The relationship between the boron dipyrromethene (BODIPY) structure and the effectiveness of homogeneous and heterogeneous solar hydrogen-generating systems as well as DSSCs

2015 ◽  
Vol 17 (15) ◽  
pp. 9716-9729 ◽  
Author(s):  
Geng-Geng Luo ◽  
Hui Lu ◽  
Xiao-Long Zhang ◽  
Jing-Cao Dai ◽  
Ji-Huai Wu ◽  
...  

BODIPY photosensitizers were used to investigate the relationship between structure and effectiveness of visible-light-driven hydrogen production as well as DSSCs.

2007 ◽  
Vol 79 (11) ◽  
pp. 1917-1927 ◽  
Author(s):  
Akihiko Kudo

Photocatalytic water splitting is a challenging reaction because it is an ultimate solution to energy and environmental issues. Recently, many new powdered photocatalysts for water splitting have been developed. For example, a NiO (0.2 wt %)/NaTaO3:La (2 %) photocatalyst with a 4.1-eV band gap showed high activity for water splitting into H2 and O2 with an apparent quantum yield of 56 % at 270 nm. Overall water splitting under visible light irradiation has been achieved by construction of a Z-scheme photocatalysis system employing visible-light-driven photocatalysts, Ru/SrTiO3:Rh and BiVO4 for H2 and O2 evolution, and an Fe3+/Fe2+ redox couple as an electron relay. Moreover, highly efficient sulfide photocatalysts for solar hydrogen production in the presence of electron donors were developed by making solid solutions of ZnS with AgInS2 and CuInS2 of narrow band gap semiconductors. Thus, the database of powdered photocatalysts for water splitting has become plentiful.


Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 848
Author(s):  
Jong-Wook Hong

Visible-light-driven hydrogen production through photocatalysis has attracted enormous interest owing to its great potential to address energy and environmental issues. However, photocatalysis possesses several limitations to overcome for practical applications, such as low light absorption efficiency, rapid charge recombination, and poor stability of photocatalysts. Here, the preparation of efficient noble metal–semiconductor hybrid photocatalysts for photocatalytic hydrogen production is presented. The prepared ternary Rh–TiO2–CeO2 hybrid photocatalysts exhibited excellent photocatalytic performance toward the hydrogen production reaction compared with their counterparts, ascribed to the synergistic combination of Rh, TiO2, and CeO2.


Author(s):  
Stavroula Kampouri ◽  
Fatmah M. Ebrahim ◽  
Maria Fumanal ◽  
Makenzie Nord ◽  
Pascal A. Schouwink ◽  
...  

Author(s):  
Parul Verma ◽  
Ashish Singh ◽  
Faruk Ahamed Rahimi ◽  
Tapas Kumar Maji

Colocalization of essential molecular components in the solvated soft supramolecular assembly towards realizing visible-light-driven hydrogen evolution would be an exciting approach for sustainable energy by generating clean solar fuel. In...


2016 ◽  
Vol 146 (9) ◽  
pp. 1655-1662 ◽  
Author(s):  
Xiang-Yu Liu ◽  
Wen-Dong Wei ◽  
Shi-Cong Cui ◽  
Jin-Gang Liu

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