scholarly journals Hydrogen-bond acidity of ionic liquids: an extended scale

2015 ◽  
Vol 17 (29) ◽  
pp. 18980-18990 ◽  
Author(s):  
Kiki A. Kurnia ◽  
Filipa Lima ◽  
Ana Filipa M. Cláudio ◽  
João A. P. Coutinho ◽  
Mara G. Freire
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Theoretical Approaches ◽  
Hydrogen Bond Acidity ◽  
Extended Scale

Through the combination of experimental and theoretical approaches, a new extended scale for the hydrogen-bonding acidity of ionic liquids is provided.

Hydrogen-bonding. Part 11. A quantitative evaluation of the hydrogen-bond acidity of imides as solutes

1990 ◽  
Vol 55 (7) ◽  
pp. 2227-2229 ◽  
Author(s):  
Michael H. Abraham ◽  
Priscilla L. Grellier ◽  
David V. Prior ◽  
Jeffrey J. Morris ◽  
Peter J. Taylor ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Quantitative Evaluation ◽  
Hydrogen Bond Acidity

scholarly journals Alternative probe for the determination of the hydrogen-bond acidity of ionic liquids and their aqueous solutions

2017 ◽  
Vol 19 (18) ◽  
pp. 11011-11016 ◽  
Author(s):  
Pedro P. Madeira ◽  
Helena Passos ◽  
Joana Gomes ◽  
João A. P. Coutinho ◽  
Mara G. Freire
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Chemical Shifts ◽  
Nmr Chemical Shifts ◽  
Hydrogen Bond Acidity ◽  
C Nmr

The alternative probe pyridine-N-oxide allows the determination of the hydrogen-bond acidity of both neat ionic liquids and their aqueous solutions based on 13C NMR chemical shifts.

The solubility of gases and vapours in ethanol - the connection between gaseous solubility and water-solvent partition

1998 ◽  
Vol 76 (6) ◽  
pp. 703-709 ◽  
Author(s):  
Michael H Abraham ◽  
Gary S Whiting ◽  
Wendel J Shuely ◽  
Ruth M Doherty
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Correlation Equation ◽  
Strong Hydrogen Bond ◽  
Log P ◽  
Water Solvent ◽  
Chemical Factors ◽  
Solubility Of Gases ◽  
Solubility Coefficients ◽  
Hydrogen Bond Acidity

Ostwald solubility coefficients, as log L, for solutes in water and ethanol have been combined to give log PEtOH for partition between the two pure solvents. Sixty-four such values have been correlated through our solvation equation, the coefficients of which lead to the conclusion that ethanol and water solvents are equally strong hydrogen-bond bases, but that ethanol is much weaker as a hydrogen-bond acid. A slightly different solvation equation has been used to correlate 68 values of log LEtOH; the coefficients in this equation yield the same conclusions as to the hydrogen-bond acidity and basicity of bulk ethanol. In addition, an analysis of the various terms in the log LEtOH correlation equation allows the elucidation of the various chemical factors that govern the solubility of gaseous solutes in ethanol solvent at 298 K.Key words: solubility, partition, hydrogen-bonding, ethanol, water.

scholarly journals Extended scale for the hydrogen-bond basicity of ionic liquids

2014 ◽  
Vol 16 (14) ◽  
pp. 6593 ◽  
Author(s):  
Ana Filipa M. Cláudio ◽  
Lorna Swift ◽  
Jason P. Hallett ◽  
Tom Welton ◽  
João A. P. Coutinho ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquids ◽  
Hydrogen Bond Basicity ◽  
Extended Scale

Hydrogen bonding. Part 7. A scale of solute hydrogen-bond acidity based on log K values for complexation in tetrachloromethane

1989 ◽  
pp. 699 ◽  
Author(s):  
Michael H. Abraham ◽  
Priscilla L. Grellier ◽  
David V. Prior ◽  
Philip P. Duce ◽  
Jeffrey J. Morris ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Hydrogen Bond Acidity

scholarly journals Tough and stretchable inorganic/organic double network ion gel containing gemini-type ionic liquid as a multiple hydrogen bond cross-linker

RSC Advances ◽  
2019 ◽  
Vol 9 (21) ◽  
pp. 11870-11876 ◽  
Author(s):  
Tomoki Yasui ◽  
Eiji Kamio ◽  
Hideto Matsuyama
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquid ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Double Network ◽  
Multiple Hydrogen Bond ◽  
Ion Gel ◽  
Cross Linker ◽  
Ion Gels

The extensibility and toughness of inorganic/organic double-network ion gels were dramatically increased using gemini-type ionic liquids as a hydrogen bonding-based weak cross-linker.

Highly efficient separation of 5-hydroxymethylfurfural from imidazolium-based ionic liquids

2021 ◽  
Author(s):  
Huiyong Wang ◽  
Jingjing Cui ◽  
Yuling Zhao ◽  
Zhiyong Li ◽  
Jianji Wang
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Hydrogen Bonding Interaction ◽  
Hydrogen Bond Acceptor ◽  
Efficient Separation ◽  
Highly Efficient ◽  
Bonding Interaction

The hydrogen bond acceptor ability of solvents, the interactions between the anion and cation of ILs, and the hydrogen bonding interaction of the anion with 5-HMF play important roles in the separation of 5-HMF from ILs.

scholarly journals Mechanisms of hydrogen bond formation between ionic liquids and cellulose and the influence of water content

2015 ◽  
Vol 17 (8) ◽  
pp. 5767-5775 ◽  
Author(s):  
Brooks D. Rabideau ◽  
Ahmed E. Ismail
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Ionic Liquids ◽  
Water Content ◽  
Complex Network ◽  
Bond Formation ◽  
Hydrogen Bond Formation ◽  
Influence Of Water

We explore the complex network of transitions occurring between different hydrogen bonding states within ionic liquids and cellulose.

scholarly journals α-Fluoro-o-cresols: The Key Role of Intramolecular Hydrogen Bonding in Conformational Preference and Hydrogen-Bond Acidity

ChemPhysChem ◽  
2016 ◽  
Vol 17 (17) ◽  
pp. 2702-2709 ◽  
Author(s):  
Elena Bogdan ◽  
Alexis Quarré de Verneuil ◽  
François Besseau ◽  
Guillaume Compain ◽  
Bruno Linclau ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Intramolecular Hydrogen Bonding ◽  
Conformational Preference ◽  
Hydrogen Bond Acidity ◽  
Intramolecular Hydrogen
Sign in / Sign up

Export Citation Format

Share Document