Solution concentration controlled self-assembling structure with host–guest recognition at the liquid–solid interface

2015 ◽  
Vol 17 (37) ◽  
pp. 24462-24467 ◽  
Author(s):  
Siqi Zhang ◽  
Junyong Zhang ◽  
Ke Deng ◽  
Jingli Xie ◽  
Wubiao Duan ◽  
...  
Keyword(s):  
Solution Concentration ◽  
Heptanoic Acid ◽  
Structural Variety ◽  
Solid Interface ◽  
Self Assembling

This work describes structural variety in the co-assembly of H3TTCA/COR controlled by the solution concentration of COR at the 1-heptanoic acid/HOPG interface.

Steric matching and the concentration induced self-assembled structural variety of 2,7-bis(n-alkoxy)-9-fluorenone at the aliphatic solvent/graphite interface

2014 ◽  
Vol 16 (24) ◽  
pp. 12544-12553 ◽  
Author(s):  
Xinrui Miao ◽  
Li Xu ◽  
Lihua Cui ◽  
Wenli Deng
Keyword(s):  
Self Assembly ◽  
Solution Concentration ◽  
The Self ◽  
Structural Polymorphism ◽  
Structural Variety ◽  
Self Assembled

The self-assembly F–OCn displays structural polymorphism depending on the change of solution concentration at the aliphatic solvent/graphite interface.

scholarly journals Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

2014 ◽  
Vol 50 (88) ◽  
pp. 13465-13468 ◽  
Author(s):  
W. Song ◽  
N. Martsinovich ◽  
W. M. Heckl ◽  
M. Lackinger
Keyword(s):  
Self Assembly ◽  
Enthalpy Change ◽  
Heptanoic Acid ◽  
Solid Interface

The overall enthalpy change associated with hexabromotriphenylene monolayer self-assembly at the heptanoic acid–graphite interface was assessed by an adapted Born–Haber cycle.

A size, shape and concentration controlled self-assembling structure with host–guest recognition at the liquid–solid interface studied by STM

Nanoscale ◽  
2016 ◽  
Vol 8 (23) ◽  
pp. 11962-11968 ◽  
Author(s):  
Mengqi Shen ◽  
Zhouyang Luo ◽  
Siqi Zhang ◽  
Shuai Wang ◽  
Lili Cao ◽  
...  
Keyword(s):  
Solid Interface ◽  
Self Assembling

scholarly journals Concentration-dependent rhombitrihexagonal tiling patterns at the liquid/solid interface

2015 ◽  
Vol 6 (10) ◽  
pp. 5853-5858 ◽  
Author(s):  
Vladimir Stepanenko ◽  
Ramesh Kandanelli ◽  
Shinobu Uemura ◽  
Frank Würthner ◽  
Gustavo Fernández
Keyword(s):  
Solid Interface ◽  
Self Assembling ◽  
Archimedean Tiling ◽  
Complex Forms ◽  
Tiling Patterns

A self-assembling Pd(ii) complex forms sophisticated concentration-dependent Archimedean tiling patterns composed of three types of polygons at the liquid/solid interface.

Concentration-dependent structure and structural transition from chirality to nonchirality at the liquid–solid interface by coassembly

Nanoscale ◽  
2015 ◽  
Vol 7 (27) ◽  
pp. 11734-11745 ◽  
Author(s):  
Li Xu ◽  
Xinrui Miao ◽  
Lihua Cui ◽  
Pei Liu ◽  
XiaoFeng Chen ◽  
...  
Keyword(s):  
Building Block ◽  
Structural Transition ◽  
Solution Concentration ◽  
Close Packing ◽  
Solvent Interactions ◽  
Solid Interface ◽  
Loose Packing

The structural transition from a chiral loose-packing to nonchiral close-packing pattern by one building block was pursued by changing the solution concentration and codependent molecule–solvent interactions.

