scholarly journals Hydrogen bonding in the ethanol–water dimer

2015 ◽  
Vol 17 (37) ◽  
pp. 24210-24214 ◽  
Author(s):  
Ian A. Finneran ◽  
P. Brandon Carroll ◽  
Marco A. Allodi ◽  
Geoffrey A. Blake
Keyword(s):  
Hydrogen Bonding ◽  
Fourier Transform ◽  
Ground State ◽  
Microwave Spectroscopy ◽  
Water Dimer ◽  
Rotational Spectrum ◽  
Chirped Pulse ◽  
Fourier Transform Microwave Spectroscopy

We report the first rotational spectrum of the ground state of the isolated ethanol–water dimer using chirped-pulse Fourier transform microwave spectroscopy between 8–18 GHz.

Analysis of Internal Rotation and Determination of the Heavy Atom Structure of anti-2,3-Dimethylthiirane by Fourier Transform Microwave Spectroscopy

1996 ◽  
Vol 51 (10-11) ◽  
pp. 1099-1106 ◽  
Author(s):  
Holger Hartwig ◽  
Helmut Dreizler
Keyword(s):  
Fourier Transform ◽  
Internal Rotation ◽  
Ground State ◽  
Heavy Atom ◽  
Microwave Spectroscopy ◽  
Rotational Spectrum ◽  
Advanced Technique ◽  
Fourier Transform Microwave Spectroscopy ◽  
Potential Parameters

Abstract We used the advanced technique of Fourier transform microwave spectroscopy to measure and assign the ground state rotational spectrum of anti-2,3-dimethylthiirane, and to analyse the internal rotation of the two methyl groups. The potential parameters obtained are V3 = 13.1678(21) and V12' = -1.6678(25) kJ/mol. The measurement and assignment of the 13C and 34S isotopomers in the ground state allowed to determine the molecular structure of the heavy atom frame using the Τs and Τ0 methods.

The rotational spectrum of epifluorohydrin measured by chirped-pulse Fourier transform microwave spectroscopy

2006 ◽  
Vol 238 (2) ◽  
pp. 200-212 ◽  
Author(s):  
Gordon G. Brown ◽  
Brian C. Dian ◽  
Kevin O. Douglass ◽  
Scott M. Geyer ◽  
Brooks H. Pate
Keyword(s):  
Fourier Transform ◽  
Microwave Spectroscopy ◽  
Rotational Spectrum ◽  
Chirped Pulse ◽  
Fourier Transform Microwave Spectroscopy
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