liquid 1- butyl-3-methylimidazolium chloride ([Bmim]Cl) on the soil micro-ecological system, the toxicity of [Bmim]Cl to soil microorganisms and its impact on soil physico-chemical properties were investigated. Three soil samples, which were taken from the rape land, nursery land and the broad bean land respectively, were used for this study. The toxicity test results show that the [Bmim]Cl inhibited the growth of soil microorganisms including bacteria and actinomycetes. This inhibition became stronger with the [Bmim]Cl concentration increasing. The EC50 of soil bacteria was close to that of the Vibrio fischeri, and the EC50 of soil actinomycetes was near to that of the Pseudokirchneriella subcapitata. The soil physico-chemical properties test results indicate that the organic mass and the soluble salts in soil increased with the increase of the [Bmim]Cl concentration. The [Bmim]Cl also caused the pH change in the soil micro-ecological system. It suggests that the ionic liquid [Bmim]Cl would influence the soil micro- ecological system by inhibiting the growth of soil microorganisms and altering the soil physico-chemical properties when it contaminated the soil system.

scholarly journals Proposals on establishing a methodology for the systematic analysis of energy coal mixtures in judicial practice

2020 ◽  
Vol 305 ◽  
pp. 00059
Author(s):  
Csaba Lorinţ ◽  
Eugen Traistă ◽  
Adrian Florea
Keyword(s):  
Chemical Properties ◽  
Volatile Matter ◽  
Matter Content ◽  
Mineralogical Analysis ◽  
Systematic Analysis ◽  
Hygroscopic Moisture ◽  
Judicial Practice ◽  
Physico Chemical ◽  
Different Types ◽  
Coal Mixtures

There are several situations in which it is necessary to clarify the types of coal that enter into the composition of mixtures: technical expertise and/or establishing the nature of some coal wastes, often from old stockpiles, in order to eliminate them. The proposed method is based on the identification and description of those mineralogical-petrographic and physico-chemical properties whose pursuit can lead to a diagnosis in differentiation of coal types. Systematic analysis involves in the first stage the identification of the different types of coal present in the sample by mineralogical analysis. From the sample subjected to mineralogical analysis, granules are extracted from the different types of coal present in the sample and the characteristics defining them are determined: moisture and hygroscopic moisture content, volatile matter content, fixed carbon content, agglutination characteristics, etc. Further, the characteristics of the mixtures are determined on another part of the sample and their structure is determined by algebraic methods.

The estimation of physico-chemical properties of ionic liquid N-propylpyridine rheniumate

2009 ◽  
Vol 283 (1-2) ◽  
pp. 93-96 ◽  
Author(s):  
Shu-liang Zang ◽  
Da-Wei Fang ◽  
Jian-xin Li ◽  
Yu-Yang Zhang ◽  
Shuang Yue
Keyword(s):  
Ionic Liquid ◽  
Chemical Properties ◽  
Physico Chemical

scholarly journals PHYSICO-CHEMICAL PROPERTIES OF MAGNESIUM IONIC LIQUID ANALOGOUS

2012 ◽  
Vol 57 (3) ◽  
pp. 1208-1212 ◽  
Author(s):  
Huaiyou Wang ◽  
Yongzhong Jia ◽  
Xiaohua Wang ◽  
Jun Ma ◽  
Yan Jing
Keyword(s):  
Ionic Liquid ◽  
Chemical Properties ◽  
Physico Chemical

Synthesis and characterization of 2′,3′-epoxy propyl-N-methyl-2-oxopyrrolidinium salicylate ionic liquid and study of its interaction with water or methanol

RSC Advances ◽  
2016 ◽  
Vol 6 (66) ◽  
pp. 61566-61575 ◽  
Author(s):  
A. Vasanthakumar ◽  
I. Bahadur ◽  
G. Redhi ◽  
R. M. Gengan
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Chemical Properties ◽  
Synthesis And Characterization ◽  
Physico Chemical

Important physico-chemical properties of ionic liquids (ILs) can be manipulated by adjusting the nature of the cation or anion.

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