Temperature-controlled self-assembling structure with selective guest-recognition at the liquid–solid interface

2013 ◽  
Vol 15 (1) ◽  
pp. 125-128 ◽  
Author(s):  
Yibao Li ◽  
Chunhua Liu ◽  
Yunzhi Xie ◽  
Xiaokang Li ◽  
Xun Li ◽  
...  
Keyword(s):  
Solid Interface ◽  
Self Assembling ◽  
Temperature Controlled

Synthesis of Chiral Self-Assembling Rhombs and Their Characterization in Solution, in the Gas Phase, and at the Liquid−Solid Interface

2005 ◽  
Vol 127 (50) ◽  
pp. 17672-17685 ◽  
Author(s):  
Kyung Seok Jeong ◽  
Sun Young Kim ◽  
Ueon-Sang Shin ◽  
Michael Kogej ◽  
Nguyen T. M. Hai ◽  
...  
Keyword(s):  
Gas Phase ◽  
Solid Interface ◽  
Self Assembling

The Precipitation of Si in AlCuSi Thin Films

1973 ◽  
Vol 31 ◽  
pp. 34-35 ◽  
Author(s):  
R. M. Anderson
Keyword(s):  
Electron Microscopy ◽  
Thin Films ◽  
Heat Treatment ◽  
Solid Solution ◽  
Integrated Circuit ◽  
Copper Film ◽  
Solution Concentration ◽  
X Ray ◽  
Silicon Thin Films ◽  
Before And After

Aluminum-copper-silicon thin films have been considered as an interconnection metallurgy for integrated circuit applications. Various schemes have been proposed to incorporate small percent-ages of silicon into films that typically contain two to five percent copper. We undertook a study of the total effect of silicon on the aluminum copper film as revealed by transmission electron microscopy, scanning electron microscopy, x-ray diffraction and ion microprobe techniques as a function of the various deposition methods.X-ray investigations noted a change in solid solution concentration as a function of Si content before and after heat-treatment. The amount of solid solution in the Al increased with heat-treatment for films with ≥2% silicon and decreased for films <2% silicon.

Atom-probe analysis of the solid-liquid interface

1995 ◽  
Vol 53 ◽  
pp. 676-677
Author(s):  
J.A. Panitz
Keyword(s):  
Molecular Level ◽  
Selective Adsorption ◽  
Electronic Devices ◽  
Atom Probe ◽  
Chemical Agent ◽  
Hostile Environment ◽  
Solid Interface ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Chemically Selective

The first few atomic layers of a solid can form a barrier between its interior and an often hostile environment. Although adsorption at the vacuum-solid interface has been studied in great detail, little is known about adsorption at the liquid-solid interface. Adsorption at a liquid-solid interface is of intrinsic interest, and is of technological importance because it provides a way to coat a surface with monolayer or multilayer structures. A pinhole free monolayer (with a reasonable dielectric constant) could lead to the development of nanoscale capacitors with unique characteristics and lithographic resists that surpass the resolution of their conventional counterparts. Chemically selective adsorption is of particular interest because it can be used to passivate a surface from external modification or change the wear and the lubrication properties of a surface to reflect new and useful properties. Immunochemical adsorption could be used to fabricate novel molecular electronic devices or to construct small, “smart”, unobtrusive sensors with the potential to detect a wide variety of preselected species at the molecular level. These might include a particular carcinogen in the environment, a specific type of explosive, a chemical agent, a virus, or even a tumor in the human body.

Torus Circumference and Thickness Parameters From a Linear DNA Size Series Suggest How Toruses Self-Assemble

1985 ◽  
Vol 43 ◽  
pp. 522-523
Author(s):  
George C. Ruben ◽  
Kenneth A. Marx
Keyword(s):  
Tertiary Structure ◽  
Dna Complexes ◽  
Tertiary Structures ◽  
Self Assembling ◽  
Double Stranded Dna ◽  
Calf Thymus ◽  
Dna Organization ◽  
Condensed Dna ◽  
Dna Size

Certain double stranded DNA bacteriophage and viruses are thought to have their DNA organized into large torus shaped structures. Morphologically, these poorly understood biological DNA tertiary structures resemble spermidine-condensed DNA complexes formed in vitro in the total absence of other macromolecules normally synthesized by the pathogens for the purpose of their own DNA packaging. Therefore, we have studied the tertiary structure of these self-assembling torus shaped spermidine- DNA complexes in a series of reports. Using freeze-etch, low Pt-C metal (10-15Å) replicas, we have visualized the microscopic DNA organization of both calf Thymus( CT) and linear 0X-174 RFII DNA toruses. In these structures DNA is circumferentially wound, continuously, around the torus into a semi-crystalline, hexagonal packed array of parallel DNA helix sections.

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